Electrophilic aromatic substitution of furan favors addition to the 2-position because the intermediate cation is more stable than addition to the 3-position. Draw the mechanism arrows for the Friedel-Crafts acylation of furan. In steps 1-3 draw the curved arrows to show the formation of the acyliumion electrophile and acylation of furan. In steps 4 and 5 draw all resonance structures for the intermediate cation, then showing reaction of the last resonance structure with FeCl4 to generate the final product. Make sure to draw lone pairs of electrons for all species and nonzero formal charges.

Answers

Answer 1

Answer:

See picture below

Explanation:

In the attached picture, you have the mechanism of all this reaction.

In the first step, as this is Friedel Craft acylation, we need to use either AlCl₃ or FeCl₃. So, this compound (I will use FeCl₃) will attach to the Chlorine group of the CH₃COCl.

In the second step, the whole CH₃CO is attached to the furan, because of the attack of the double bond of the ring.

After this, it occurs several resonance structure, to give a more stable structure, and the Hydrogen in the 2 position is substracted to give the final product of acylation.

Hope this helps.

Electrophilic Aromatic Substitution Of Furan Favors Addition To The 2-position Because The Intermediate

Related Questions

Calculate the molar mass of ZnCr04

Answers

Answer:

181.403 g/mol is the answer as it is Zinc chromate

Explanation:

Answer:

181.403 g/mol

Explanation:

Molar mass of ZnCrO4 = 181.3737 g/mol. This compound is also known as Zinc Chromate. Convert grams ZnCrO4 to moles or moles ZnCrO4 to grams. 65.38 + 51.9961 + 15.9994*4

True or false: to get 8 valence electrons, oxygen can borrow or share some electrons

Answers

Answer:

True

Explanation:

In ionic compounds, oxygen borrows electrons. In covalent compounds, oxygen shares electrons.

Which of the following statements is true?

Answers

Answer:

option first is right answer

When you draw a bow'across a violin string, which kind of wave is created in
the air surrounding the string?
A. surface
B. electromagnetic
C. longitudinal
D. Transverse

Answers

Answer:

C

Explanation:

Answer: C. Longitudinal

Explanation: A P 3 X

9. How much power is flowing into your house if the voltage is 120 V and the current is 50 A? Use the formula P = VI.

O A. 1200 Watts
O B. 240 Watts
O C. 6000 Watts
O D. 4800 Watts

Answers

4800 mannnnnnnnnnnnnn

If you had 6H2 molecules and 4O2 molecules, how many H2O molecules could you produce?

Answers

Answer:

6

Explanation:

As , 2H2 + O2 = 2H2O

with 6 H2, 4O2 is excess.

H2O molecules formed = 6

Which of the following statements is a true statement regarding a solution with [H1+] =1x10-5 M and [OH1-]= 1x10-9 M?

A. The [H1+] > [OH1-] and the solution is basic
B. The [H1+] >[OH1-] and the solution is acidic
C. The [OH1-] > [H1+] and the solution is basic
D. The [OH1-] > [H1+] and the solution is acidic

Answers

Answer:

B. The [H1+] >[OH1-] and the solution is acidic

Ionisation enthalpy across the group (increase or decrease)

Give reasons??​

Answers

Answer:

As we move from left to right across a period, the ionization energy of elements increases. This is due to the decrease in the size of atoms across a period.

Answer:

[tex]\huge\boxed{Answer\hookleftarrow}[/tex]

Ionization enthalpy (IE) is the energy required to remove the highest-energy electron from a neutral atom. In general, ionization energy increases across a period and decreases down a group.So, for your question IE decreases down the group.

____________________

ʰᵒᵖᵉ ⁱᵗ ʰᵉˡᵖˢ

# ꧁❣ RainbowSalt2²2² ࿐

What is biocapacity?

PLZZ HELP TY

Answers

Answer:

Explanation:

The biocapacity or biological capacity of an ecosystem is an estimate of its production of certain biological materials such as natural resources, and its absorption and filtering of other materials such as carbon dioxide from the atmosphere.

