Select the correct answer. A certain reaction has this form: aA bB. At a particular temperature and [A]0 = 2.00 x 10-2 Molar, concentration versus time data were collected for this reaction and a plot of ln[A]t versus time resulted in a straight line with a slope value of -2.97 x 10-2 min-1. What is the half-life of this reaction? A. 23.33 seconds B. 0.043 minutes C. 0.0043 seconds D. 23.33 minutes E. 1680 minutes

Answers

Answer 1

Answer:

[tex]\large \boxed{\text{D. 23.34 min}}[/tex]

Explanation:

1. Find the order of reaction

Use information from the graph to find the order.

If a plot of ln[A] vs time is linear, the reaction is first order and the slope = -k.

2. Find the  half-life

[tex]k = \dfrac{\ln2}{ t_{\frac{1}{2}}}\\\\k = \text{-slope} = -(-2.97 \times 10^{-2} \text{ min}^{-1}) =2.97 \times 10^{-2} \text{ min}^{-1} \\ t_{\frac{1}{2}} =\dfrac{\ln 2}{k} = \dfrac{\ln 2}{2.97 \times 10^{-2}\text{ min}^{-1}} =\textbf{23.34 min}\\\\\text{The half-life is $\large \boxed{\textbf{23.34 min}}$}[/tex]

Answer 2

The half life of the reaction is 23.33 minutes.

We know that for a first order reaction;

ln[A]t = ln[A]o  - kt

A plot of ln[A]t  against time (t) will yield a straight line graph with a slope of -k.

From the question, the slope is -2.97 x 10-2 min-1.

So, -2.97 x 10-2 min-1 = - k

k = 2.97 x 10-2 min-1

The half life of a first order reaction is obtained from;

t1/2 = 0.693/k

t1/2 = 0.693/2.97 x 10-2 min-1

t1/2 = 23.33 minutes

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Related Questions

can I get some urgent help please?​

Answers

Answer:

hi here goes your answer

Explanation:

iv. The lower the PH, the weaker the base

The ionization constant of lactic acid ch3ch(oh) co2h am acid found in the blood after strenuous exercise is 1.36×10^-4 If 20.0g of latic acid is used to make a solution with a volume of 1.00l what is the concentration of hydronium ion in the solution

Answers

Answer:

Explanation:

CH₃CHOHCOOH    ⇄    CH₃CHOHCOO⁻   +    H⁺

ionisation constant = 1.36 x 10⁻⁴ .

molecular weight of lactic acid = 90 g

moles of acid used = 20 / 90

= .2222

it is dissolved in one litre so molar concentration of lactic acid formed

C = .2222M

Let n be the fraction of moles ionised  

CH₃CHOHCOOH    ⇄    CH₃CHOHCOO⁻   +    H⁺

C  - nC                                          nC                  nC

By definition of ionisation constant Ka

Ka = nC x nC / C - nC

= n²C ( neglecting n in the denominator )

n² x .2222 = 1.36 x 10⁻⁴

n = 2.47  x 10⁻²

nC = 2.47  x 10⁻² x .2222

= 5.5 x 10⁻³

So concentration of hydrogen or hydronium ion = 5.5  x 10⁻³ g ion per litre .

The concentration of hydrogen or hydronium ion = 5.5  x 10⁻³ g ion per liter .

Ionization of lactic acid can be represented as:

CH₃CHOHCOOH⇄ CH₃CHOHCOO⁻  + H⁺

Given:

ionization constant = 1.36 x 10⁻⁴

mass= 20.0 g

Now, Molecular weight of lactic acid = 90 g

[tex]\text{Number of moles}=\frac{20}{90} =0.22mol[/tex]

It is dissolved in 1.00L so molar concentration of lactic acid formed will be

C = 0.22M

Consider "n" to be the fraction of moles ionized  

CH₃CHOHCOOH    ⇄    CH₃CHOHCOO⁻   +    H⁺

C  - nC                                          nC                  nC

By definition of ionization constant Ka

[tex]K_a =\frac{nC*nC}{C-nC}[/tex]

[tex]K_a= n^2C[/tex] ( neglecting n in the denominator )

On substituting the values we will get:

[tex]n^2 *0.22 = 1.36 *10^{-4}\\\\n = 2.47 * 10^{-2}[/tex]

To find the concentration of hydronium ion in the solution,

[tex]nC = 2.47 *10^{-2} *0.22\\\\nC= 5.5 * 10^{-3}[/tex]

So, concentration of hydrogen or hydronium ion = 5.5  x 10⁻³ g ion per liter.  

