Explanation:
system at equilibrium, will the reaction shift towards reactants ~
--?'
2. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). The production of ammonia is an
exothermic reaction. Will heating the equilibrium system increase o~e amount of
ammonia produced? . .co:(
3. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). Ifwe use a catalyst, which way will
the reaction shift? ':'\
.1.+- w~t s~,H (o')l r'eo.c. e~ ei~i"liht-,·u.fn\ P~~,
4. (3 Pts) ff 1ven th e o £ 11 owmg d t a a £ or th ere action: A(g) + 2B(s) =; AB2(g)
Temperature (K) Kc
300 1.5x104
600 55 k ' pr, cl l<..J~
e- ~ r fee, ct o. ~ 1<
900 3.4 X 10-3
Is the reaction endothermic or exothermic (explain your answer)?
t d- IS o.,;r-. \4\a..i~1f't~ °the te.Y'il(lf1,:J'u.r-a a•~S. j lrvdu..c,,.) +~H~to{' '\
exothe-rnh't.-- ,.. ..,. (/.., ,~.
5. (4 Pts) Consider the reaction, N2(g) + 3H2(g) =; 2NH3(g). Kc= 4.2 at 600 K.
What is the value of Kc for 4 NH3(g) =; 2N2(g) + 6H2(g)
N ... ~l + 3 H~(ri ~ ~Nli3~) kl,= ~:s;H,J3 # 4. J..
~ ;)N~~) ~ ~ H ~) ~\-_ == [A!;J:t D~~Jb
J. [,v 1+3] ~
I
4,:i.~ = 0,05
5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.
Initially, there are 5.00 mol of ammonia in a 5.00 L reactor vessel. The initial concentration of ammonia is:
[tex][NH_3]_i = \frac{5.00mol}{5.00L} = 1.00 M[/tex]
At equilibrium, there is 1.00 mole of ammonia in the 5.00 L vessel. The concentration of ammonia at equilibrium is:
[tex][NH_3]eq = \frac{1.00mol}{5.00L} = 0.200 M[/tex]
We can calculate the concentrations of all the species at equilibrium using an ICE chart.
2 NH₃(g) ⇄ 3 H₂(g) + N₂(g)
I 1.00 0 0
C -2x +3x +x
E 1.00-2x 3x x
Since the concentration of ammonia at equilibrium is 0.200 M,
[tex]1.00-2x = 0.200\\\\x = 0.400 M[/tex]
The concentrations of all the species at equilibrium are:
[tex][NH_3] = 0.200 M\\[H_2] = 3x = 1.20 M\\[N_2] = x = 0.400 M[/tex]
The concentration equilibrium constant (Kc) is:
[tex]Kc = \frac{[H_2]^{2} [N_2]}{[NH_3]^{2} } = \frac{(1.20^{3})(0.400) }{0.200^{2} } = 17.3[/tex]
5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.
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Calculate the volume in liters of a M mercury(II) iodide solution that contains of mercury(II) iodide . Round your answer to significant digits.
Answer:
41L
Explanation:
Of a 4.8x10⁻⁵M mercury (II) iodide that contains 900mg of mercury (II) iodide. 2 significant digits
Molarity, M, is an unit of concentration in chemistry defined as the ratio between moles of solute (Mercury (II) iodide in this case) per Liter of solution.
A 4.8x10⁻⁵M solution contains 4.8x10⁻⁵ moles of solute per liter.
Now, 900mg = 0.900g of mercury (II) iodide (Molar mass: 454.4g/mol) are:
0.900g × (1mol / 454.4g) = 1.98x10⁻³moles of HgI₂
If in 1L there are 4.8x10⁻⁵ moles of HgI₂, There are 1.98x10⁻³moles of HgI₂ in:
1.98x10⁻³moles of HgI₂ ₓ (1L / 4.8x10⁻⁵moles) =
41L30. What is the Bronsted base of H2PO4- + OH- ⟶HPO42- + H2O?
Answer:
OH⁻ is the Bronsted-Lowry base.
Explanation:
A Bronsted-Lowry base is a substance that accepts protons. In the chemical equation, OH⁻ accepts a proton from H₂PO₄⁻ to become H₂O. H₂PO₄⁻ would be a Bronsted-Lowry acid because it donates a proton to OH⁻ and becomes HPO₄²⁻.
Hope that helps.