Answer: the capacity to produce biological materials and absorb wastes materials by or from humans in an ecosystem

Identify the most and the least acidic compound in each of the following sets. Leave the remaining answer in each set blank. a) 2,4-dinitrobenzoic acid: _______ p-nitrobenzoic acid: _______ p-bromobenzoic acid: _______ b) oxalic acid: _______ acetic acid: _______ formic acid: _______ c) p-cyanobenzoic acid: _______ benzoic acid: _______ p-aminobenzoic acid:

Answers

Answer:

a) 2,4-dinitrobenzoic acid: the most acidic compound, p-nitrobenzoic acid: _______, p-bromobenzoic acid: the least acidic compound

b) oxalic acid: the most acidic compound, acetic acid: the least acidic compound, formic acid: _______.

c) p-cyanobenzoic acid: the least acidic compound, benzoic acid: the most acidic compound, p-aminobenzoic acid: _______.

Explanation:

a) 2,4-dinitrobenzoic acid is the most acidic compound of this set because it has two strong electronegative substituents (nitrogen dioxide) which increases the acidity of benzoic acid, while p-bromobenzoic acid is the least acidic compound because bromine is a weaker electron withdrawing group than nitrogen dioxide.

b) The presence of 2 -COOH group makes Oxalic acid the most acidic compound of this set, while decrease in acidity of carboxylic acid due to the presence of methyl group on carbon of -COOH group makes acetic acid the least acidic compound of this set.  

(c) Benzoic acid has a higher acid dissociation constant value (4.45 Ka) therefor it is the most acidic compound of this set, while p-cyanobenzoic acid is the least acidic compound of this set as it has the least acid dissociation constant value (16 Ka).

What is the molarity of a solution in which 0.257 moles of HNO2 is dissolved in 490ml of water?

Answers

2.00 = 550xl in cash

0.52 molar is the molarity of a solution in which 0.257 moles of HNO2 is dissolved in 490ml of water.

What do you mean by the term molarity ?

The term molarity is defined as the number of moles of solutes are dissolved in per litre of solution. It is represented by the symbol "M". The unit of molarity is molar(M).

To calculate the molarity of a solution, divide the moles of solute by the volume of the solution expressed in liters.

The formula of molarity = a number of moles of solutes /  litre of solution

Given:

Number of moles = 0.257 moles

Volume = 490ml = 0.49 litre

Molarity = ?

According to the definition of molarity,

Molarity = Number of moles of solute / litre of solution

Molarity =  0.257 moles / 0.49 litre

Molarity = 0.52 molar

Thus, the molarity of a solution in which 0.257 moles of HNO2 is dissolved in 490ml of water is 0.52 molar.

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Ammonia is produced by the Haber process. The equation is shown.

N2 (g) + 3H2 (g) ⇔ 2NH3 (g)

The forward reaction is exothermic.

Which statement is correct?



Increasing pressure decreases the yield of ammonia, but speeds up the reaction.



Increasing temperature decreases the yield of ammonia, but speeds up the reaction.



Increasing the concentration of hydrogen and nitrogen results in a lower yield of ammonia.



Increasing the temperature increases the yield of ammonia and speeds up the reaction.

Answers

Answer:

option D

Explanation:

Increasing the temperature increases the yield of ammonia and speeds up the reaction as chemical reaction is affected by temperature.

Answer:

increasing the temperature decreases the yield of ammonia but speeds up the reaction

Explanation:

first pressure have no effect in chemical reaction

8. Write the formulas for and give the names of
the compounds formed by the following ions:
a. Cr2+ and F
b. Ni2+ and 02-
c. Fe3+ and 02-

Answers

Answer is c...............