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2) 2.5 mol of an ideal gas at 20 oC under 20 atm pressure, was expanded up to 5 atm pressure via; (a) adiabatic reversible and (b) adiabatic irreversible process. Calculate the values of w, q, ΔU, ΔH for each process. (Cv = 5 cal / mol.K ≈ 5/2 R; R ≈ 2 cal / mol.K) (Please find the desired values by making the corresponding derivations

Answers

Answer:

a) for adiabatic reversible, ΔU(internal energy is constant) = 0, ΔH = 0(no heat is entering or leaving the surrounding)

workdone (w) = -8442.6 J  ≈ -8.443 KJ

heat transferred (q) of the ideal gas = - w

q = 8.443 KJ

b) For ideal gas at adiabatic reversible, Internal energy (ΔU) = 0 and enthalpy (ΔH) = 0

the workdone(w) in the ideal gas= - 4567.5 J  ≈ - 4.57 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

Explanation:

given

mole of an ideal gas(n) = 2.5 mol

Temperature (T) = 20°C

= (20°C + 273) K  = 293 K

Initial pressure of the ideal gas(P₁) = 20 atm

Final pressure of the ideal gas(P₂) = 5 atm.

2) (a)for adiabatic reversible process,

note: adiabatic process is a process by which no heat or mass is transferred between the system and its surrounding.

Work done (w) = nRT ln[tex]\frac{P_{1} }{P_{2} }[/tex]

= 2.5 mol × 8.314 J/mol K × 293 K × ln[tex]\frac{5atm}{20atm}[/tex]

= 6090.01 J × [-1.3863]

= -8442.6 J  ≈ -8.443 KJ

So, the work done (w) of ideal gas = -8.443 KJ

For ideal gas at adiabatic reversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-8.443 KJ)

q = 8.443 KJ

heat transfer (q) of the ideal gas = 8.443 KJ

(b) For adiabatic irreversible, the temperature T remains constant because the internal energy U depends only on temperature T. Since at constant temperature, the entropy is proportional to the volume, therefore, entropy will increase.

Work done (w) = -nRT(1 - ln[tex]\frac{P_{1} }{P_{2} }[/tex] )

= - 2.5 mol × 8.314 J / mol K× 293 K × [1- (5 atm /20 atm)]

= - 6090.01 J × 0.75

= - 4567.5 J  ≈ - 4.57 KJ

∴work done(w) of an ideal gas = - 4.57 KJ

For ideal gas at adiabatic Irreversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-4.5675 KJ)

q = 4.5675 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

what is the meaning of the word tetraquark?​

Answers

Answer:

A tetraquark in physics is an exotic meson composed of four valence quarks.

Explanation:

It has been suspected to be allowed by quantum chromodynamics, the modern story of strong interactions.

Hope it helps.

Air contains nitrogen, oxygen, argon, and trace gases. Ifthe partial pressure of nitrogen is 592 mm Hg, oxygen is160 mm Hg, argon is 7 mm Hg, and trace gas is 1 mm Hg,what is the atmospheric pressure

Answers

Answer:

760 mmHg

Explanation:

Step 1: Given data

Partial pressure of nitrogen (pN₂): 592 mmHgPartial pressure of oxygen (pO₂): 160 mmHgPartial pressure of argon (pAr): 7 mmHgPartial pressure of the trace gas (pt): 1 mmHg

Step 2: Calculate the atmospheric pressure

Since air is a gaseous mixture, the atmospheric pressure is equal to the sum of the gases that compose it.

P = pN₂ + pO₂ + pAr + pt = 592 mmHg + 160 mmHg + 7 mmHg + 1 mmHg = 760 mmHg

Why was it important to establish the Clean Air Act?

Answers

Answer: The Clean Air Act was important because it emphasized cost-effective methods to protect the air; encouraged people to study the effects of dirty air on human health; and created a regulation that makes any activities that pollute the air illegal.

Explanation:

Answer:

Clean Air Act (CAA), U.S. federal law, passed in 1970 and later amended, to prevent air pollution and thereby protect the ozone layer and promote public health. The Clean Air Act (CAA) gave the federal Environmental Protection Agency (EPA) the power it needed to take effective action to fight environmental pollution.

Drag each image to the correct location on the model. Each image can be used more than once. Apply the rules and principles of electron configuration to draw the orbital diagram of aluminum. Use the periodic table to help you.