A chemist adds of a M barium chlorate solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.
The given question is incomplete, the complete question is:
A chemist adds 200.0 ml of a 0.52M barium chlorate (Ba(CIO3)2) solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.
Answer:
The correct answer is 32 grams.
Explanation:
Based on the given solution, the molarity of barium chlorate solution given is 0.52 M, this shows that the solution will comprise 0.52 moles in 1 L or 1000 ml of the solution.
Therefore, in 200 ml, it will comprise 0.52/1000 × 200 moles of Ba(ClO₃)₂,
= 0.52/1000 × 200 = 0.104 moles
The molecular mass of Ba(ClO₃)₂ is 304.23 gram per mole
So, the mass of Ba(ClO₃)₂ in 0.104 moles will be,
= 304.23 g/mol × 0.104
= 31.639 grams or 32 grams.
You are given a sample of metal and asked to determine its specific heat. You weigh the sample and find that its weight is 30.0 N. You carefully add 1.25×10^4 J of heat energy to the sample and find that its temperature rises 15.0 °C. What is the sample's specific heat?
Answer:
272.33 J/Kg°C
Explanation:
Data obtained from the question include the following:
Weight of metal = 30 N
Heat used (Q) = 1.25×10⁴ J
Change in temperature (ΔT) = 15.0 °C.
Specific heat capacity (C) =..?
Next, we shall determine the mass of the metal.
The mass of the metal can be obtained as follow:
Weight (W) = mass (m) x acceleration due to gravity (g)
W = mg
Weight of metal = 30 N
Acceleration due to gravity = 9.8 m/s²
Mass (m) =..?
W = mg
30 = m x 9.8
Divide both side by 9.8
m = 30/9.8
m = 3.06 Kg
Finally, we shall determine the specific heat capacity of the metal as show below:
Heat used (Q) = 1.25×10⁴ J
Change in temperature (ΔT) = 15.0 °C.
Mass (m) = 3.06 Kg
Specific heat capacity (C) =..?
Q = mCΔT
1.25×10⁴ = 3.06 x C x 15
Divide both side by 3.06 x 15
C = (1.25×10⁴) / (3.06 x 15)
C = 272.33 J/Kg°C
Therefore, the specific heat capacity of metal is 272.33 J/Kg°C.
Calculate the [H+] and pH of a 0.0040 M hydrazoic acid solution. Keep in mind that the Ka of hydrazoic acid is 2.20×10−5. Use the method of successive approximations in your calculations or the quadratic formula.
Answer:
[tex][H^+]=0.000285[/tex]
[tex]pH=3.55[/tex]
Explanation:
In this, we can with the ionization equation for the hydrazoic acid ([tex]HN_3[/tex]). So:
[tex]HN_3~<->~H^+~+~N_3^-[/tex]
Now, due to the Ka constant value, we have to use the whole equilibrium because this is not a strong acid. So, we have to write the Ka expression:
[tex]Ka=\frac{[H^+][N_3^-]}{[HN_3]}[/tex]
For each mol of [tex]H^+[/tex] produced we will have 1 mol of [tex]N_3^-[/tex]. So, we can use "X" for the unknown values and replace in the Ka equation:
[tex]Ka=\frac{X*X}{[HN_3]}[/tex]
Additionally, we have to keep in mind that [tex]HN_3[/tex] is a reagent, this means that we will be consumed. We dont know how much acid would be consumed but we can express a subtraction from the initial value, so:
[tex]Ka=\frac{X*X}{0.004-X}[/tex]
Finally, we can put the ka value and solve for "X":
[tex]2.2X10^-^5=\frac{X*X}{0.004-X}[/tex]
[tex]2.2X10^-^5=\frac{X^2}{0.004-X}[/tex]
[tex]X= 0.000285[/tex]
So, we have a concentration of 0.000285 for [tex]H^+[/tex]. With this in mind, we can calculate the pH value:
[tex]pH=-Log[H^+]=-Log[0.000285]=3.55[/tex]
I hope it helps!
The [H+] and pH of a 0.0040 M hydrazoic acid solution is 0.000296648 and 3.527759
pH based problem:What information do we have?