Unit: Stoichiometry
"Multi-Step Problems" â WS #3
Directions: Use dimensional analysis to perform the following calculations. Be sure to show all of your work, include your units, and round your answers to the correct number of significant figures. How many formula units of sodium nitrate will react with 20.0 g of calcium carbonate to product sodium carbonate and calcium nitrate according to the following reaction?
2 Na(NO3) + Ca(CO3) à Na2(CO3) + Ca(NO3)2
What volume of oxygen is produced at STP when 6.58 x 1024 molecules of water is decomposed according to the following reaction? 2 H2O à 2 H2 + O2
How many liters of nitrogen gas are needed to react with 90.0 g of potassium at STP in order to produce potassium nitride according to the following reaction? 6 K + N2 à 2 K3N

Answers

Answer:

1. 2.41 × 1023 formula units

2. 122 L

3. 7.81 L

Explanation:

1. Equation of the reaction: 2 Na(NO3) + Ca(CO3) ---> Na2(CO3) + Ca(NO3)2

Mole ratio of NaNO3 to CaCO3 = 2 : 1

Moles of CaCO3 = mass/molar mass

Mass of CaCO3 = 20 g; molar mass of CaCO3 = 100 g

Moles of CaCO3 = 20 g/100 g/mol = 0.2 moles

Moles of NaNO3 = 2 × 0.2 moles = 0.4 moles

1 Mole of NaNO3 = 6.02 × 10²³ formula units

0.4 moles of NaNO3 = 0.4 × 6.02 × 10²³ = 2.41 × 1023 formula units

2. Equation of reaction : 2 H2O ----> 2 H2 + O2

Mole ratio of oxygen to water = 1 : 2

At STP contains 6.02 × 10²³ molecules = 1 mole of water

6.58 × 10²⁴ molecules = 6.58 × 10²⁴ molecules × 1 mole of water/ 6.02 × 10²³ molecules = 10.93 moles of water

Moles of oxygen gas produced = 10.93÷2 = 5.465 moles of oxygen gas

At STP, 1 mole of oxygen gas = 22.4 L

5.465 moles of oxygen gas = 5.465 moles × 22.4 L/1 mole = 122 L

3.Equation of reaction: 6 K + N2 ----> 2 K3N

Mole ratio of Nitrogen gas and potassium = 6 : 1

Moles potassium = mass/ molar mass

Mass of potassium = 90.0 g, molar mass of potassium = 39.0 g/mol

Moles of potassium = 90.0 g / 39.0 g/mol = 2.3077moles

Moles of Nitrogen gas = 2.3077 moles / 6 = 0.3846 moles

At STP, 1 mole of nitrogen gas = 22.4 L

0.3486 moles of oxygen gas = 0.3486 moles × 22.4 L/1 mole = 7.81 L

1. Volume of oxygen 2.41 × 1023   units

2. Nitrogen gas 122 L

3. 7.81 L

What will be the volume of oxygen and nitrogen?

Equation of the reaction:

[tex]\rm 2Na(No_3)+Ca(Co_3)---- > Na_2(Co_3)+Ca(No_3)_2[/tex]

[tex]NaNo_3\ and \ CaCo_3=\dfrac{2}{1}[/tex]

[tex]\rm Moles \ of \ CaCo_3=\dfrac{Mass}{Molar\ Mass}[/tex]

Mass of CaCO3 = 20 g; molar mass of CaCO3 = 100 g

[tex]\rm \ Moles \ of \ CaCo_3=\dfrac{20}{100} =0.2[/tex]

[tex]Moles \ of \ NaNo_3=2\times 0.2=0.4\ moles[/tex]

[tex]1\ mole\ of \ NaNo_3=6.02\times10^{23}[/tex]

0.4 moles of NaNO3 = [tex]0.4\times 6.02\times 10^{23}=2.41\times 10^{23}[/tex]  

2. Equation of reaction :[tex]2H_2o---- > 2H_2+o_2[/tex]  

The mole ratio of oxygen to water =  [tex]\dfrac{2}{1}[/tex]

At STP contains

 [tex]\dfrac{6.02\times 10^{24}\times 1 \ mole \ of \ water}{6.02\times 10^{23}} =10.93\ moles \ of \ water[/tex]

Moles of oxygen gas produced =

[tex]\dfrac{10.93}{2} =5.465\ Moles \ of \ oxygen \ gas[/tex]

At STP, 1 mole of oxygen gas = 22.4 L

5.465 moles of oxygen gas =    [tex]5.465\times 22.4=122\ L[/tex]  

3. Equation of reaction:

[tex]6k+N_2---- > 2K_3N[/tex]6

The mole ratio of Nitrogen gas and potassium =   [tex]\dfrac{6}{1}[/tex]

