Answer:
Partial pressure (Ar) = 316.1mmHg
Explanation:
In the mixture of Ar and H₂ you can find the total moles of both gases using general gas law and with the mass of the sample and molar weight of each gas find the mole fraction of Argon and thus, its partial pressure.
Moles of gases:
PV = nRT
P = 910.0mmHg ₓ (1atm / 760mmHg) = 1.1974atm
V = 1.66L
n = Moles gases
R = 0.082atmL/molK
T = 54.9°C + 273.15K = 328.05K
PV = nRT
1.1974atm*1.66L = n*0.082atmL/molK*328.05K
0.0739 moles = total moles of the sampleKnowing H₂ = 2.016g/mol and Ar = 39.948g/mol you can write:
1.13g = 2.016X + 39.948Y (1)
Where X = moles of hydrogen and Y = moles of Argon.
Also we can write:
0.0739moles = X + Y (2)
Total moles of the sample are moles of hydrogen + moles Argon
Replacing 2 in 1:
1.13g = 2.016(0.0739-Y) + 39.948Y
1.13 = 0.1564 - 2.016Y + 39.948Y
0.9736 = 37.932Y
0.02567 = Y = moles of Argon
As total moles are 0.0739moles, mole fraction of Ar in the sample are:
XAr = 0.02567mol / 0.0739mol
X Ar = 0.347
Last, partial pressure of Ar = X Ar * total pressure.
Partial pressure (Ar) = 0.347*910.0mmHg
Partial pressure (Ar) = 316.1mmHg
Draw the Lewis structure for methane (CH4) and ethane (C2H6) in the box below. Then predict which would have the higher boiling point. Finally, explain how you came to that conclusion.
Answer:
Ethane would have a higher boiling point.
Explanation:
In this case, for the lewis structures, we have to keep in mind that all atoms must have 8 electrons (except hydrogen). Additionally, each carbon would have 4 valence electrons, with this in mind, for methane we have to put the hydrogens around the carbon, and with this structure, we will have 8 electrons for the carbon. In ethane, we will have a bond between the carbons, therefore we have to put three hydrogens around each carbon to obtain 8 electrons for each carbon.
Now, the main difference between methane and ethane is an additional carbon. In ethane, we have an additional carbon, therefore due to this additional carbon, we will have more area of interaction for ethane. If we have more area of interaction we have to give more energy to the molecule to convert from liquid to gas, so, the ethane will have a higher boiling point.
I hope it helps!
The Lewis structure shows the valence electrons in a molecule. Ethane will have a higher boiling point than methane.
We can deduce the number of valence electrons in a molecule by drawing the Lewis structure of the molecule. The Lewis structure consists of the symbols of elements in the compound and the valence electrons in the compound.
We know that the higher the molar mass of a compound the greater its boiling point. Looking at the Lewis structures of methane and ethane, we cam see that ethane has a higher molecular mass (more atoms) and consequently a higher boiling point than methane.
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AB2AB2 has a molar solubility of 3.72×10−4 M3.72×10−4 M. What is the value of the solubility product constant for AB2AB2? Express your answer numerically.
Answer:
Ksp = 2.06x10⁻¹⁰
Explanation:
For AB₂. solubility product constant, Ksp, is written as follows:
AB₂(s) ⇄ A²⁺ + 2Br⁻
Ksp = [A²⁺] [Br⁻]²
Molar solubility represents how many moles of AB₂ are soluble per liter of solution. and is obtained from Ksp:
AB₂(s) ⇄ A²⁺ + 2Br⁻
AB₂(s) ⇄ X + 2X
where X are moles that are soluble (Molar solubility)
Ksp = [X] [2X]²
Ksp = 4X³As molar solubility of the salt is 3.72x10⁻⁴M:
Ksp = 4X³
Ksp = 4(3.72x10⁻⁴)³
Ksp = 2.06x10⁻¹⁰How many mL of calcium hydroxide are required to neutralize 25.0 mL of 0.50 M
nitric acid?