Hydrazoic acid solution = 0.0040 M
Ka of hydrazoic acid = 2.20 × 10⁻⁵
We know that weak acids
[H+] = √( Ka × C)
[H+] = √( 2.2 × 10⁻⁵ × 0.0040)
[H+] = 0.000296648
So,
pH = -log [H+]
pH = -log [0.000296648]
Using log calculator
pH = 3.527759
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An acetic acid buffer solution is required to have a pH of 5.27. You have a solution that contains 0.010 mol of Acetic acid. What molarity of sodium acetate will you need to add to the solution
Answer:
Molarity of sodium acetate you will need to add is 0.0324M
Explanation:
Assuming volume of the buffer is 1L.
The pH of a buffer can be determined using Henderson-Hasselbalch equation:
pH = pKa + log [A⁻] / [HA]
Where pKa is pKa of the weak acid, [A⁻] molar concentration of conjugate base and [HA] molar concentration of weak acid
Replacing for the acetic buffer (pKa = 4.76):
pH = 4.76 + log [Sodium Acetate] / [Acetic Acid]
As you have 0.010 moles of acetic acid in 1L:
[Acetic Acid] = 0.010mol / 1L = 0.010M
And you require a pH of 5.27:
5.27 = 4.76 + log [Sodium Acetate] / [0.010M]
0.51 = log [Sodium Acetate] / [0.010M]
10^0.51 = [Sodium Acetate] / [0.010M]
3.236 = [Sodium Acetate] / [0.010M]
3.236 [0.010M] = [Sodium Acetate]
0.0324M = [Sodium Acetate]
Molarity of sodium acetate you will need to add is 0.0324M
A study of the system, 4NH3(g) + 7O2(g) <--> 2N2O4(g) + 6H2O(g), was carried out. A system was prepared with [NH3] = [O2] = 3.60 M as the only components initially. At equilibrium, [N2O4] is 0.600 M. Calculate the equilibrium concentration of NH3(g).
Answer:
The equilbrium concentration of NH₃(g) is 2.4 M
Explanation:
The balanced reaction is:
4 NH₃(g) + 7 O₂(g) ⇔ 2 N₂O₄(g) + 6 H₂O(g)
By stoichiometry of the reaction, 2 moles of N₂O₄ are formed from 4 moles of NH₃.
Considering that the concentration is [tex]concentration=\frac{number of moles}{volume}[/tex] and with a volume of 1 liter, it is possible to apply the following rule of three: if 2 M of N₂O₄ are formed from 4 M of NH₃, 0.6 M of N₂O₄ from what concentration of NH₃ are formed?
[tex]concentration of NH_{3}=\frac{0.6 M of N_{2}O_{3} *4MofNH_{3} }{2 M of N_{2}O_{3} }[/tex]
concentration of NH₃= 1.2 M
By subtracting the moles of NH3 in equilibrium from the moles of NH₃ initially, you will see how many moles of NH₃ were converted and remain in equilibrium: 3.6 M - 1.2 M= 2.4 M
The equilbrium concentration of NH₃(g) is 2.4 M
What mass of Si, in grams, can be produced from the reaction below starting with 225 g SiCl4 and 101 g Mg? SiCl4 + Mg Si + MgCl2 Given: 1 mol SiCl4 = 169.8963 g SiCl4 1 mol Mg = 24.3050 g Mg 1 mol Si = 28.0855 g Si
Answer:
[tex]m_{Si}=37.2gSi[/tex]
Explanation:
Hello,
In this case, for the undergoing balanced chemical reaction:
[tex]SiCl_4 + 2Mg \rightarrow Si + 2MgCl_2[/tex]
We must first identify the limiting reactant given the 225 g of SiCl4 and 101 g of Mg. Thus, we compute the available moles of SiCl4:
[tex]n_{SiCl_4}=225gSiCl_4*\frac{1molSiCl_4}{169.8963gSiCl_4}=1.324molSiCl_4[/tex]
Next, by using the 1:2 mole ratio between SiCl4 and Mg, we compute the moles of SiCl4 consumed by 101 g of Mg:
[tex]n_{SiCl_4}^{consumed}=101gMg*\frac{1molMg}{24.3050gMg} *\frac{1molSiCl_4}{2molMg} =2.08molSiCl_4[/tex]
Thus, since less moles of SiCl4 are available, we can infer it is the limiting reactant whereas the Mg is in excess. In such a way, the produced grams of Si are computed considering the 1:1 molar ratio between SiCl4 and Si:
[tex]m_{Si}=1.324molSiCl_4*\frac{1molSi}{1molSiCl_4} *\frac{28.0855gSi}{1molSi} \\\\m_{Si}=37.2gSi[/tex]
Best regards.