Answers

Answer:

The answer to your question is given below.

Explanation:

Aluminium has atomic number of 13. Thus, the electronic configuration of aluminium can be written as:

Al (13) —› 1s² 2s²2p⁶ 3s²3p¹

The orbital diagram is shown on the attached photo.

Answer: screen shot

Explanation:

Predict the order of acid strengths in the following series of cationic
species: CH3CH2NH3
+, CH3CH=NH2

Answers

Answer:

CH3CH=NH2+>CH3CH2NH3+

Explanation:

If we look at the both species under review, we will realize that they are both amines hence they possess the polar N-H bond.

Electrons are ordinarily attracted towards the nitrogen atom hence making both compounds acidic. It is worthy of note that certain features of a compound may make it more acidic than another of close structural proximity. 'More acidic' simply means that the proton is more easily lost.

CH3CH=NH2+ contains an sp2 hybridized carbon atom which is highly electronegative and further withdraws electron density from the N-H bond thereby leading to a greater acidity of CH3CH=NH2+ compared to CH3CH2NH3+

what is the difference between acidic and basic protein​

Answers

Answer:

Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.

Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10 genes.

Answer:

Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.

Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10

Explanation:

Calculate the pH of a buffer solution obtained by dissolving 18.0 g of KH2PO4(s) and 35.0 g of Na2HPO4(s) in water and then diluting to 1.00 L.

Answers

Answer:

pH of the buffer is 7.48

Explanation:

The H₂PO₄⁻/HPO₄²⁻ buffer has a pKa of 7.21. You can find pH of this buffer following H-H equation:

pH = pKa + log [A⁻] / [HA]

pH = 7.21 + log [HPO₄²⁻] / [ H₂PO₄⁻]

Where [] represents molarity of each specie of the buffer and, as volume is 1.00L, also represents its moles.

Thus, to find pH of the buffer we need to calculate moles of each specie, thus

Moles of 18.0g of KH₂PO₄(Molar mass: 136.086g/mol) = moles of H₂PO₄⁻ are:

18.0g KH₂PO₄ ₓ (1mol / 136.086g) = 0.132 moles of KH₂PO₄= H₂PO₄⁻

Moles of 35.0g of Na₂HPO₄(Molar mass: 141.96g/mol) = moles of HPO₄²⁻ are:

35.0g Na₂HPO₄ ₓ (1mol / 141.96g) = 0.2465 moles of Na₂HPO₄= HPO₄²⁻

Replacing in H-H equation:

pH = 7.21 + log [HPO₄²⁻] / [ H₂PO₄⁻]

pH = 7.21 + log [0.2465] / [0.132]

pH = 7.48

pH of the buffer is 7.48

A chemistry student weighs out of formic acid into a volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with solution. Calculate the volume of solution the student will need to add to reach the equivalence point. Round your answer to significant digits.

Answers

The given question is incomplete, the complete question is:

A chemistry student weighs out 0.0349g of formic acid HCHO2 into a 250.mL volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with 0.1500M NaOH solution. Calculate the volume of NaOH solution the student will need to add to reach the equivalence point. Round your answer to 3 significant digits.

Answer:

The correct answer is 5.06 ml.

Explanation:

Based on the given information, the weight of formic acid given is 0.0349 grams. The volume of formic acid of V1 given is 250 ml. The molecular mass of formic acid is 46 grams per mole. Now the molarity of formic acid will be,  

[HCOOH] = weight * 1000 / molecular mass * volume (ml)

= 0.0349 * 1000 / 46 * 250

= 0.003035 M or M1

The molarity of NaOH given is 0.1500 M or M2

Let us assume that the volume needed to attain equivalence point is V2 ml.  The volume V2 can be determined by using the dilution equation,  

M1V1 = M2V2

V2 = M1V1/M2  

V2 = 0.003035 * 250 / 0.1500

V2 = 5.06 ml.  

Hence, the volume of NaOH needed is 5.06 ml.  

Identify a process that is NOT reversible. A. melting of steel B. freezing water C. melting of ice D. frying an egg E. deposition of carbon dioxide (gas to solid)

Answers

I’m pretty sure it would be D. Frying an egg

A process that is not a reversible reaction is frying an egg.

What are reversible reactions?

Reversible reactions are those reactions in which product will again change into the reactant.

