Nitrosyl bromide, NOBr, is formed from NO and Br2.
2 NO(g) + Br2(g) 2 NOBr(g)
Experiments show the reaction is second order in NO and first order in Br2.
(a) What is the rate equation for the reaction?
rate = k[NO]2[Br2]
rate = k[NO][Br2]
rate = k[NO]2[Br2]2
rate = k[NO]2[Br]2

(b) How does the reaction rate change if the concentration of Br2 is changed from 0.0022 mol/L to 0.0066 mol/L?
the rate will double
the rate will remain unchanged
the rate will triple

(c) What is the change in the reaction rate if the concentration of NO is changed from 0.0024 mol/L to 0.0048 mol/L?
the rate will increase by a factor of 4
the rate will remain unchanged
the rate will also decrease by a factor of 1/2

Answer:

550 m/s

Explanation:

The average molecular speed (v) is the speed associated with a group of molecules on average. We can calculate it using the following expression.

[tex]v = \sqrt{\frac{3 \times R \times T}{M} }[/tex]

where,

We can use the info of argon to calculate the temperature for both samples.

[tex]T = \frac{v^{2} \times M}{3 \times R} = \frac{(391m/s)^{2} \times 39.95g/mol}{3 \times 8.314J/k.mol} = 2.45 \times 10^{5} K[/tex]

Now, we can use the same expression to find the average molecular speed in a sample of Ne gas.

[tex]v = \sqrt{\frac{3 \times R \times T}{M} } = \sqrt{\frac{3 \times (8.314J/k.mol) \times 2.45 \times 10^{5}K }{20.18g/mol} } = 550 m/s[/tex]

Answer:

D. Use x-ray radiation to see if there are any fractured bones.

Explanation:

The football player may have fractured a bone while he was practicing or playing, so it is best for the doctor to check if the player broke his bone or fractured it.

Answer:

[tex]14\\8[/tex]O

Explanation:

The top number always represents the mass number.

The bottom number always represents the atomic number.

The element always goes after the numbers.

If charge is present, that comes after the element.

Answer:

[tex]3Sr^{+2}+6Cl^{-}+6Li^{+}+2PO_{4}^{3-}-->Sr_{3}(PO_{4})_{2}+6Li^{+}+6Cl^{-}\\\\3Sr^{+2}+2PO_{4}^{3-} --->Sr_{3}(PO_{4})_{2}[/tex]

First equation is the complete ionic equation.

Second equation is the net ionic equation.

Answer:

Explanation:

We shall find out the molecular formula of the substance .

Ration of number of atoms of C , O and H

= [tex]\frac{37.48}{12} :\frac{49.93}{16} :\frac{12.58}{1}[/tex]

= 3.12 : 3.12 : 12.58

= 1 : 1 : 4

volume of gas at NTP

= 250 x 273 / 350 mL .

= 195 mL .

Molecular weight of the substance = .2804 x 22400 / 195 g

= 32. approx

Let the molecular formula be

(COH₄)n  

n x 32 = 32

n = 1

Molecular formula = COH₄

The compound appears to be CH₃OH

a )

CO + 2H₂ = CH₃OH

28g     4g          32g

59      8

For 8 kg hydrogen , CO required = 56 kg

CO is in excess .  hydrogen is the limiting reagent .

mass of product formed

= 32 x 8 / 4

= 64 kg

b )

percentage yield = product actually formed / product to be formed theoretically  x 100

= 59.6 x 100 / 64

= 93.12 %

c )

2CH₃OH + 3O₂ = 2CO₂ + 4H₂O .

64 g                     2 x 22.4 L

Gram of gas in 1 gallon of fuel

= .7914 x 3785

= 2995.5 g

CO₂ produced at NTP by 2995.5 g CH₃OH

= 2 x 22.4 x 2995.5 / 64 L

= 2096.85 L

At 27° C and 766 mm Hg , this volume is equal to

2096.85 x 300 x 760 / 273 x 766

= 2286.18  L .

d )

C₈H₁₈  =  8CO₂

114g           8 x 22.4 L

gram of fuel per unit gallon

= .6986 x 3785

= 2644.2g

gram of CO₂ produced by 1 gallon of fuel  at NTP

= 8 x 22.4 x 2644.2 / 114

= 4156.5 L

So it produces more CO₂ .