A sample of neon gas at a pressure of 0.609 atm and a temperature of 25.0 °C, occupies a volume of 19.9 liters. If the gas is compressed at constant temperature to a
volume of 12.7 liters, the pressure of the gas sample will be
atm.
Answer:
The pressure of the gas sample will be 0.954 atm.
Explanation:
Boyle's law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; conversely if the pressure decreases, the volume increases.
Boyle's law is expressed mathematically as:
Pressure * Volume = constant
o P * V = k
To determine the change in pressure or volume during a transformation at constant temperature, the following is true:
P1 · V1 = P2 · V2
That is, the product between the initial pressure and the initial volume is equal to the product of the final pressure times the final volume.
In this case:
P1= 0.609 atmV1= 19.9 LP2=?V2= 12.7 LReplacing:
0.609 atm* 19.9 L= P2* 12.7 L
Solving:
[tex]P2=\frac{0.609 atm* 19.9 L}{12.7 L}[/tex]
P2= 0.954 atm
The pressure of the gas sample will be 0.954 atm.
what is the difference between acidic and basic protein
Answer:
Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.
Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10 genes.
Answer:
Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.
Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10
Explanation:
Zinc bromide is considered which of the following?
A) molecular compound
B) atomic element
C) molecular element
D) ionic compound
Answer:
D
Explanation:
soluble in water and acidic11. How did the solubility product constant Ksp of KHT in pure water compare to its solubility product constant Ksp of KHT in KCl solution? Are these results what you would expect? Why?
Answer:
Explanation:
KHT is a salt which ionises in water as follows
KHT ⇄ K⁺ + HT⁻
Solubility product Kw= [ K⁺ ] [ HT⁻ ]
product of concentration of K⁺ and HT⁻ in water
In KCl solution , the solubility product of KHT will be decreased .
In KCl solution , there is already presence of K⁺ ion in the solution . So
in the equation
[ K⁺ ] [ HT⁻ ] = constant
when K⁺ increases [ HT⁻ ] decreases . Hence less of KHT dissociates due to which its solubility decreases . It is called common ion effect . It is so because here the presence of common ion that is K⁺ in both salt to be dissolved and in solvent , results in decrease of solubility of the salt .
Charcoal from the dwelling level of the Lascaux Cave in France gives an average count of 0.97 disintegrations of ^14 C per minute per gram of sample. Living wood gives 6.68 disintegrations per minute per gram. Estimate the date of occupation and hence the probable date of the wall painting in the Lascaux Cave. Hint: Disintegrations per minute per gram" has the same units as the time-derivative of concentration for a radioactive decay model. (You may use the fact that the half-life of ^14C is 5568 years.)
Answer:
Explanation:
count given by old sample = .97 disintegrations per minute per gram
count given by fresh sample = 6.68 disintegrations per minute per gram
Half life of radioactive carbon = 5568 years
rate of disintegration
dN / dt = λ N
In other words rate of disintegration is proportional to no of radioactive atoms present . As number reduces rate also reduces .
Let initial no of radioactive be N₀ and after time t , number reduces to N
N₀ / N = 6.68 / .97
Now
[tex]N=N_0e^{-\lambda t}[/tex]
[tex]\frac{N}{N_0} =e^{-\lambda t}[/tex]
[tex]\frac{6.68}{.97} = e^{\lambda t}[/tex]
λ is disintegration constant
λ = .693 / half life
= .693 / 5568
= .00012446 year⁻¹
Putting the values in the equation above
[tex]\frac{6.68}{.97} = e^{.00012446\times t}[/tex]
[tex]6.8866 = e^{.00012446\times t}[/tex]
1.929577 = .00012446 t
t = 15503.6 years .
what is the meaning of the word tetraquark?
Answer:
A tetraquark in physics is an exotic meson composed of four valence quarks.
Explanation:
It has been suspected to be allowed by quantum chromodynamics, the modern story of strong interactions.
Hope it helps.
After the reaction between sodium borohydride and the ketone is complete, the reaction mixture is treated with water and H2SO4 to produce the desired alcohol. Explain the reaction by clearly indicating the source of the hydrogen atom that ends up on the oxygen
Answer:
The hydrogen can be gotten from the added Acid or water during "workup".