Answer:
6.5 mL
Explanation:
Step 1: Write the balanced reaction
Ca(OH)₂ + 2 HNO₃ ⇒ Ca(NO₃)₂ + 2 H₂O
Step 2: Calculate the reacting moles of nitric acid
25.0 mL of 0.50 M nitric acid react.
[tex]0.0250L \times \frac{0.50mol}{L} = 0.013 mol[/tex]
Step 3: Calculate the reacting moles of calcium hydroxide
The molar ratio of Ca(OH)₂ to HNO₃ is 1:2. The reacting moles of Ca(OH)₂ are 1/2 × 0.013 mol = 6.5 × 10⁻³ mol
Step 4: Calculate the volume of calcium hydroxide
To answer this, we need the concentration of calcium hydroxide. Since the data is missing, let's suppose it is 1.0 M.
[tex]6.5 \times 10^{-3} mol \times \frac{1,000mL}{1.0mol} = 6.5 mL[/tex]
Identify the elements that have the following abbreviated electron configurations.
A) [Ne] 3s23p5.
B) [Ar] 4s23d7.
C) [Xe] 6s1.
Answer:
A) Chlorine (Cl)
B) Cobalt (Co)
C) Caesium (Cs)
Hope this helps.
The abbreviated electron configurations that was given in the question belongs to
Chlorine (Cl)
Cobalt (Co)
Caesium (Cs) respectively.
Electronic configurations can be regarded as the electronic structure, which is the way an electrons is arranged in energy levels towards an atomic nucleus.The electron configurations is very useful when describing the orbitals of an atom in its ground state.To calculate an electron configuration, we can put the periodic table into sections, and this section will represent the atomic orbitals which is the regions that house the electrons. Groups one of the period table and two belongs to s-block, group 3 through 12 belongs to the d-block, while 13 to 18 can be attributed to p-block ,The rows that is found at bottom are the f-blockTherefore, electron configurations explain orbitals of an atom when it is in it's ground state.
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Limiting reagent problem. How many grams of H2O is produced from 40.0 g N2O4 and 25.0 g N2H4. N2O4 (l) + 2 N2H4 (l) → 3 N2 (g) + 4 H2O(g)
Answer:
28.13 g of H2O.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is illustrated below:
N2O4(l) + 2N2H4 (l) → 3N2(g) + 4H2O(g)
Next, we shall determine the masses of N2O4 and N2H4 that reacted and the mass of H2O produced from the balanced equation.
This is illustrated below:
Molar mass of N2O4 = (14x2) + (16x4) = 92 g/mol
Mass of N2O4 from the balanced equation = 1 x 92 = 92g
Molar mass of N2H4 = (14x2) + (4x1) = 32 g/mol
Mass of N2H4 from the balanced equation = 2 x 32 = 64 g
Molar mass of H2O = (2x1) + 16 = 18 g/mol
Mass of H2O from the balanced equation = 4 x 18 = 72 g
Summary:
From the balanced equation above,
92 g of N2O4 reacted with 64 g of N2H4 to produce 72 g of H2O.
Next, we shall determine the limiting reactant.
This can be obtained as follow:
From the balanced equation above,
92 g of N2O4 reacted with 64 g of N2H4.
Therefore, 40 g of N2O4 will react with = (40 x 64)/92 = 27.83 g of N2H4.
From the calculations made above, we can see that it will take a higher mass i.e 27.83 g than what was given i.e 25 g of N2H4 to react completely with 40 g of N2O4.
Therefore, N2H4 is the limiting reactant and N2O4 is the excess reactant.
Finally, we shall determine the mass of H2O produced from the reaction of 40.0 g of N2O4 and 25.0 g of N2H4.
In this case the limiting reactant will be used because it will produce the maximum amount of H2O as all of it is consumed in the reaction.
The limiting reactant is N2H4 and the mass of H2O produced can be obtained as follow:
From the balanced equation above,
64 g of N2H4 reacted to produce 72 g of H2O.
Therefore, 25 g of N2H4 will react to produce = (25 x 72)/64 = 28.13 g of H2O.