[tex]Moles\ of \ potassium = \dfrac{Mass}{Molar\ Mass}[/tex]

Mass of potassium = 90.0 g,

molar mass of potassium = 39.0 g/mol

[tex]Moles\ of \ potassium = \dfrac{90}{39}=2.3077\ moles[/tex]

[tex]Moles\ of \ Nitrogen = \dfrac{ 2.3077}{6}=0.3846\ moles[/tex]

At STP, 1 mole of nitrogen gas = 22.4 L

0.3486 moles of oxygen gas =

[tex]0.3486\times 22.4=7.81\ L[/tex]

Thus

1. Volume of oxygen 2.41 × 1023   units

2. Nitrogen gas 122 L

3. 7.81 L

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93 Points!!! Which of the following join together to form molecules?

Atoms
Organisms
Organs
Tissues

Answers

Answer:

Atoms

Explanation:

Atoms are the smallest thing meaning they form molecules which are made of atoms.

Also, your question is not 93 points but whatever lol.

Answer:

Atoms

Explanation:

I took the test

what is a characteristic of property acids pls help

Answers

Answer:

General Characteristics of Acids:

Sour taste (though you should never use this characteristic to identify an acid in the lab) Reacts with a metal to form hydrogen gas. Increases the H+ concentration in water. Donates H+ ions. Turns blue litmus indicator red.

ph>7
also turns blue litmus red

Which of the following polyatomic ions will form an ionic compound with a single sodium ion?

CO3 2-
HCO3 1-
SO4 2-
SO3 2-

Answers

Answer:

Option B, HCO3 1-

Explanation:

The valence of Sodium ion is +1 and the valence of HCO3 is -1. Thus, sodium ion has an extra electron to be donated to complete its outer shell  while HCO3 needs an electron to complete its outer shell

Hence Na will combine with HCO3 to form NaHCO3

Option B is correct

The polyatomic ion which will form an ionic compound with a single sodium ion is; HCO3 ¹-

In chemical bonding between ions;

The major criteria is a balance of charges within the compound formed.

As such, all polyatomic ions in the option are di-ionic except for HCO3 1- which can perfectly form an ionic compound with 1 single sodium ion.

Read more on ionic compounds:

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A popular classroom demonstration consists of filing notches into a new penny and soaking the penny in hydrochloric acid overnight. Because new pennies are made of zinc coated with copper, and hydrochloric acid dissolves zinc and not copper, the inside of the penny is dissolved by the acid, while the outer copper shell remains. Suppose a penny contains 2.5 g of zinc and is soaked in 20.0 mL of 6.0 M HCl. Calculate the concentra- tion of the HCl solution after all of the zinc has dissolved. Hint: The Zn from the penny is oxidized to Zn2

Answers

Answer:

[tex]HCl conc=2.2M[/tex]

Explanation:

From the question we are told that:

Mass of zinc [tex]Mass_{z_n}=2.5g[/tex]

Initial conc of HCl [tex]HConc_1=6.0M[/tex]

Initial volume of HCl [tex]Hvol_1=20.0mL[/tex]

Molar mass of zinc [tex]M_{Z_n}=65.38g/mol[/tex]

Generally the equation for reaction  is mathematically given by

[tex]2HCL+Zn\implies ZnCl_2 +H_2[/tex]

Generally the equation for moles of zinc [tex]m_{z_n}[/tex] is mathematically given by

[tex]m_{z_n}=\frac{Mass_{Z_n}}{M_{Z_n}}[/tex]

[tex]m_{z_n}=\frac{2.5g}{M_{65.38}}[/tex]

[tex]m_{z_n}=0.038molZn[/tex]

Generally the equation for moles of [tex]m_{HCl}[/tex] is mathematically given by

[tex]m_{HCl}=HConc_1*Hvol_1[/tex]

[tex]m_{HCl}=6.0M*20.0mL[/tex]

[tex]m_{HCl}=6.0M*20.0*10^{-3}L[/tex]

[tex]m_{HCl}=0.12\ mol\ HCl[/tex]

Generally the reacted moles of HCl [tex]HCl_[reacted][/tex] is mathematically given by