Explanation:
Basically we can say that the reaction describe in this question is a Reduction reaction because of the chemical compound called sodium borohydride. In the reaction described above we can see that there is a Reduction of ketone to alcohol by the compound; sodium borohydride.
For the reduction Reaction to occur the C-O bond must break so as to enable the formation of O-H bond and C-H bond.
So, "the reaction mixture is treated with water and H2SO4 to produce the desired alcohol", thus, the oxygen will definitely pick up the hydrogen from H2SO4 or H2O.
below are three reactions showing how chlorine from CFCs (chlorofluorocarbons) destroy ozone (O3) in the stratosphere. Ozone blocks harmful ultraviolet radiation from reaching earth’s surface. Show how these 3 equations sum to produce the net equation for the decomposition of two moles of ozone to make three moles of diatomic oxygen (2 O3→ 3 O2), and calculate the enthalpy change. (6 points) R1 O2 (g) → 2 O (g) ΔH1°= 449.2 kJ R2 O3 (g) + Cl (g) → O2 (g) + ClO (g) ΔH2° = -126 kJ R3 ClO (g) + O (g) → O2 (g) + Cl (g) ΔH3°= -268 kJ
Answer:
ΔH = -338.8kJ
Explanation:
it is possible to sum the enthalpy changes of some reactions to obtain the enthalpy change of the whole reaction (Hess's law).
Using the reactions:
R₁ O₂(g) → 2O(g) ΔH₁°= 449.2 kJ
R₂ O₃(g) + Cl(g) → O₂(g) + ClO(g) ΔH₂° = -126 kJ
R₃ ClO (g) + O (g) → O₂ (g) + Cl (g) ΔH₃°= -268 kJ
By the sum 2R₂ + 2R₃:
(2R₂ + 2R₃) = 2O(g) + 2O₃(g) → 4O₂(g)
ΔH = 2ₓ(-126kJ) + (2ₓ-268kJ) = -788kJ
Now, this reaction + R₁
2O₃(g) → 3O₂(g)
ΔH = -768kJ + 449.2kJ
ΔH = -338.8kJNeed help finding major products
Answer:
Explanation:
RX + AgNO₃ = R⁺ ( carbocation ) + AgX + NO₃⁻
C₂H₅OH ( a nucleophile ) + R⁺ = ROC₂H₅
C₅H₁₁X + AgNO₃ = C₅H₁₁⁺ + AgX + NO₃⁻
In the first case carbocation produced is CH₃CH₂CH₂CH₂CH₂⁺
CH₃CH₂CH₂CH₂CH₂⁺ ⇒ CH₃CH₂CH₂C⁺HCH₃ ( secondary carbocation more stable )
CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃
Hence option D is correct .
b )
In the second case carbocation produced is
CH₃CH₂CH₂CH⁺CH₃
CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃
The product formed is same as in case of first
Option B is correct
A radioactive isotope of mercury, 197Hg, decays togold, 197Au, with a disintegration constant of 0.0108 h-1. What fraction of a sample will remain at the end of three half-lives (
Answer:
THE FRACTION OF THE SAMPLE REMAINING AFTER THREE HALF LIVES IS 0.125 OR 125/1000
Explanation:
A radioactive isotope of mercury decay to gold with a disintegration constant of 0.0108 h^-1
To calculate the fraction of sample remaining after three half life, we first calculate the half life of the decay.
Half life = ln 2 / Y
Y = disintegration constant
So therefore,
half life = ln 2 / 0.0108
half life = 0.693 / 0.0108
half life = 64.18 hours.
So a decay occurs after 64.18 hours.
To calculate the fraction remaining after 3 half life:
N(t) = N(o) e ^-Yt
where t = 3 half life
So, N / No = e^-Y ( 3 t1/2)
Since t 1/2 = ln 2 / Y, so we can re-write the formula as:
Nt / No = e^-Y ( 3 ln 2/ Y)
Nt / No = e^-3 ln2
Nt / No = e^-3 * 0.693
Nt / No = e^-2.079
Nt / No = 0.125
So the fraction of the sample remaining after 3 half lives is 125/ 1000 or 0.125
Select the correct answer. A certain reaction has this form: aA bB. At a particular temperature and [A]0 = 2.00 x 10-2 Molar, concentration versus time data were collected for this reaction and a plot of ln[A]t versus time resulted in a straight line with a slope value of -2.97 x 10-2 min-1. What is the half-life of this reaction? A. 23.33 seconds B. 0.043 minutes C. 0.0043 seconds D. 23.33 minutes E. 1680 minutes
Answer:
[tex]\large \boxed{\text{D. 23.34 min}}[/tex]
Explanation:
1. Find the order of reaction
Use information from the graph to find the order.
