One mole of CO2(g) is expanding isothermally and reversibly from a volume of 0.100 dm3 to a volume of 100 dm3. Calculate the work in "kJ" of the expansion process if: 1/ the gas is considered real gas. (Hint: use the Van Der Waals equation for real gases to express the pressure in the work equation). 2/ The gas is considered perfect gas. Given: The constants for CO2(g) are: a= 3.59 atm L2/mol2, b= 0.0427 L/mol Answer: a) the expansion work for CO2 as real gas is W = kJ. b) the expansion work for CO2 as perfect gas is W = kJ.

Answers

Answer 1

Solution :

For the real gas following Vander Waals equation, reversible isothermal work done is given by :

[tex]$W= \int P \ dV$[/tex]

[tex]$W= \int \left(\frac{nR}{V-nb}-\frac{an^2}{V^2}\right) dV$[/tex]

[tex]$W_{real}=-nRT \ln \left[\frac{V_2-b}{V_1-b}\right]-an^2\left[\frac{1}{V_2}-\frac{1}{V_1}\right]$[/tex]

Given : [tex]$V_1=0.1 \ dm^3$[/tex], [tex]$$V_2 =100 \ dm^3[/tex]  

[tex]$a=359 \ atm \ L^2/ mol^2, \ \ b = 0.0427 \ L/mol$[/tex]

As T is not given, assuming T = 290 K

[tex]$W_{real} = 0.0823 \times 240 \left[ \ln \left(\frac{100-0.042}{0.1-0.0427}\right)\right]-3.59\left[\frac{1}{100}-\frac{1}{0.1}\right]$[/tex]

[tex]$W_{real}= -183.06+35.864$[/tex]

[tex]$W_{real}=-147.196$[/tex]

For the perfect gas,

[tex]$W=nRT \ln\left[\frac{V_2}{V_1}\right] =(1)(0.0823)(290) \ln \left[\frac{100}{0.1}\right]$[/tex]

[tex]$W_{ideal}=169.415$[/tex] kJ


Related Questions

Smoking cigarettes is a lifestyle choice that may lead to cardiovascular disease.
Some people who have never smoked cigarettes still have cardiovascular disease.
Give two other factors that may contribute to the occurrence of cardiovascular
disease.

Answers

Answer:

High blood pressure. High blood pressure (hypertension) is one of the most important risk factors for CVD.

High cholesterol - High-fat diet.

Hello, I need help in this part of chemistry, I need the chemical names of the following four:

1) B and F3

2) Se and I2

3) As2 and Se3


ASAP! Please,,, ​

Answers

1- Biron trifluoride
2- selenide
3- arsenic triselenide

ANSWER ASAP Please! How do groups and periods differ? What trend specifically occurs in either?

Answers

A period is a horizontal row of the periodic table. A group is a vertical row of the periodic table. Periodic trends arise from the changes in the atomic structure of the chemical elements within their respective periods (horizontal rows) and groups in the periodic table.

Colour of crushed chalk + Iodine solution​

Answers

I guess if you mix them together, the chalk would get less harder.

The mass of this atom is:
u. 3 mass units
b. 4 mass units
c. 6 mass units
d. 7 mass units
e. 11 mass units

Answers

The answer is going to be c


If we have 0.072 g of FeCl3 then how many moles are there?

Answers

Answer:

~0.0004

Explanation:

[tex]n=\frac{m}{M}[/tex]

n=0.072/(56+(35.5*3))=0.072/162.5~~0.004

If you start with 13 mole H2O and 50 grams of O2 what is the percent yield of H202 if 100 grams of H202 is actually made?

Answers

Answer:

94.1 %

Explanation:

We firstly determine the equation:

2H₂O + O₂ →  2H₂O₂

2 moles of water react to 1 mol of oxygen in order to produce 2 moles of oxygen peroxide.

We convert the mass of oxygen to moles:50 g . 1mol /32g = 1.56 mol

Certainly oxygen is the limiting reactant.

2 moles of water react to 1 mol of oxygen.

13 moles of water may react to 13/2 = 6.5 moles. (And we only have 1.56)

As we determine the limiting reactant we continue to the products:

1 mol of O₂ can produce 2 moles of H₂O₂

Then 1.56 moles of O₂ will produce (1.56 . 2) = 3.125 moles

We convert the moles to mass: 3.125 mol . 34 g/mol= 106.25 g

That's the 100% yield or it can be called theoretical yield.