Answer:

143pm is the radius of an Al atom

Explanation:

In a face centered cubic structure, FCC, there are 4 atoms per unit cell.

First, you need to obtain the mass of an unit cell using molar mass of Aluminium  and thus, obtain edge length and knowing Edge = √8R you can find the radius, R, of an Al atom.

Mass of an unit cell

As 1 mole of Al weighs 26.98g. 4 atoms of Al weigh:

4 atoms × (1mole / 6.022x10²³atoms) × (26.98g / mole) = 1.792x10⁻²²g

Edge length

As density of aluminium is 2.71g/cm³, the volume of an unit cell is:

1.792x10⁻²²g × (1cm³ / 2.71g) = 6.613x10⁻²³cm³

And the length of an edge of the cell is:

∛6.613x10⁻²³cm³ = 4.044x10⁻⁸cm = 4.044x10⁻¹⁰m

Radius:

As in FCC structure, Edge = √8 R, radius of an atom of Al is:

4.044x10⁻¹⁰m = √8 R

1.430x10⁻¹⁰m = R.

In pm:

1.430x10⁻¹⁰m ₓ (1x10¹²pm / 1m) =

The radius of the atom of Al in the FCC structure has been 143 pm.

The FCC lattice has been contributed with atoms at the edge of the cubic structure.

The FCC has consisted of 4 atoms in a lattice.

[tex]\rm 6.023\;\times\;10^2^3[/tex] atoms = 1 mole

4 atoms = [tex]\rm \dfrac{4}{6.023\;\times\;10^2^3}[/tex] moles

The mass of 1 mole Al has been 26.98 g/mol.

The mass of [tex]\rm \dfrac{4}{6.023\;\times\;10^2^3}[/tex] moles = [tex]\rm \dfrac{4}{6.023\;\times\;10^2^3}[/tex] moles × 26.98 g

The mass of 1 unit cell of Al has been = 1.792 [tex]\rm \bold{\times\;10^-^2^2}[/tex] g.

Density = [tex]\rm \dfrac{mass}{volume}[/tex]

Volume = Density × Mass

The volume of Al unit cell = 2.71 g/[tex]\rm cm^3[/tex] × 1.792 [tex]\rm \times\;10^-^2^2[/tex] g

The volume of Al cell = 6.613 [tex]\rm \times\;10^-^2^3[/tex] [tex]\rm cm^3[/tex]

Volume = [tex]\rm edge\;length^3[/tex]

6.613 [tex]\rm \times\;10^-^2^3[/tex] [tex]\rm cm^3[/tex] = [tex]\rm edge\;length^3[/tex]

Edge length = [tex]\rm \sqrt[3]{6.613\;\times\;10^-^2^3}[/tex] cm

Edge length = 4.044 [tex]\rm \times\;10^-^8[/tex] cm

Edge length = 4.044 [tex]\rm \bold{\times\;10^-^1^0}[/tex] m.

Edge length = [tex]\rm \sqrt{8\;\times\;radius}[/tex]

4.044 [tex]\rm \bold{\times\;10^-^1^0}[/tex] m = [tex]\rm \sqrt{8\;\times\;radius}[/tex]

Radius = 1.430 [tex]\rm \bold{\times\;10^-^1^0}[/tex] m.

1 m = [tex]\rm 10^1^2[/tex] pm

1.430 [tex]\rm \bold{\times\;10^-^1^0}[/tex] m = 143 pm.

The radius of the atom of Al in the FCC structure has been 143 pm.

For more information about the FCC structure, refer to the link:

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Answer:

A. [OH⁻] = 2.188x10⁻³M

B. pKb = 6.02

Explanation:

When hydrazine is in equilbrium with water, its reaction is:

N₂H₄(aq) + H₂O(l) ⇄ HN₂H₄⁺(aq) + OH⁻(aq)

Where Kb, is defined as the ratio between concentrations in equilibrium of the species, thus:

Kb = [HN₂H₄⁺] [OH⁻] / [N₂H₄]

A. From pH, you can find [OH⁻], thus:

pH = -log [H⁺]

11.34 = -log [H⁺]

4.57x10⁻¹² = [H⁺]

As 1x10⁻¹⁴ = [OH⁻] [H⁺]

1x10⁻¹⁴ / 4.57x10⁻¹² = [OH⁻]