Since

Zn:HCl =1:2

Therefore

[tex]HCl_[reacted]=0.038*\frac{2}{1}[/tex]

[tex]HCl_[reacted]=0.076mol \ HCl[/tex]

Generally the moles of HCl after Zn oxidization X is mathematically given by

[tex]x=0.12-0.076[/tex]

[tex]x=0.044 mol HCl[/tex]

Generally the conc of hydrochloride acid X is mathematically given by

[tex]X=\frac{0.044}{0.020}[/tex]

[tex]X=2.2 M Hcl[/tex]

Therefore Conc of HCl

[tex]HCl conc=2.2M[/tex]

How many molecules are in 3 moles of CO2?
O A. 5.418 x 1024
OB. 1.806 x 1024
O C. 6.02 x 1024
O D. 1.806 x 1023

Answers

Answer:

1.806 × 10²⁴

Explanation:

The number of molecules can be found by using the formula

N = n × L

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

N = 3 × 6.02 × 10²³

We have the final answer as

1.806 × 10²⁴

Hope this helps you

Answer: OB. 1.806 x 1024

Explanation:


Mr. Ragusa asks Hassan to make silver crystals from the following reaction.
2AgNO3 + Cu --> Cu(NO3)2 + 2Ag
Mr. Ragusa gives Hassan 51 g of silver nitrate to conduct the experiment. Hassan gives Mr. Ragusa 20 g of
silver crystals. What was Hassan's percent yield for his experiment?
Please round your answer to 2 decimal places

Answers

Answer:

Percentage yield = 61.7%

Explanation:

We'll begin by writing the balanced equation for the reaction. This is illustrated:

2AgNO₃ + Cu —> Cu(NO₃)₂ + 2Ag

Next, we shall determine the mass of AgNO₃ that reacted and the mass of Ag produced from the balanced equation. This is illustrated below:

Molar mass of AgNO₃ = 108 + 14 + (16×3)

= 108 + 14 + 48

= 170 g/mol

Mass of AgNO₃ from the balanced equation = 2 × 170 = 340 g

Molar mass of Ag = 108 g/mol

Mass of Ag from the balanced equation = 2 × 108 = 216 g

SUMMARY:

From the balanced equation above,

340 g of AgNO₃ reacted to produce 216 g of Ag.

Next, we shall determine the theoretical yield of Ag. This can be obtained as follow:

From the balanced equation above,

340 g of AgNO₃ reacted to produce 216 g of Ag.

Therefore, 51 g of AgNO₃ will react to produce = (51 × 216)/340 = 32.4 g of Ag.

Thus, the theoretical yield of Ag is 32.4 g.

Finally, we shall determine the percentage yield of Ag. This can be obtained as follow:

Actual yield = 20 g

Theoretical yield = 32.4 g

Percentage yield =?

Percentage yield = Actual yield /Theoretical yield × 100

Percentage yield = 20 / 32.4 × 100

Percentage yield = 61.7%

What is the molarity of a solution that is made with 3 moles of Na and 2 L of water

Answers

Answer - 1.50 M Na

Explanation -

3.00 moles of Na over 2.00 L of water.

3.00/2.00 = 1.50 M Na

I cannot be entirely sure. But it's an educated guess.

If I have 100 mL of oil in a container and 100 mL of water in another
conta in er Which container wouldhave more mass?

Answers

Answer:

The answer is 200mL each amount have the same mass

Explanation:

100mL +100ML= 200mL mass in each container

Answer:

200ml

Explanation:

balance Al2O3 + NaOH + H2O = NaAl(OH)4

Answers

Answer:

Al₂O₃ + 2 NaOH + 3 H₂O = 2 NaAl(OH)₄

HELP !! Which statement describes a periodic trend of electronegativity?
A. Electronegativity increases from right to left across a period.
B. Electronegativity increases from left to right across a period.
C. Electronegativity increases from top to bottom of a group.
D. Electronegativity remains the same within a period.

Answers

Answer:

B

Explanation:

1. How many grams of potassium chloride (KCI)
can be dissolved at 10°C?

Answers

Answer:

At 10 ∘C , the solubility of potassium chloride is measured to be 31.2⋅g per 100⋅g of water.