Percent yield = (Yield produced / Theoretical yield) . 100

(100g / 106.25 g) . 100 = 94.1 %

The driest desert on Earth is the several years to not receive any rainfall. desert. There it has been recorded for O Atacama Sahara (T) Antartic ( Gobi​

Answers

Answer:

Atacama

Explanation:

Help me pretty please

Answers

Answer:

I'm pretty sure light waves do not require a medium to travel

For the reaction So3 + H2O -> H2SO4, how many grams of sulfur trioxide are required to produce 4.00 mol of sulfuric acid

Answers

Answer:

320 grams of sulfur trioxide are required to produce 4.00 mol of sulfuric acid.

Explanation:

The balanced reaction is:

SO₃ + H₂O → H₂SO₄

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

SO₃: 1 moleH₂O: 1 moleH₂SO₄: 1 mole

Being the molar mass of each compound:

SO₃: 80 g/moleH₂O: 18 g/moleH₂SO₄: 98 g/mole

By reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

SO₃: 1 mole* 80 g/mole= 80 gramsH₂O: 1 mole* 18 g/mole= 18 gramsH₂SO₄: 1 mole* 98 g/mole= 98 grams

Then you can apply the following rule of three: if 1 mole of sulfuric acid is produced by the reaction of 80 grams of sulfur trioxide, 4 moles of sulfuric acid is produced from how much mass of sulfur trioxide?

[tex]mass of sulfur trioxide= \frac{4 moles of sulfuric acid* 80 grams of sulfur trioxide}{1 mole of sulfuric acid }[/tex]

mass of sulfur trioxide= 320 grams

320 grams of sulfur trioxide are required to produce 4.00 mol of sulfuric acid.

The mass of the required compound is 320 grams

Chemical reactions

Given the chemical equation expressed as:

[tex]SO_3 + H_2O \rightarrow H_2SO_4[/tex]

According to stochiometry, 1 mole of SO3  produces 1 mole of H2SO4, hence the moles of SO3 will also be 4.00moles

Determine the mass of SO3

Mass = mole * molar mass

Mass = 4.0 * [32+3(16)]

Mass = 4.0 * 80

Mass = 320 grams

The mass of the required compound is 320 grams

Learn more on stoichiometry here:  https://brainly.com/question/16060223

What are the major parts of the ecosystem

Answers

Answer:

Ecosystems have lots of different living organisms that interact with each other. The living organisms in an ecosystem can be divided into three categories: producers, consumers and decomposers. They are all important parts of an ecosystem. Producers are the green plants.

Explanation:

Hope this helps

El mercurio ha sido utilizado como elemento para medir la temperatura porque Es una mezcla. Al aumentar la temperatura se dilata con facilidad. Es un buen conductor del calor. Es un buen conductor de la electricidad.

Answers

Answer:

La respuesta correcta es: Al aumentar la temperatura se dilata con facilidad

Explanation:

El mercurio (Hg) es un elemento metálico que a temperatura ambiente es un líquido. Tiene la propiedad de dilatarse con facilidad al aumentar la temperatura, propiedad que ha sido utilizada en los termómetros de mercurio. En estos termómetros, el mercurio está dentro de un tubo de vidrio graduado con un bulbo para transmitir el calor. Al estar en contacto con un cuerpo más caliente (a mayor temperatura), el mercurio del interior del termómetro se dilata (expande su volumen) y asciende por el tubo indicando la temperatura correspondiente, graduada en el vidrio.

If 3.0 moles of a gas are in a 60.0 liters container at 400.0 K, what is the pressure, in atm, inside
the container?
A.
0.61 atm
B.
16 atm
C.
1.6 atm

Answers

Answer:

C. 1.6 atm

Explanation:

PV = nRT

Solve for P --> P = nRT/V

n = 3.0 mol

R = 0.08206 L atm / mol K

T = 400.0 K

V = 60.0 L

P = (3.0)(0.08206)(400.0) / (60.0) = 1.6 atm

9
If you wanted to make 250 mL of a 0.01 M solution of CaCl, calculate how many moles of calcium chloride would be
needed. Your response must include both a correct numerical setup and the calculated result. [1]

Answers

Answer:

0.0025moles

Explanation:

Molarity of a solution (M) = number of moles (n) ÷ volume (V)

According to this question, to make 250 mL of a 0.01 M solution of CaCl, the following number of moles is needed:

Volume = 250mL = 250/1000 = 0.250Litres.

Using; molarity = n/V

0.01 = n/0.250

n = 0.0025

n = 2.5 × 10^-3 moles.