If a plot of ln[A] vs time is linear, the reaction is first order and the slope = -k.
2. Find the half-life
[tex]k = \dfrac{\ln2}{ t_{\frac{1}{2}}}\\\\k = \text{-slope} = -(-2.97 \times 10^{-2} \text{ min}^{-1}) =2.97 \times 10^{-2} \text{ min}^{-1} \\ t_{\frac{1}{2}} =\dfrac{\ln 2}{k} = \dfrac{\ln 2}{2.97 \times 10^{-2}\text{ min}^{-1}} =\textbf{23.34 min}\\\\\text{The half-life is $\large \boxed{\textbf{23.34 min}}$}[/tex]
The half life of the reaction is 23.33 minutes.
We know that for a first order reaction;
ln[A]t = ln[A]o - kt
A plot of ln[A]t against time (t) will yield a straight line graph with a slope of -k.
From the question, the slope is -2.97 x 10-2 min-1.
So, -2.97 x 10-2 min-1 = - k
k = 2.97 x 10-2 min-1
The half life of a first order reaction is obtained from;
t1/2 = 0.693/k
t1/2 = 0.693/2.97 x 10-2 min-1
t1/2 = 23.33 minutes
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Identify a process that is NOT reversible. A. melting of steel B. freezing water C. melting of ice D. frying an egg E. deposition of carbon dioxide (gas to solid)
A process that is not a reversible reaction is frying an egg.
What are reversible reactions?Reversible reactions are those reactions in which product will again change into the reactant.
Melting of steel and ice are reversible reaction as after cooling again we get the original state of steel and ice.Freezing of water is also reversible reaction as at normal temperature we get the original state of water.Deposition of carbon dioxide is also a reversible reaction.Frying an egg is a non reversible reaction as after frying an egg we didn't get the original egg again.Hence option (D) is correct.
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A chemistry student weighs out of chloroacetic acid into a volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with solution. Calculate the volume of solution the student will need to add to reach the equivalence point. Round your answer to significant digits.
Answer:
11.6mL of the 0.1400M NaOH solution
Explanation:
0.154g of chloroacetic acid diluted to 250mL. Titrated wit 0.1400M NaOH solution.
The reaction of chloroacetic acid, ClCH₂COOH (Molar mass: 94.5g/mol) with NaOH is:
ClCH₂COOH + NaOH → ClCH₂COO⁻ + Na⁺ + H₂O
Where 1 mole of the acid reacts per mole of the base.
That means the student will reach equivalence point when moles of chloroacetic acid = moles NaOH.
You will titrate the 0.154g of ClCH₂COOH. In moles (Using molar mass) are:
0.154g ₓ (1mol / 94.5g) = 1.63x10⁻³ moles of ClCH₂COOH
To reach equivalence point, the student must add 1.63x10⁻³ moles of NaOH. These moles comes from:
1.63x10⁻³ moles of NaOH ₓ (1L / 0.1400moles NaOH) = 0.0116L of the 0.1400M NaOH =
11.6mL of the 0.1400M NaOH solutionCalculate the maximum wavelength of light that will cause the photoelectric
effect for potassium. Potassium has work function 2.29 eV = 3.67 x 10-19 J.
Answer:
Explanation:
Work function of potassium = 2.29 eV = 3.67 X 10⁻¹⁹ J
So the minimum energy of photon must be equal to 3.67 X 10⁻¹⁹ J .
energy of photon of wavelength λ = hc / λ
where h = 6.67 x 10⁻³⁴
c = 3 x 10⁸
Putting the values in the equation above
6.67 x 10⁻³⁴ x 3 x 10⁸ / λ = 3.67 X 10⁻¹⁹
λ = 6.67 x 10⁻³⁴ x 3 x 10⁸ / 3.67 X 10⁻¹⁹
= 5.452 x 10⁻⁷
= 5452 x 10⁻¹⁰ m
= 5452 A .