Therefore, 28.13 g of H2O were obtained from the reaction.
Draw a Lewis structure for one important resonance form of HBrO4 (HOBrO3). Include all lone pair electrons in your structure. Do not include formal charges in your structure.
Answer:
The Lewis structure is attached with the answer -
Explanation:
Lewis structure or Lewis dot diagram are diagrams or representation of showing the bonding between different or same atoms of a molecule in any and also shows lone pairs of electrons that may exist in the molecule as dots.
HBrO₄ is bromine oxoacid which is also known as perbromic acid. It is a unstable inorganic compound.
The Lewis structure is attached in form of image with representation of lone pairs of electrons.
What is the molar mass of a protein if a solution of 0.020 g of the protein in 25.0 mL of solution has an osmotic pressure of 0.56 torr at 25 ∘ C
Answer:
26.5 kD
Explanation:
Here we can apply the formula ∏ = iMRT, where ∏ = osmotic pressure = 0.56 - ( given ). This is only one part of the information we are given / can conclude in this case ....
i = van’t Hoff factor = 1 for a protein molecule,
R = gas constant = 62.36 L torr / K-mol,
T ( temperature in Kelvin ) = 25 + 273 - conversion factor C° + 273 = 298K
( Known initially ) ∏ = osmotic pressure = 0.56 torr
..... besides the part " M " in the formula, which we have no information on whatsoever, as we have to determine it's value.
_____
Substitute derived / known values to solve for M ( moles / liter ) -
∏ = iMRT
⇒ 0.56 = ( 1 )( M )( 62.36 )( 298 )
⇒ 0.56 = M( 18583.28 )
⇒ M = 0.56 / 18583.28 ≈ 0.00003013461 ....
_____
We know that M = moles / liter, so we can use this to solve for moles, and hence calculate the molar mass by the formula molar mass = g / mol -
M = mol / l
⇒ 0.00003013461 = 0.020 / 25 mL ( 0.025 L ),
0.020 / 0.025 = 0.8 g / L
⇒ 0.8 g = 0.00003013461 moles,
molar mass = 0.8 g / 0.00003013461 moles = 26,548 g / mol = 26.5 kD
Complete ionic equation K2CO3(aq)+2CuF(aq) → Cu2CO3(s)+2KF(aq) Examine each of the chemical species involved to determine the ions that would be present in solution. Be sure to consider both the coefficients and subscripts of the molecular equation, and then write this precipitation reaction in the form of a balanced complete ionic equation. Express your answer as a chemical equation including phases.
Answer:
2K+(aq) + CO3²¯(aq) + Ca^2+(aq) + 2F¯(aq) —› Cu2CO3(s) + 2K+(aq) + 2F¯(aq)
Explanation:
K2CO3(aq) + 2CuF(aq) → Cu2CO3(s) + 2KF(aq)
The complete ionic equation for the above equation can be written as follow:
In solution, K2CO3 and CuF will dissociate as follow:
K2CO3(aq) —› 2K+(aq) + CO3²¯(aq)
CuF(aq) —› Ca^2+(aq) + 2F¯(aq)
Thus, we can write the complete ionic equation for the reaction as shown below:
K2CO3(aq) + 2CuF(aq) —›
2K+(aq) + CO3²¯(aq) + Ca^2+(aq) + 2F¯(aq) —› Cu2CO3(s) + 2K+(aq) + 2F¯(aq)
When a solution is diluted with water, the ratio of the initial to final
volumes of solution is equal to the ratio of final to initial molarities
Select one:
True
-
When a solution is diluted with water, the ratio of the initial to final volumes of solution is equal to the ratio of final to initial molarities. The statement is True.
Concentration refers to the amount of a substance in a defined space. Another definition is that concentration is the ratio of solute in a solution to either solvent or total solution.
There are various methods of expressing the concentration of a solution.
Concentrations are usually expressed in terms of molarity, defined as the number of moles of solute in 1 L of solution.
Solutions of known concentration can be prepared either by dissolving a known mass of solute in a solvent and diluting to a desired final volume or by diluting the appropriate volume of a more concentrated solution (a stock solution) to the desired final volume.