1.9x10^23 atoms of sulfur to grams of sulfur

Answers

Answer:

see explanation and punch in the numbers yourself ( will be better for your test)

Explanation:

If you are given atoms you need to divide by Avogadro's number 6.022x10^23

then you will have moles of sulfur-- once you have moles multiply by the molar mass of sulfur to go from moles to grams

mm of sulfur is 32 g/mol

Mole measure the number of elementary entities of a given substance that are present in a given sample. Therefore, the grams of sulfur in  1.9x10²³ atoms of sulfur is 9.92g.

What is mole?

The SI unit of amount of substance in chemistry is mole. The mole is used to measure the quantity of amount of substance.

Given number of atoms= 1.9x10²³atoms

we know one mole of any element contains 6.022×10²³ atoms which is also called Avogadro number

mole =given number of atoms ÷ 6.022×10²³(Avogadro number)

Substituting the values

mole=1.9x10²³÷ 6.022×10²³

mole = 0.31 mole of sulfur

Mole = given mass÷ Molar mass

Molar mass of sulfur=32g/mol

mass of sulfur =0.31 mole ×32g/mol

mass of sulfur=9.92g

Therefore, the grams of sulfur in  1.9x10²³ atoms of sulfur is 9.92g.

To know more about mole, here:

https://brainly.com/question/15209553

#SPJ2

In q = mCΔT, what does C stand for?

Answers

Answer:

The symbol c stands for specific heat and depends on the material and phase. The specific heat is the amount of heat necessary to change the temperature of 1.00 kg of mass by 1.00ºC.

why is conventional solar electricity is so expensive to generate??

Answers

Answer:

Most solar cells are made from silicon—the same semiconductor material that is at the heart of computers. The cells are expensive to produce because it takes a great deal of energy to purify the silicon.

A slug travels the length of a log in 2 hours. If the slug's average speed is 1.5 cm / minute how long is the log

Answers

Answer:

The length of the log is 180 cm

Explanation:

From the question given above, the following data were obtained:

Time = 2 hours

Speed = 1.5 cm/min

Distance =?

Next, we shall convert 2 hours to minutes. This can be obtained as follow:

1 h = 60 mins

Therefore,

2 h = 2 × 60

2 h = 120 mins

Finally, we shall determine the Lenght of the log. This can be obtained as follow:

Time = 120 mins

Speed = 1.5 cm/min

Distance =?

Speed = distance / time

15 = distance / 120

Cross multiply

Distance = 1.5 × 120

Distance = 180 cm

Therefore, the length of the log is 180 cm

Answer:

180

Explanation:

7. Given the balanced equation:


As a sample of I2(s) sublimes to I2(g), the entropy of the sample

Answers

Gas molecules have more freedom in motion—and gases can be thought of as more “disordered”—than molecules of a solid, which are rigidly held in place. When it comes to phases, the entropy increases as you go from a solid to liquid to gas (the gaseous state having the greatest entropy and the solid state having the least).

So, as a sample of solid iodine sublimes to form gaseous iodine, the entropy of the sample increases.

what happens to the rate of a reaction as the reaction progresses

Answers

The rate of a reaction decreases as the reaction progresses.

How does the heart keep the blood flowing throughout the body?

It contracts and relaxes
It inflates and deflates
It inhales and exhales
It opens and closes

Answers

Answer:

b

Explanation:

Answer:

It contracts and relaxes awnser is a

Explanation:

im from flvs

6 a What does the sacrificial protection of iron mean?
b Both magnesium and zinc can be used for it. Why?
c But copper will not work. Explain why.

Answers

Explanation:

A-Corrosion

B- Magnesium helps ur body regulates its zinc levels and zinc absorbs into absorbs magnesium more efficiently

At a certain temperature 3.24 moles of co2 gas at 2.15atm takes up a volume of 35.28 what is the temperature in celsius

Answers

Answer:

The temperature is 12.35 C.

Explanation:

An ideal gas is a theoretical gas that is considered to be composed of point particles that move randomly and do not interact with each other. Gases in general are ideal when they are at high temperatures and low pressures.

An ideal gas is characterized by three state variables: absolute pressure (P), volume (V), and absolute temperature (T). The relationship between them constitutes the ideal gas law, an equation that relates the three variables if the amount of substance, number of moles n, remains constant and where R is the molar constant of the gases:

P * V = n * R * T

In this case:

P= 2.15 atmV= 35.28 Ln= 3.24 molesR= 0.082 [tex]\frac{atm*L}{mol*K}[/tex]T= ?