A student obtained a clean flask. She weighed the flask and stopper on an analytical balance and found the total mass to be 34.232 g. She then filled the flask with water and found the new mass to be 60.167 g. The temperature of the water was measured to be
Answer:
25.99mL is the volume internal volume of the flask
Explanation:
To complete the question:
The temperature of the water was measured to be 21ºC. Use this data to find the internal volume of the stoppered flask
The flask was filled with water, that means the internal volume of the flask is equal to the volume that the water occupies.
To find the volume of the water you need to find the mass and by the use of density of water at 21ºC (0.997992g/mL), you can find the volume of the flask, thus:
Mass water = Mass filled flask - Mass of clean flask
Mass water = 60.167g - 34.232g
Mass water = 25.935g of water.
To convert this mass to volume:
25.935g × (1mL / 0.997992g) =
25.99mL is the volume internal volume of the flaskHydrogen iodide decomposes according to the equation: 2HI(g) H 2(g) + I 2(g), K c = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of HI at equilibrium.
Answer:
[HI] = 0.264M
Explanation:
Based on the equilibrium:
2HI(g) ⇄ H₂(g) + I₂(g)
It is possible to define Kc of the reaction as the ratio between concentration of products and reactants using coefficients of each compound, thus:
Kc = 0.0156 = [H₂] [I₂] / [HI]²
As initial concentration of HI is 0.660mol / 2.00L = 0.330M, the equlibrium concentrations will be:
[HI] = 0.330M - 2X
[H₂] = X
[I₂] = X
Where X is reaction coefficient.
Replacing in Kc:
0.0156 = [X] [X] / [0.330M - 2X]²
0.0156 = X² / [0.1089 - 1.32X + 4X² ]
0.00169884 - 0.020592 X + 0.0624 X² = X²
0.00169884 - 0.020592 X - 0.9376 X² = 0
Solving for X:
X = - 0.055 → False solution, there is no negative concentrations
X = 0.0330 → Right solution.
Replacing in HI formula:
[HI] = 0.330M - 2×0.033M
[HI] = 0.264MHow many milliliters of 0.0850 M NaOH are required to titrate 25.0 mL of 0.0720 M hydrobromic acid, HBr, to the equivalence point?
Answer:
21.2 mL
Explanation:
Step 1: Write the balanced equation.
NaOH + HBr ⇒ NaBr + H₂O
Step 2: Calculate the reacting moles of HBr
25.0 mL of 0.0720 M hydrobromic acid react.
[tex]0.0250 L \times \frac{0.0720mol}{L} = 1.80 \times 10^{-3} mol[/tex]
Step 3: Calculate the reacting moles of NaOH
The molar ratio of NaOH to HBr is 1:1. The reacting moles of NaOH are 1/1 × 1.80 × 10⁻³ mol = 1.80 × 10⁻³ mol.
Step 4: Calculate the required volume of NaOH
[tex]1.80 \times 10^{-3} mol \times\frac{1,000mL}{0.0850mol} = 21.2 mL[/tex]
Write the equilibrium constant expression for the experiment you will be studying this week. 2. If the equilibrium values of Fe3+, SCN- and FeSCN2+ are 9.5 x 10-4 M, 3.6 x 10-4 M and 5.7 x 10-5 M respectively, what is the value of Kc? 3. Write the general form of the dilution equation. 4. A solution is prepared by adding 18 mL of 0.200 M Fe(NO3)3 and 2 mL of 0.0020 M KSCN. Calculate the initial concentrations of Fe3+ and SCNin the solution.