B. Concentrations in equilibrium of the species are:

[N₂H₄] = 5.0M - X

[HN₂H₄⁺] = X

[OH⁻] = X

Where X is reaction coordinate

As [OH⁻] = 2.188x10⁻³M

X = 2.188x10⁻³M

Replacing:

[N₂H₄] = 5.0M - 2.188x10⁻³M = 4.9978M

[HN₂H₄⁺] = 2.188x10⁻³M

[OH⁻] = 2.188x10⁻³M

Replacing in Kb expression:

Kb = [HN₂H₄⁺] [OH⁻] / [N₂H₄]

Kb = [2.188x10⁻³M] [2.188x10⁻³M] / [4.9978M]

Kb = 9.577x10⁻⁷

pKb is defined as -log Kb

pKb = -log 9.577x10⁻⁷

Answer:

WHEN 63.7 g OF K2SO4 IS DISSOLVED IN WATER, 0.73 MOLES OF POTASSIUM ION AND 0.366 MOLES OF SULFATE ION ARE FORMED.

Explanation:

Equation for the reaction:

K2SO4 + H20 ------->2 K+ + SO4^2-

When K2SO4 dissolves in water, potassium ion and sulfate ion are formed.

1 mole of K2SO4 produces 2 moles and 1 mole of SO4^2-

At STP, 1 mole of K2SO4 will be the molar mass of the substance

Molar mass of K2SO4 = ( 39 *2 + 32 + 16*4) g/mol

Molar mass = 174 g/mol

So therefore;

1 mole of K2SO4 contains 174 g and it produces 2 moles of potassium and 1 mole of sulfate ion

When 63.7 g is used; we have:

174 g = 2 moles of K+

63.7 g = ( 63.7 * 2 / 174) moles of K+

= 0.73 moles of K+

Forr sulfate ion, we have:

174 g = 1 mole ofSO4^2-

63.7 g = (63.7 * 1 / 174) moles of SO4^2-

= 0.366 moles of SO4^2-

In other words, when 63.7 g of K2SO4 is dissolved in water, 0.73 moles of potassium ion and 0.366 moles of sulfate ion are formed.

Answer:

The element is strontium and the number of neutrons it have is 51.

Explanation:

Based on the given information, the ionic compound is,  

XCl₂ ⇔ X₂⁺ + 2Cl⁻

X2+ is the ion of the mentioned element

As mentioned in the given question, the number of electrons of the element X is 36 and as seen from the reaction the charge present on the ion is +2. Now the atomic number will be,  

No. of electrons = atomic number - charge

36 = atomic number - 2

Atomic number = 38

Based on the periodic table, the atomic number 38 is for strontium element, and the sign of strontium is Sr. Hence, the element X is Sr.  

Now based on the given information, the mass number of the element is 89. Now the no. of neutrons will be,  

No. of neutrons = mass number - atomic number

= 89 - 38

= 51 neutrons.  

Answer:

a.

[tex]M_{Co^{2+}}=0.5M\\ \\M_{NO_3^{-}}=1.0M[/tex]

b.

[tex]M_{Fe^{3+}}=1.0M\\ \\M_{ClO_4^{-}}=3.0M[/tex]

Explanation:

Hello,

a. In this case, the ions are cobalt (II) and nitrate, for which, one mole of cobalt (II) nitrate contains one mole of cobalt (II) and two moles of nitrate (see subscripts), therefore, concentrations turn out:

[tex]M_{Co^{2+}}=0.5\frac{molCo(NO_3)_2}{L}* \frac{1molCo}{1molCo(NO_3)_2}=0.5M\\ \\M_{NO_3^{-}}=0.5\frac{molCo(NO_3)_2}{L}* \frac{2molNO_3^{-}}{1molCo(NO_3)_2}=1.0M[/tex]

b. In this case, the ions are iron (III) and chlorate, for which one mole of iron (III) is contained in one mole of iron (III) chlorate and three moles of chlorate are in one mole of iron (III) chlorate (see subscripts), therefore, the concentrations turn out:

[tex]M_{Fe^{3+}}=1.0\frac{molFe(ClO_4)_3}{L}* \frac{1molFe^{3+}}{1molFe(ClO_4)_3}=1.0M\\ \\M_{ClO_4^{-}}=0.5\frac{molFe(ClO_4)_3}{L}* \frac{3molClO_4^{-}}{1molFe(ClO_4)_3}=3.0M[/tex]

Regards.