Replacing:

2.15 atm* 35.28 L= 3.24 moles* 0.082[tex]\frac{atm*L}{mol*K}[/tex] * T

Solving:

[tex]T=\frac{2.15 atm* 35.28 L}{3.24 moles* 0.082\frac{atm*L}{mol*K}}[/tex]

T=285.5 K= 12.35 C (being 273.15 K= 0 C)

The temperature is 12.35 C.

The relation between the moles, volume, temperature, and pressure is given by the ideal gas equation. The temperature of a gas is 12.35 celsius.

What is the ideal gas law?

The ideal gas law is the hypothetical gas law that depicts the relation between pressure, volume, moles of the compound, and the temperature of the gas.

The ideal gas equation is given as,

[tex]\rm PV = nRT[/tex]

Given,

Pressure (P) = 2.15 atm

Volume (V) = 35.28 L

Number of moles (n) = 3.24 mol

Gas constant (R) = 0.082

Temperature (T) = ?

Substituting values in the above equation, the temperature is calculated as:

[tex]\begin{aligned} \rm T &= \rm \dfrac{PV}{nR}\\\\&= \dfrac{2.15\times 35.28}{3.24 \times 0.082}\\\\&= 286.23 \;\rm K\end{aligned}[/tex]

Therefore, 12.35 degrees Celsius is the temperature of the gas.

Learn more about ideal gas law here:

https://brainly.com/question/4406716

convert 5.91 x 10^26 molecules h20 to moles

Answers

Answer:

0.432 mol

Explanation:

Divide the given number of molecules by Avogadro's constant. Avogradro's constant is the number of atoms/molecules in a mole of a substance.

Therefore,

2.60

10

23

molecules

6.022

10

23

molecules/mol

=

0.432175 moles

0.432 moles

Explanation:

How many grams are in 4.5 x 10^22 molecules of water? please show dimensional analysis

Answers

Answer:

1.1grams

Explanation:

Find moles of water:

4.5x10^22/(6.02x10^23)=0.07mol

Find molar mass of the water

O=16.00g/mol

0.07x 16.00=1.1 grams

How do the mass number and atomic change as a particle goes through alpha decay?

Answers

Since an alpha particles is a helium nucleus, it involves the loss of 2 protons and 2 neutrons. As a result, the atom the loses an alpha particle decreases its mass number by four ( 2 protons and 2 neutrons) and decreases it's atomic number by 2 ( it loses two protons).

I have a Helium party balloon that can hold 3.0 liters of gas. If I blow up this balloon with 0.10 moles of oxygen gas at a pressure of 1.0 atmosphere, what is the temperature of the balloon?

Answers

Answer:

I am not yet sure on my answer

I would not want to give you wrong answers

Sorry

If a balloon with a volume of 10L at 500kpa is heated until the balloon has a temperature of 300°C, 750atm and now has a volume of 100mL. What was the original temperature of the balloon (in °C)

Answers

Answer:

103.6°C

Explanation:

We solve this problem, with the Ideal Gases Law. We know that moles of gas are not changed through time.

P . V = n . R . T

So n (number of moles) and R (Ideal Gases constant) are the same, they are cancelled. In the two different states, we can propose:

P₁ . V₁ / T₁ = P₂ . V₂ /T₂

We need to make some conversions:

100 mL . 1 L/ 1000mL = 0.1L

500 kpa . 1atm / 101.3 kPa = 4.93 atm

300°C + 273 = 573 K

We replace data:

4.93 atm . 10L / T₂ = 750 atm . 0.1L / 573K

4.93 atm . 10L = (750 atm . 0.1L / 573K) . T₂

(4.93 atm . 10L) / (750 atm . 0.1L / 573K) → T₂

T₂ = 376.65 K

We convert K to °C →  376.65 K - 273 = 103.6 °C

in what order were the sun and earth created according to both the younger theory and the older theory

Answers

answer: the earth orbits around the sun for 365 while getting older to the young theory.

Answer:

The older theory was that the sun (and other planets) revolved around earth and the new theory is that the earth (and other planets) revolved around the sun.

Explanation:

Most large mountains are the result of a(n)?

River
Volcano
Earthquake
Hurricane

Answers

Answer:

C.) Earthquake

Explanation:

Most mountains occur due to the movement of tectonic plates. They slowly push into each other, and the earth's crust rises over time forming mountains.

Earthquakes occur due to the shift of tectonic plates. It sends seismic waves throughout the earth's crust, and causes the ground to shake temporarily.