Explanation:

names the process which takes place when a red litmus paper turns white when dropped into chlorine water​

Answers

Answer:

Chlorine gas bleaches the damp litmus (red or blue). Bleaching is an oxidation process.

Explanation:

Answer:

Chlorine gas bleaches the damp litmus (red or blue). Bleaching is an oxidation process. If you are considering the colour change only - refer to it as bleaching. If you are considering the reaction mechanism and how the chemicals which provide the colour are changed, then refer to it as oxidation.

Explanation:

Enter an equation showing how this buffer neutralizes added aqueous acid (HI). Express your answer as a chemical equation. Identify all of the phases in your answer.

Answers

Answer:

[tex]H^++NH_3\rightleftharpoons NH_4^+[/tex]

Explanation:

Hello there!

In this case, since the buffer is not given, we assume it is based off ammonia, it means the ammonia-ammonium buffer, whereas the ammonia is the weak base and the ammonium ion stands for the conjugate acid. In such a way, when adding HI to the solution, the base of the buffer, NH3, reacts with the former to promote the following chemical reaction:

[tex]H^++NH_3\rightleftharpoons NH_4^+[/tex]

Because the HI is totally ionized in solution so the iodide ion becomes an spectator one.

Best regards!

Answer:

the above answer is wrong

Explanation:

its really not but the mastering chemistry says it is

An aqueous solution was made by dissolving 0.543 g of an unknown, monoprotic acid into 25.00 mL of water in an Erlenmeyer flask. After an acid/base indicator was added, 41.21 mL of 0.150 M NaOH was used to reach the end point.
a)Find the molar mass of the acid.
b)Determine the identity of the acid based on the following data:

PLEASE HELP ME

Answers

Answer:

a. 87.8g/mol is the molar mass of the acid.

b. The answer is in the explanation.

Explanation:

To solve this question we must find the moles of the monoprotic acid using the reaction with NaOH (1mole of monoprotic acid reacts with 1 mole of NaOH). With the moles and the mass of the unknown we can find the molar mass.

Moles of NaOH added:

0.04121L * (0.150moles / L) = 6.1815x10⁻³ moles NaOH = Moles monoprotic acid

Molar mass is:

0.543g / 6.1815x10⁻³ moles = 87.8g/mol is the molar mass of the acid

b. I can't see the image you are giving because has a low resolution. But the identity of the acid can be obtained because the acid:

Has the same molar mass.

Is a monoprotic acid.

(a) The molecular mass of the unknown monoprotic acid will be 87.84 g/moles.

(b) The acid can be butyric acid, as it is a monoprotic and have mass near about 87.84 g/mol.

(a) The endpoint by the addition of NaOH has been reached when the monoprotic acid has been completely utilized. Since the NaOH has been monobasic. The moles of NaOH will be equal to the moles of acid.

Moles of NaOH = moles of acid

The molarity of NaOH = 0.15 M

Volume of NaOH = 41.21 ml

Molarity = [tex]\rm \dfrac{moles}{volume\;(L)}[/tex]

Moles = molarity [tex]\times[/tex] volume (L)

Moles of NaOH = 0.15 [tex]\times[/tex] 0.04121 L

Moles of NaOH = 0.00618 moles

Moles of NaOH = moles of acid

moles of acid = 0.00618 moles.

Mass of acid dissolved = 0.543 grams

Molecular weight of acid = [tex]\rm \dfrac{weight}{moles}[/tex]

Molecular weight of acid = [tex]\rm \dfrac{0.543}{0.006815}[/tex]

Molecular weight of acid = 87.84 g/moles.

(b) The acid with the molecular mass of 87.84 g/mol with being the monoprotic acid can be butyric acid. The butyric acid has a molecular weight of 88 g/mol.

For more information about monoprotic acid, refer to the link:

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Question 10.
Which of the following are agricultural implements?
(a) Seed drills
(b) Silos
(c) Harrow
(d) All of these​

Answers

D should be the correct answer. Hope that helps.

Plz answer very fast anyone knows

Answers

Answer:

probably the sun

.

Explanation:

because the sun's heat result to evaporation

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