Answer:

The correct answer is 0.00080 gram per liter.

Explanation:

Based on the given information, the solubility of water is 0.00380 gram per liter, the temperature mentioned is 25 degree C, the partial pressure of oxygen gas is 760 torr, and the mole fraction of oxygen is 0.210. There is a need to determine the solubility of oxygen in water.  

Based on Henry's law,  

Solubility of oxygen gas = Henry's constant × partial pressure of oxygen gas

Henry's constant, K = solubility of oxygen gas / partial pressure of oxygen gas

= 0.00380 g/L × 1 mol/32 grams / 760 torr × 1 atm/760 torr

= 0.00012 mol/L/atm

= 0.00012 M/atm

Now the partial pressure of the oxygen gas = mole fraction of oxygen × atmospheric pressure

= 0.210 × 1 atm

= 0.210 atm

Now putting the values in Henry's law equation we get,  

Solubility of oxygen gas = 0.00012 mol/L/atm × 0.210 at,

= 0.000025 mol/L × 32 gram/mol

= 0.00080 gram per liter

Answer:

7p

Explanation:

principal quantum number is 7

n=7( principle shell)

angular momentum quantum number gives sub shell

l = 1 means it is p orbital

so answer is 7p orbital

Answer:

3,4,1 and 6,5,2

Explanation:

In the electromagnetic spectrum the arrangement of the waves in increasing frequencies and decreasing wavelengths are as follows;

Radio waves

Microwaves

Infrared waves

Visible light rays

Ultraviolet rays

X-rays

Gamma rays

(a simple mnemonic is RMIVUXG)

Answer:

a) 101%

b)59.7%

Explanation:

The equation for the thermal decomposition of baking soda is shown;

2NaHCO3 → Na2CO3 + H2O + CO2

Number of moles of baking soda= mass/molar mass= 1.555g/84.007 g/mol = 0.0185 moles

From the reaction equation;

2 moles of baking soda yields 1 mole of sodium carbonate

0.0185 moles of baking soda will yield = 0.0185 moles ×1 /2 = 9.25 ×10^-3 moles of sodium carbonate.

Therefore, mass of sodium carbonate= 9.25 ×10^-3 moles × 106gmol-1= 0.9805 g of sodium carbonate. This is the theoretical yield of sodium carbonate.

%yield = actual yield/theoretical yield ×100

% yield = 0.991/0.9805 ×100

%yield = 101%

Since ;

2NaHCO3 → Na2CO3 + H2O + CO2

And H2O + CO2 ---> H2CO3

Hence I can write, 2NaHCO3 → Na2CO3 + H2CO3

Molar mass of H2CO3= 62.03 gmol-1

Molar mass of baking soda= 84 gmol-1

Therefore, mass of baking soda=

0.325/62.03 × 2 × 84 = 0.88 g of NaHCO3

% of NaHCO3= 0.88/1.473 × 100 = 59.7%

The decomposition reaction of baking soda is a reaction in which water and carbon dioxide ae given off as gaseous products.

Reasons:

Mass of baking soda = 1.555 g

Mass of Na₂CO₃ produced = 0.991 g

Required:

Calculation for the theoretical yield

Solution:

Theoretical yield (mass) of Na₂CO₃ produced is found as follows;

Molar mass of Na₂CO₃ = 105.9888 g/mol

Molar mass of NaHCO₃ = 84.007 g/mol

[tex]\displaystyle 1.555 \, g \, NaHCO_3 \times \frac{1 \, mol \, NaHCO_3}{84.007 \, g \, NaHCO_3} \times \frac{1 \, mol \, Na_2CO_3}{2 \, mol \, NaHCO_3} \times 105.9888 \ g \approx 0.9809 \, g \, Na_2CO_3[/tex]

The theoretical yield of Na₂CO₃ ≈ 0.9809 grams.

The percentage yield is given as follows;

[tex]\displaystyle Percentage \ yield = \mathbf{\frac{Actual \, Yield}{Theorectical \, Yield} \times 100 \%}[/tex]

The percentage yield of Na₂CO₃ is therefore;

[tex]\displaystyle Percentage \ yield \ of \ Na_2CO_3= \frac{0.991}{0.9809} \times 100 \% \approx \underline{ 101.02 \%}[/tex]

(Some baking soda may remain if the reaction is not completed)

6. Mass of the unknown mixture of baking soda = 1473 g

Mass loss from the mixture = 0.325 g

Required:

The percentage of NaHCO₃ in the mixture.