Other Questions
A researcher was interested in the relationship between the number of texts sent in a day and the number of e-mails sent in a day by employees at a certain company. Using 15 data values, a 90 percent confidence interval for the slope of a regression model was found to be (2.31, 3.47). The researcher claims that the interval would have been narrower with a different sample size if all other things remained the same. Which of the following sample sizes would make the researcher's claim NOT true? A. 14 B. 16 C. 20 D. 30 E. 100 Please Help!!! 15 Points!!! Will Mark Brainliest!!! Please show your work!!A pick-up truck if fitted with new tires which have a diameter of 40 inches. How fast will the pick-up truck be moving when the wheels are rotating at 365 revolutions per minute? Express your answer in miles per hour rounded to the nearest whole number. solve the rational equation 2x/x-3=3x/x-2First to answer gets Brainlyest Update: answer is 0,5 PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!! PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!! PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!! PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!!PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!! PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!!! PLSSS HELPPPP I WILLL GIVE YOU BRAINLIEST!!!!! Nos_____(gustar) ir a la casa de nuestros tos. PLSSSS SOMEONE HELP ME ASSAPPPPP ILL GIVE U BRAINLIEST Please help me please thx Ill give brainliest Plz help me I well mark brainliest I dont know if this is correct !!!!!!! Please answer correctly !!!!!!! Will mark Brianliest !!!!!!!!!!!!!!!!!! The two lines represented by the equations below are graphed on a coordinate plane. Which statement best describesthe two lines?2x + y = 12y-2 = 3(x - 2)1) parallel2) perpendicular3) the same line4) neither parallel nor perpendicular What makes human garbage (waste) different from the waste that other living thingsproduce? Oxygen molecules are sixteen times as massive as hydrogen molecules.At the same temperature, which type of molecule would you expect to move faster? HURRY!!!!!! HELP PLEASEEE To begin the experiment, 1.65g of methane CH4 is burned in a bomb calorimeter containing 1000 grams of water. The initial temperature of water is 18.98oC. The specific heat of water is 4.184 J/g oC. The heat capacity of the calorimeter is 615 J/ oC . After the reaction the final temperature of the water is 36.38oC.2. Calculate the change in temperature, T. Show your work. (1pt)3. Calculate the heat absorbed by water. Use the formula qwater = m C T Show your work (2pts)4.Calculate the heat absorbed by the Calorimeter. Use the formula: qcal = Ccal T Show your work. (2pts)5. The total heat absorbed by the water and the calorimeter can be calculated by adding the heat calculated in steps 3 and 4. The amount of heat released by the reaction is equal to the amount of heat absorbed with the negative sign as this is an exothermic reaction. (2pts)a.Using the formula H = - (qcal + qwater ) , calculate the total heat of combustion. Show your work. b. Convert heat of combustion (answer from part a) from joules to kilojoules. Show your work.6. Evaluate the information contained in this calculation and complete the following sentence: (2pts)This calculation shows that burning _______ grams of methane [TAKES IN] / [GIVES OFF] energy (Choose one).7. The molar mass of methane is 16.04 g/mol. Calculate the number of moles of methane burned in the experiment. Show your work. (2pts)8. What is the experimental molar heat of combustion in KJ/mol? Show your work. (2pts)9. The accepted value for the heat of combustion of methane is -890 KJ/mol . Explain why the experimental data might differ from the theoretical value in 2-3 complete sentences. (2pts)10. Given the formula: % error= |(theoretical value - experimental value)/theoretical value)| x 100 Calculate the percent error. Show your work. (2pts) How Did The Development Of The Railroad Afeact Texas population? Compared to hieroglyphics and cuneiform, the writings of the Harappan civilization are what property is used here 3(+2)=3+6 A belt of negligible mass passes between cylinders A and B and is pulled to the right with a force P. Cylinders A and B weigh, respectively, 5 and 20 lb. The shaft of cylinder A is free to slide in a vertical slot and the coefficients of friction between the belt and each of the cylinders are s = 0.50 and k = 0.40. For P = 3.6 lb, Determine: (a) Whether slipping occurs between the belt and either cylinder, (b) The angular acceleration of each cylinder. (a) Tom is 7 years old. Bill is 5 years older than Tom.Write Bill's age in terms of T. Woodpeckers and squirrels fight for nesting rights in the same holes and spaces in trees, while the lions and cheetahs of the African savanna fight for the same antelope and gazelle prey. Which of the following statements about these relationships is accurate?A. These are examples of competition because the organisms are fighting for resources.B. These are examples of predation because the organisms are trying to take each others food and homes.C. These are examples of predation because lions and cheetahs eat woodpeckers and squirrels.D.These are examples of competition because no organisms are helped or harmed. What did Fazlullah's The Mullah followers look like?