Melting of steel and ice are reversible reaction as after cooling again we get the original state of steel and ice.Freezing of water is also reversible reaction as at normal temperature we get the original state of water.Deposition of carbon dioxide is also a reversible reaction.Frying an egg is a non reversible reaction as after frying an egg we didn't get the original egg again.

Hence option (D) is correct.

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1. Suppose 1.00 g of NaOH is used to prepare 250 mL of an NaOH solution. Compare the expected molarity of this solution to the actual average molarity you measured in the standardization. What do you notice? 2. Do you think the results would have been more accurate if a different type of acid or base were used in the standardization? Why, or why not? 3. There are many different primary standards that could be used in a standardization titration. What are the criteria for a primary standard?

Answers

Answer:

See explanation

Explanation:

The calculated concentration of the sodium hydroxide is;

Number of moles= mass/molar mass = 1g/40gmol-1 = 0.025 moles

Concentration= number of moles/volume= 0.025×1000/250 = 0.1 M

This calculated concentration will be different from the molarity of NaOH obtained by standardization with acid. The result will not be more accurate if a different acid is used for the standardization this is because sodium hydroxide is deliquescent and absorbs moisture thereby leading to inaccuracy in the calculated molarity.

Any substance that must be used as a primary standard must not absorb moisture, it must be stable and it must be a substance in its pure form.

Need help finding major products

Answers

Answer:

Explanation:

RX + AgNO₃ = R⁺ ( carbocation ) + AgX + NO₃⁻

C₂H₅OH ( a nucleophile ) + R⁺ = ROC₂H₅

C₅H₁₁X + AgNO₃ = C₅H₁₁⁺ + AgX + NO₃⁻

In the first case carbocation produced is CH₃CH₂CH₂CH₂CH₂⁺

CH₃CH₂CH₂CH₂CH₂⁺ ⇒  CH₃CH₂CH₂C⁺HCH₃ ( secondary carbocation more stable )

CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃

Hence option D is correct .

b )

In the second case carbocation produced is

CH₃CH₂CH₂CH⁺CH₃

CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃

The product formed is same as in case of first

Option B is correct

Limiting reagent problem. How many grams of H2O is produced from 40.0 g N2O4 and 25.0 g N2H4. N2O4 (l) + 2 N2H4 (l) → 3 N2 (g) + 4 H2O(g)

Answers

Answer:

28.13 g of H2O.

Explanation:

We'll begin by writing the balanced equation for the reaction. This is illustrated below:

N2O4(l) + 2N2H4 (l) → 3N2(g) + 4H2O(g)

Next, we shall determine the masses of N2O4 and N2H4 that reacted and the mass of H2O produced from the balanced equation.

This is illustrated below:

Molar mass of N2O4 = (14x2) + (16x4) = 92 g/mol

Mass of N2O4 from the balanced equation = 1 x 92 = 92g

Molar mass of N2H4 = (14x2) + (4x1) = 32 g/mol

Mass of N2H4 from the balanced equation = 2 x 32 = 64 g

Molar mass of H2O = (2x1) + 16 = 18 g/mol

Mass of H2O from the balanced equation = 4 x 18 = 72 g

Summary:

From the balanced equation above,

92 g of N2O4 reacted with 64 g of N2H4 to produce 72 g of H2O.

Next, we shall determine the limiting reactant.

This can be obtained as follow:

From the balanced equation above,

92 g of N2O4 reacted with 64 g of N2H4.

Therefore, 40 g of N2O4 will react with = (40 x 64)/92 = 27.83 g of N2H4.

From the calculations made above, we can see that it will take a higher mass i.e 27.83 g than what was given i.e 25 g of N2H4 to react completely with 40 g of N2O4.

Therefore, N2H4 is the limiting reactant and N2O4 is the excess reactant.

Finally, we shall determine the mass of H2O produced from the reaction of 40.0 g of N2O4 and 25.0 g of N2H4.

In this case the limiting reactant will be used because it will produce the maximum amount of H2O as all of it is consumed in the reaction.

The limiting reactant is N2H4 and the mass of H2O produced can be obtained as follow:

From the balanced equation above,

64 g of N2H4 reacted to produce 72 g of H2O.

Therefore, 25 g of N2H4 will react to produce = (25 x 72)/64 = 28.13 g of H2O.

Therefore, 28.13 g of H2O were obtained from the reaction.

After the reaction between sodium borohydride and the ketone is complete, the reaction mixture is treated with water and H2SO4 to produce the desired alcohol. Explain the reaction by clearly indicating the source of the hydrogen atom that ends up on the oxygen

Answers

Answer:

The hydrogen can be gotten from the added Acid or water during "workup".