Solution:

The chemical in the mass loss from heating the NaHCO₃ = H₂CO₃

Molar mass of H₂CO₃ = 62.03 g/mol

[tex]\displaystyle \mathrm{Number \ of \ moles \ of \ H_2CO_3 \ produced} = \frac{0.325 \, g}{62.03 \, g/mol} \approx 5.2394 \times 10^{-3} \ moles[/tex]

The chemical reaction is presented as follows;

The number of moles of NaHCO₃ in the mixture is therefore;

Mass of NaHCO₃ in the mixture is therefore

[tex]\displaystyle Percentage \ of \ NaHCO_3 \ in \ the \ mixture \ = \mathbf{ \frac{Mass \ of \ NaHCO_3}{Mass \ of \ mixture} \times 100}[/tex]

Which gives;

Learn more here:

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The question is incomplete as some part is missing:

concentration in octanol Partition Ratio = concentration in water

a) What are the intermolecular forces of attraction between octanol molecules? Explain.

b) Which of the intermolecular forces of attraction identified in (a) account for most of the interactions between octanol molecules? Explain. Use the immiscibility in water and the data included in figures 1 and 2 as evidence to support your answer.

c) Would a compound with a partition coefficient less than one be more hydrophobic or more hydrophilic than one with a partition coefficient greater than 10? Explain.

d) Would nonane (figure 2) be more soluble in water or octanol? Explain.

e) Draw another structure for a compound with the same chemical formula as nonane (CH20) that has a lower boiling point. Explain.

f) Are any of the C atoms in the structure you drew for CH20 sp?hybridized? Explain.

Octanol Boiling point = 195°C Figure 2 Nonane (CH20) Boiling point = 151°C

Answer:

1. The forces between octanol molecules would be attractive. These forces include Vanderwaal forces, H-bonds due to the presence of highly polar O-H group.

2. H-bonding ahould account for most of the attractive forces. The O-H bond should behave like and dipole, oxygen of one molecule attracts the hydrogen of the neighbouring molecule forming D-H...A links throughout (D stands for donor of H-Bond and A for acceptor for H-Bond).

3. Partition coefficient less than 1 will be more hydrophilic, generally drugs with low partition coefficients are regarded as hydrophilic. As parition coefficient of 10 mean more of the solute is dispersed in octanol as compared to water.

4. Nonane is non polar, so it would not dissolve in water. It follows the rule like dissolves like. Polar substances dissolve in polar solvents. 1-octanol is able to bind with water through hydrogen bonds thus its soluble in water but nonane doesn't. Nonane will forms a different layer from water.

5) no all carbons in 2-methyloctane are single bonded. Thus sp3 hybrid. A sp2 hybridised carbon would have a double bond C=C.

Answer:

Option B. 0.136 g

Explanation:

The balanced equation for the reaction is given below:

2AgNO3(aq) + 2NaOH(aq) —> Ag2O(s) + 2NaNO3(aq) + H2O(l)

Next, we shall determine the masses of AgNO3 and NaOH that reacted and the mass of Ag2O produced from the balanced equation. This is illustrated below:

Molar mass of AgNO3 = 108 + 14 + (16x3) = 170g/mol

Mass of AgNO3 from the balanced equation = 2 x 170 = 340g

Molar mass of NaOH = 23 + 16 + 1 = 40g/mol

Mass of NaOH from the balanced equation = 2 x 40 = 80g

Molar mass of Ag2O = (108x2) + 16 = 232g/mol

Mass of Ag2O from the balanced equation = 1 x 232 = 232g

Summary:

From the balanced equation above,

340g of AgNO3 reacted with 80g of NaOH to produce 232g of Ag2O.

Next, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

340g of AgNO3 reacted with 80g of NaOH.

Therefore, 0.2g of AgNO3 will react with = (0.2 x 80)/340 = 0.047g of NaOH.

From the calculations made above, only 0.047g out of 0.2g of NaOH given, reacted completely with 0.2g of AgNO3. Therefore, AgNO3 is the limiting reactant and NaOH is the excess reactant.

Now, we can calculate the mass of Ag2O produced from the reaction of 0.2g of AgNO3 and 0.2g of NaOH.