Answer:
Kc = 166.7
[Fe³⁺] = 0.18 M
[SCN⁻] = 2×10⁻⁴ M
Explanation:
In the reaction of Fe³⁺ and SCN⁻, it is formed a complex:
Fe³⁺ + SCN⁻ ⇄ FeSCN²⁺ Kc
Let's make the expression for Kc → [FeSCN²⁺] / [Fe³⁺] . [SCN⁻]
5.7×10⁻⁵ / 9.5×10⁻⁴. 3.6×10⁻⁴ = 166.7
We determine the mmoles, we add from each reactant:
18 ml . 0.2M = 3.6 mmoles of Fe³⁺
2 ml . 0.002M = 4×10⁻³ mmoles of SCN⁻
General form of the dilution equation is:
Concentrated [C] . Concentrated Volume = Diluted [C] . Diluted Volume
Total volume = 20mL
[Fe³⁺]: 3.6 mmoles /20mL = 0.18 M
[SCN⁻]: 4×10⁻³ mmoles /20mL = 2×10⁻⁴ M
The value should be 1.67 x 10^2
The initial concentration should be 0.18 M and 2.0 x 10^(-4) M
Calculation of the value and initial concentration:The value is
= 5.7 x 10^(-5)/(9.5 x 10^(-4) x 3.6 x 10^(-4))
= 167
= 1.67 x 10^2
we know that
Initial moles = volume x concentration
So,
= 18/1000 x 0.200
= 0.0036 mol
Now
Initial moles = volume x concentration
= 2/1000 x 0.0020
= 4.0 x 10^(-6) mol
So,
Total volume should be
= 18 + 2
= 20 mL
= 0.02 L
Now
Initial concentration
= moles /total volume
= 0.0036/0.02
= 0.18 M
Now
Initial concentration
= moles /total volume
= 4.0 x 10^(-6)/0.02
= 2.0 x 10^(-4) M
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What was one idea Dalton taught about atoms?
A. Atoms contained negatively charged particles scattered inside.
B. Atoms of one type would not react with atoms of another type.
C. All atoms of one type were identical in mass and properties.
D. Atoms changed into new elements when they formed compounds.
Answer:
C
Explanation:
I had this question and C is the right answer
One idea that Dalton taught about atoms was that all atoms of one type were identical in mass and properties.
What is an atom?
An atom is defined as the smallest unit of matter which forms an element. Every form of matter whether solid,liquid , gas consists of atoms . Each atom has a nucleus which is composed of protons and neutrons and shells in which the electrons revolve.
The protons are positively charged and neutrons are neutral and hence the nucleus is positively charged. The electrons which revolve around the nucleus are negatively charged and hence the atom as a whole is neutral and stable due to presence of oppositely charged particles.
Atoms of the same element are similar as they have number of sub- atomic particles which on combination do not alter the chemical properties of the substances.
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A reaction is performed in a lab whereby two solutions are mixed together. The products are a liquid and a solid precipitate. What procedures would facilitate measurement of actual yield of the solid
Answer:
filtration, drying, and weighing
Explanation:
The procedures that would facilitate the measurement of the actual yield of the solid would be filtration of the precipitate, drying of the precipitate, and weighing of the precipitate respectively.
The liquid/solid mixture resulting from the reaction can be separated by the process of filtration using a filter paper. The residue in the filter paper would be the solid while the filtrate would be the liquid portion of the reaction's product.
The residue can then be allowed to dry, and then weighed using a laboratory-grade weighing balance. The weight of the solid represents the actual yield of the solid.
Water (2190 g ) is heated until it just begins to boil. If the water absorbs 5.83×105 J of heat in the process, what was the initial temperature of the water?
Answer:
The initial temperature was [tex]36.4^\circ \:C[/tex]
Explanation:
[tex]\Delta t=\frac{q}{m\cdot C_s}=\frac{5.83\times10^5}{2190\times 4.184}\\\\=63.6^\circ\:C[/tex]
The temperature difference [tex]=100-63.6=36.4^\circ\:C[/tex]
Best Regards!
Give the formulas for all of the elements that exist as diatomic molecules under normal conditions. See if you can do this without looking anything up.
Answer:
They are:
H2, N2, O2, F2, Cl2, Br2, and I2.
Note: whether the element At molecule is monoatomic or diatomic is incredibly arguable. While some say it exists as diatomic because it is a halogen like bromine, iodine etc, At is in fact extremely unstable and no one has ever really studied the molecules on it, so, when others say it is monoatomic, this is also based on calculations. But the other 7 elements listen above is for sure diatomic.
Hydrogen (H2) , Nitrogen (N2) , Oxygen (O2) , Fluorine (F2) , Chlorine (Cl2) , Iodine (I2) , carbonmonoxide (CO) and Bromine (Br2).
Hydrogen (H2) , Nitrogen (N2) , Oxygen (O2) , Fluorine (F2) , Chlorine (Cl2) , Iodine (I2) , carbonmonoxide (CO) and Bromine (Br2) are the formulas of the elements that is present as diatomic molecules under normal environmental conditions. Diatomic molecules refers to those molecules that is composed of only two atoms of the same or different elements. There are large number of diatomic molecules which is made up of two similar elements or different elements.
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