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Carbon-14 has a half-life of 5720 years and this is a fast-order reaction. If a piece of wood has converted 75 % of the carbon-14, then how old is it?
Answer:
11445.8years
Explanation:
Half-life of carbon-14 = 5720 years
First we have to calculate the rate constant, we use the formula :
The accepted value of the number of Liters of gas in a mole is 22.4. List two possible reasons on why our experiment yielded a different value for the number of Liters in a mole of a gas.
Hint: Our experiment was conducted in July, in St. Paul, Minnesota.
Answer:
- Pressure in St. Paul, Minnesota
- Temperature in St. Paul, Minnesota
Explanation:
22.4 L or dm³ is the volume for a gas under Standard pressure and temperature conditions.
It is logically to say, that tempereature value at the day of the experiment was not 273.15 K, which is 32°F
We can say, that the pressure was not 1 atm. St Paul Minnesota has a minimum, but a little height, so the pressure differs by few figures from the standard pressure values.
We also have to mention, that 22.4 L is the value for the Ideal gases at standards conditions. Ideal gases does not exisist on practice, we always talk about real gases. Don't forget the Ideal Gases Law equation:
P . V = n . R . T
Pressure . Volume = number of moles . 0.082 L.atm /mol. K . 273.15K
Number of moles must be 1 at STP, to determine a volume of 22.4L
Drag each image to the correct location on the model. Each image can be used more than once. Apply the rules and principles of electron configuration to draw the orbital diagram of aluminum. Use the periodic table to help you.
Answer:
The answer to your question is given below.
Explanation:
Aluminium has atomic number of 13. Thus, the electronic configuration of aluminium can be written as:
Al (13) —› 1s² 2s²2p⁶ 3s²3p¹
The orbital diagram is shown on the attached photo.
Answer: screen shot
Explanation:
A sample of neon gas at a pressure of 0.609 atm and a temperature of 25.0 °C, occupies a volume of 19.9 liters. If the gas is compressed at constant temperature to a
volume of 12.7 liters, the pressure of the gas sample will be
atm.
Answer:
The pressure of the gas sample will be 0.954 atm.
Explanation:
Boyle's law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; conversely if the pressure decreases, the volume increases.
Boyle's law is expressed mathematically as:
Pressure * Volume = constant
o P * V = k
To determine the change in pressure or volume during a transformation at constant temperature, the following is true:
P1 · V1 = P2 · V2
That is, the product between the initial pressure and the initial volume is equal to the product of the final pressure times the final volume.
In this case:
P1= 0.609 atmV1= 19.9 LP2=?V2= 12.7 LReplacing:
0.609 atm* 19.9 L= P2* 12.7 L
Solving:
[tex]P2=\frac{0.609 atm* 19.9 L}{12.7 L}[/tex]
P2= 0.954 atm
The pressure of the gas sample will be 0.954 atm.
below are three reactions showing how chlorine from CFCs (chlorofluorocarbons) destroy ozone (O3) in the stratosphere. Ozone blocks harmful ultraviolet radiation from reaching earth’s surface. Show how these 3 equations sum to produce the net equation for the decomposition of two moles of ozone to make three moles of diatomic oxygen (2 O3→ 3 O2), and calculate the enthalpy change. (6 points) R1 O2 (g) → 2 O (g) ΔH1°= 449.2 kJ R2 O3 (g) + Cl (g) → O2 (g) + ClO (g) ΔH2° = -126 kJ R3 ClO (g) + O (g) → O2 (g) + Cl (g) ΔH3°= -268 kJ
Answer:
ΔH = -338.8kJ
Explanation:
it is possible to sum the enthalpy changes of some reactions to obtain the enthalpy change of the whole reaction (Hess's law).