In this case, we shall use the limiting reactant because it will produce the maximum yield of Ag2O as all of it is used up in the reaction.

The limi reactant is AgNO3 and the mass of Ag2O produced can be obtained as follow:

From the balanced equation above,

340g of AgNO3 reacted to produce 232g of Ag2O.

Therefore, 0.2g of AgNO3 will react to produce = (0.2 x 232)/340 = 0.136g of Ag2O.

Therefore, 0.136g of Ag2O was produced from the reaction.

rate=0.2*3^1*3^2=0.2*3*9=5.4(mol/L)s so the correct answer is C.

Answer:

This reaction isn't yet at an equilibrium. It must shift in the direction of the reactant (namely [tex]\rm NOBr\; (g)[/tex]) in order to reach an equilibrium.

For this mixture, the reaction quotient is [tex]Q_c = 0.0126[/tex].

Explanation:

A reversible reaction is at equilibrium if and only if its reaction quotient [tex]Q_c[/tex] is equal to the equilibrium constant [tex]K_c[/tex].

Start by calculating the equilibrium quotient [tex]Q_c[/tex] of this reaction. Given the reaction:

[tex]\rm 2\; NOBr\; (g) \rightleftharpoons 2\; NO\; (g) + Br_2\; (g)[/tex].

Let [tex][\mathrm{NOBr\; (g)}][/tex], [tex][\mathrm{NO\; (g)}][/tex], and [tex][\mathrm{Br_2\; (g)}][/tex] denote the concentration of the three species. The formula for the reaction quotient of this system will be:

[tex]\displaystyle Q_c = \frac{[\mathrm{NO\; (g)}]^2 \cdot [\mathrm{Br_2\; (g)}]}{[\mathrm{NOBr\; (g)}]^2}[/tex].

(Note, that in this formula, both [tex][\mathrm{NO\; (g)}][/tex] and [tex][\mathrm{NOBr\; (g)}][/tex] are raised to a power of two. That corresponds to the coefficients in the balanced reaction.)

Calculate the reaction quotient given the concentration of each species:

[tex]\displaystyle Q_c = \frac{[\mathrm{NO\; (g)}]^2 \cdot [\mathrm{Br_2\; (g)}]}{[\mathrm{NOBr\; (g)}]^2} \approx 1.26\times 10^{-2} = 0.0126[/tex].

(Note that the unit is ignored.)

Apparently, [tex]Q_c > K_c[/tex]. Since [tex]Q_c[/tex] and [tex]K_c[/tex] are not equal, this reaction is not at an equilibrium. If external factors like temperature stays the same,

Keep in mind that [tex]Q_c[/tex] denotes a quotient. To reduce the value of a quotient, one may:

In [tex]Q_c[/tex], that means reducing the concentration of the products while increasing the concentration of the reactants. In other words, the system needs to shift in the direction of the reactants before it could reach an equilibrium.

Answer:

Option B

Explanation:

Scientific question are answered through experimentation, through testing the theory about the physical world.

Answer: its A

through observing and measuring the physical world

Explanation:

Answer:

1: 2-bromo-3-chloropentane

Explanation:

find longest carbon chain =5

place the Br and Cl on the carbon chain

follow naming rules I guess

Answer:

680g of NaNO3.

Explanation:

The balanced equation for the reaction is given below:

2NaNO3 —> 2NaNO2 + O2

Next, we shall determine the mass of NaNO3 that decomposed and the mass of O2 produced from the balanced equation. This is illustrated below:

Molar mass of NaNO3 = 23 + 14 + (16x3) = 85g/mol

Mass of NaNO3 from the balanced equation = 2 x 85 = 170g

Molar mass of O2 = 16x2 = 32g/mol

Mass of O2 from the balanced equation = 1 x 32 = 32g

From the balanced equation above,

170g of NaNO3 decomposed to produce 32g of O2.

Now, we can obtain the mass of NaNO3 needed to produce 128g of O2 as shown below:

From the balanced equation above,

170g of NaNO3 decomposed to produce 32g of O2.

Therefore, Xg of NaNO3 will decompose to produce 128g of O2 i.e

Xg of NaNO3 = (170 x 128)/32

Xg of NaNO3 = 680g

Therefore, 680g of NaNO3 are needed to produce 128g of O2.

Answer:

pH = 3.39

Explanation:

The equilibrium in water of ascorbic acid (With its conjugate base) is:

H₂C₆H₆O₆(aq) + H₂O(l) ⇄ HC₆H₆O₆⁻(aq) + H₃O⁺(aq)

Where the acidic dissociation constant is written as:

Ka = 7.9x10⁻⁵ = [HC₆H₆O₆⁻] [H₃O⁺] / [H₂C₆H₆O₆]

H₂O is not taken in the Ka expression because is a pure liquid.

As initial concentration of H₂C₆H₆O₆ is 2.5x10⁻³M, the equilibrium concentration of each species in the equilibrium is:

[H₂C₆H₆O₆] = 2.5x10⁻³M - X

[HC₆H₆O₆⁻] = X

[H₃O⁺] = X

Replacing in the Ka expression:

7.9x10⁻⁵ = [X] [X] / [2.5x10⁻³M - X]

1.975x10⁻⁷ - 7.9x10⁻⁵X = X²

0 = X² + 7.9x10⁻⁵X - 1.975x10⁻⁷

Solving for X:

X = -0.00048566→  False solution, there is no negative concentrations

X = 0.00040666 → Right solution

As [H₃O⁺] = X, [H₃O⁺] = 0.00040666

pH is defined as -log [H₃O⁺];

pH = -log 0.00040666,

Answer:

10.328 m

Explanation:

normal atmospheric pressure = 101325 Pa

density of water at 25 °C = 1.0 g/cm^3 = 1000 kg/m^3

pressure = pgh

where p = density

g = acceleration due to gravity = 9.81 m/s^2

h = height of column

imputing values, we have

101325 = 1000 x 9.81 x h

height of column h = 101325/9810 = 10.328 m

Answer:

The base is involved in the rate determining step of an E2 reaction mechanism

Explanation:

Let us get back to the basics. Looking at an E1 reaction, the rate determining step is unimolecular, that is;

Rate = k [Carbocation] since the rate determining step is the formation of a carbonation.

For an E2 reaction however, the reaction is bimolecular hence for the rate determining step we can write;

Rate = k[alkyl halide] [base]

The implication of this is that an excess of either the alkyl halide or base will facilitate an E2 reaction.

Hence, when excess base is used, E2 reaction is favoured since the base is involved in its rate determining step. In an E1 reaction, the base is not involved in the rate determining step hence an excess of the base has no effect on an E1 reaction.

Answer:

pH at equivalence point is 8.47

Explanation:

Benzoic acid react with NaOH, thus:

HC₇H₅O₂ + NaOH → C₇H₅O₂⁻ + H₂O + Na⁺

You reach equivalence point when moles of the acid = moles of NaOH.

Moles of benzoic acid are:

0.025L ₓ (0.0988mol / L) = 0.00247 moles

To have 0.00247 moles of NaOH in solution and reach equivalence point you need to add:

0.00247 moles NaOH ₓ (1L / 0.115mol) = 0.0215L of NaOH solution.

Total volume is 0.0465L.

There are produced 0.00247 moles of C₇H₅O₂⁻ and its molarity will be:

0.00247 mol C₇H₅O₂⁻ / 0.0465L = 0.0531M C₇H₅O₂⁻

C₇H₅O₂⁻ is in equilibrium with water, thus:

C₇H₅O₂⁻(aq) + H₂O ⇄ HC₇H₅O₂(aq) + OH⁻(aq)

Where Kb = Kw / Ka = 1x10⁻¹⁴ / 6.5x10⁻⁵ = 1.54x10⁻¹⁰ is:

Kb = 1.54x10⁻¹⁰ = [HC₇H₅O₂] [OH⁻] / [C₇H₅O₂⁻]

The concentrations in equilibrium of the species are:

[HC₇H₅O₂] = X

[OH⁻] = X

[C₇H₅O₂⁻] = 0.0531M - X

Where X represents how much C₇H₅O₂⁻ react, X is reaction coordinate

Replacing in Kb expression:

1.54x10⁻¹⁰ = [HC₇H₅O₂] [OH⁻] / [C₇H₅O₂⁻]

1.54x10⁻¹⁰ = [X] [X] / [0.0531 - X]

8.169x10⁻¹² - 1.54x10⁻¹⁰X = X²

8.169x10⁻¹² - 1.54x10⁻¹⁰X - X² = 0

Solving for X:

X = -2.858x10⁻⁶M → False solution, there is no negative concentrations

X = 2.858x10⁻⁶M → Right solution

As [OH⁻] = X

[OH⁻] = 2.858x10⁻⁶M

pOH is -log [OH⁻]

pOH = 5.54

pH = 14 - pOH

pH = 8.46

Answer:

The new solution is 1.4% m/V

Explanation:

The concentration of the new solution, obtained by adding 22.5 mL of distilled water to 2.5 mL of 14 % m/V sugar solution, is 1.4% m/V.