Using the reactions:
R₁ O₂(g) → 2O(g) ΔH₁°= 449.2 kJ
R₂ O₃(g) + Cl(g) → O₂(g) + ClO(g) ΔH₂° = -126 kJ
R₃ ClO (g) + O (g) → O₂ (g) + Cl (g) ΔH₃°= -268 kJ
By the sum 2R₂ + 2R₃:
(2R₂ + 2R₃) = 2O(g) + 2O₃(g) → 4O₂(g)
ΔH = 2ₓ(-126kJ) + (2ₓ-268kJ) = -788kJ
Now, this reaction + R₁
2O₃(g) → 3O₂(g)
ΔH = -768kJ + 449.2kJ
ΔH = -338.8kJ11. How did the solubility product constant Ksp of KHT in pure water compare to its solubility product constant Ksp of KHT in KCl solution? Are these results what you would expect? Why?
Answer:
Explanation:
KHT is a salt which ionises in water as follows
KHT ⇄ K⁺ + HT⁻
Solubility product Kw= [ K⁺ ] [ HT⁻ ]
product of concentration of K⁺ and HT⁻ in water
In KCl solution , the solubility product of KHT will be decreased .
In KCl solution , there is already presence of K⁺ ion in the solution . So
in the equation
[ K⁺ ] [ HT⁻ ] = constant
when K⁺ increases [ HT⁻ ] decreases . Hence less of KHT dissociates due to which its solubility decreases . It is called common ion effect . It is so because here the presence of common ion that is K⁺ in both salt to be dissolved and in solvent , results in decrease of solubility of the salt .
When the following molecular equation is balanced using the smallest possible integer coefficients, the values of these coefficients are:
P2O5 (s) + H2O (l) =H3PO4 (aq)
The balanced chemical equation for the reaction between hydrogen sulfide and oxygen is:
2H2S(g) + 3O2(g) =2H2O(l) + 2SO2(g)
We can interpret this to mean:
3moles of oxygen and_______moles of hydrogen sulfide react to produce______moles of water and_______ moles of sulfur dioxide.
Answer:
1. The coefficients are: 1, 3, 2
2. From the balanced equation, we obtained the following:
3 moles oxygen, O2 reacted.
2 moles of Hydrogen sulfide, H2S reacted.
2 moles of water were produced.
2 moles of sulphur dioxide, SO2 were produced.
Explanation:
1. Determination of the coefficients of the equation.
This is illustrated below:
P2O5(s) + H2O(l) <==> H3PO4(aq)
There are 2 atoms of P on the left side and 1 atom on the right side. It can be balance by putting 2 in front of H3PO4 as shown below:
P2O5(s) + H2O(l) <==> 2H3PO4(aq)
There are 2 atoms of H on the left side and 6 atoms on the right side. It can be balance by putting 3 in front of H2O as shown below:
P2O5(s) + 3H2O(l) <==> 2H3PO4(aq)
Now the equation is balanced.
The coefficients are: 1, 3, 2.
2. We'll begin by writing the balanced equation for the reaction. This is given below:
2H2S(g) + 3O2(g) => 2H2O(l) + 2SO2(g)
From the balanced equation above,
3 moles of oxygen, O2 reacted with 2 moles of Hydrogen sulfide, H2S to produce 2 moles of water, H2O and 2 moles of sulphur dioxide, SO2.
cetylene gas is often used in welding torches because of the very high heat produced when it reacts with oxygen gas, producing carbon dioxide gas and water vapor. Calculate the moles of oxygen needed to produce of water.
Answer:
0.60 mol
Explanation:
There is some info missing. I think this is the original question.
Acetylene gas is often used in welding torches because of the very high heat produced when it reacts with oxygen gas, producing carbon dioxide gas and water vapor. Calculate the moles of oxygen needed to produce 1.5 mol of water.
Step 1: Given data
Moles of water required: 1.5 mol
Step 2: Write the balanced equation
C₂H₂(g) + 2.5 O₂(g) ⇒ 2 CO₂(g) + H₂O(g)
Step 3: Calculate the moles of oxygen needed to produce 1.5 mol of water
The molar ratio of O₂ to H₂O is 2.5:1. The moles of oxygen needed to produce 1.5 mol of water are (1/2.5) × 1.5 mol = 0.60 mol