We have 2.5 mL (V₁) of a concentrated solution and add it to 22.5 mL of distilled water. Assuming the volumes are additives, the volume of the new solution (V₂) is:

[tex]2.5 mL + 22.5 mL = 25.0 mL[/tex]

We want to prepare a dilute solution from a concentrated one, whose concentration is 14% m/V (C₁). We can calculate the concentration of the dilute solution (C₂) using the dilution rule.

[tex]C_1 \times V_1 = C_2 \times V_2\\C_2 = \frac{C_1 \times V_1}{V_2} = \frac{14\% m/V \times 2.5 mL}{25.0 mL} = 1.4 \% m/V[/tex]

The concentration of the new solution, obtained by adding 22.5 mL of distilled water to 2.5 mL of 14 % m/V sugar solution, is 1.4% m/V.

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Answer:

4.26 %

Explanation:

There is some info missing. I think this is the original question.

Calculate the percent ionization of nitrous acid in a solution that is 0.249 M in nitrous acid. The acid dissociation constant of nitrous acid is  4.50  ×  10 ⁻⁴.

Step 1: Given data

Initial concentration of the acid (Ca): 0.249 M

Acid dissociation constant (Ka): 4.50  ×  10 ⁻⁴

Step 2: Write the ionization reaction for nitrous acid

HNO₂(aq) ⇒ H⁺(aq) + NO₂⁻(aq)

Step 3: Calculate the concentration of nitrite in the equilibrium ([A⁻])

We will use the following expression.

[tex][A^{-} ] = \sqrt{Ca \times Ka } = \sqrt{0.249 \times 4.50 \times 10^{-4} } = 0.0106 M[/tex]

Step 4: Calculate the percent ionization of nitrous acid

We will use the following expression.

[tex]\alpha = \frac{[A^{-} ]}{[HA]} \times 100\% = \frac{0.0106M}{0.249} \times 100\% = 4.26\%[/tex]

Answer:

B. Reactant + Reactant -> Product + Product

Explanation:

Reactants are substances that- as the name suggests- reacts with other substances at the beginning of a reaction

Products are substances that are produced as a result of the reaction

Typically, when writing a chemical reaction, an arrow is used to show the direction the reaction is moving.  In this case, the arrows in options B and C suggest that the reaction only moves in one direction- forwards

And as mentioned above, reactants are the substances at the start of the reaction, they're what mixes together to form a new product.  

To keep things simple:

Products can't be at the beginning of a reaction since they weren't formed yet.

Similarly, reactants can't be part of the products since they already existed and didn't need to be made. In a lot cases, the reactants would be completely used up to make the products

As such, only one possible chemical reaction would follow that reasoning:

    Reactant + Reactant ->  Product + Product

Reactant + Reactant → Product + Product is the correctly written chemical reaction. Hence, option B is correct.

A chemical equation is a mathematical expression of the chemical reaction which represents the product formation from the reactants.

In an equation, the reactants are written on the left-hand side and the products are written on the right-hand side demonstrated by one-headed or two-headed arrows.

Hence, option B is correct.

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Answer:

k= 1.5

[A] = 1 M

[B] = 3 M

m = 2

n = 1

Explanation:

rate = k[A]”[B]"

The rate of the reaction is 4.5 mol L⁻¹s⁻¹.

Rate of a reaction is defined as the change in concentration of any one of the reactants or products of the reaction, in unit time.

Here,

The concentration of A, [A] = 1 M

The concentration of B, [B] = 3 M

The partial order with respect to A, m = 2

The partial order with respect to B, n = 1

The rate constant of the reaction, k = 1.5

The rate of the reaction,

r = k[A]^m [B}^n

r = 1.5 x 1² x 3

r = 4.5 mol L⁻¹s⁻¹

Hence,

The rate of the reaction is 4.5 mol L⁻¹s⁻¹.

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