Explanation:

Basically we can say that the reaction describe in this question is a Reduction reaction because of the chemical compound called sodium borohydride. In the reaction described above we can see that there is a Reduction of ketone to alcohol by the compound; sodium borohydride.

For the reduction Reaction to occur the C-O bond must break so as to enable the formation of O-H bond and C-H bond.

So, "the reaction mixture is treated with water and H2SO4 to produce the desired alcohol", thus, the oxygen will definitely pick up the hydrogen from H2SO4 or H2O.

Carbon-14 has a half-life of 5720 years and this is a fast-order reaction. If a piece of wood has converted 75 % of the carbon-14, then how old is it?

Answers

Answer:

11445.8years

Explanation:

Half-life of carbon-14 = 5720 years

First we have to calculate the rate constant, we use the formula :

When the following molecular equation is balanced using the smallest possible integer coefficients, the values of these coefficients are:
P2O5 (s) + H2O (l) =H3PO4 (aq)
The balanced chemical equation for the reaction between hydrogen sulfide and oxygen is:
2H2S(g) + 3O2(g) =2H2O(l) + 2SO2(g)
We can interpret this to mean:
3moles of oxygen and_______moles of hydrogen sulfide react to produce______moles of water and_______ moles of sulfur dioxide.

Answers

Answer:

1. The coefficients are: 1, 3, 2

2. From the balanced equation, we obtained the following:

3 moles oxygen, O2 reacted.

2 moles of Hydrogen sulfide, H2S reacted.

2 moles of water were produced.

2 moles of sulphur dioxide, SO2 were produced.

Explanation:

1. Determination of the coefficients of the equation.

This is illustrated below:

P2O5(s) + H2O(l) <==> H3PO4(aq)

There are 2 atoms of P on the left side and 1 atom on the right side. It can be balance by putting 2 in front of H3PO4 as shown below:

P2O5(s) + H2O(l) <==> 2H3PO4(aq)

There are 2 atoms of H on the left side and 6 atoms on the right side. It can be balance by putting 3 in front of H2O as shown below:

P2O5(s) + 3H2O(l) <==> 2H3PO4(aq)

Now the equation is balanced.

The coefficients are: 1, 3, 2.

2. We'll begin by writing the balanced equation for the reaction. This is given below:

2H2S(g) + 3O2(g) => 2H2O(l) + 2SO2(g)

From the balanced equation above,

3 moles of oxygen, O2 reacted with 2 moles of Hydrogen sulfide, H2S to produce 2 moles of water, H2O and 2 moles of sulphur dioxide, SO2.

Cyclohexane (C6H12) undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (CH3C5H9) according to the equation: C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25°C for this reaction predict the direction in which the system

Answers

Answer:

The reaction will shift leftwards, towards the formation of more cyclohexane at 25 °C

Explanation:

Hello,

In this case, for the given chemical reaction, we can write the law of mass action (equilibrium expression) as shown below:

[tex]Kc=\frac{[CH_3C_5H_9]}{[C_6H_{12} ]}[/tex]

Thus, since Kc < 1, we can conclude there are more moles of cyclohexane at equilibrium (denominator is greater than numerator), therefore, the reaction will shift leftwards, towards the formation of more cyclohexane at 25 °C.

Best regards.

below are three reactions showing how chlorine from CFCs (chlorofluorocarbons) destroy ozone (O3) in the stratosphere. Ozone blocks harmful ultraviolet radiation from reaching earth’s surface. Show how these 3 equations sum to produce the net equation for the decomposition of two moles of ozone to make three moles of diatomic oxygen (2 O3→ 3 O2), and calculate the enthalpy change. (6 points) R1 O2 (g) → 2 O (g) ΔH1°= 449.2 kJ R2 O3 (g) + Cl (g) → O2 (g) + ClO (g) ΔH2° = -126 kJ R3 ClO (g) + O (g) → O2 (g) + Cl (g) ΔH3°= -268 kJ

Answers

Answer:

ΔH = -338.8kJ

Explanation:

it is possible to sum the enthalpy changes of some reactions to obtain the enthalpy change of the whole reaction (Hess's law).

Using the reactions:

R₁ O₂(g) → 2O(g) ΔH₁°= 449.2 kJ

R₂ O₃(g) + Cl(g) → O₂(g) + ClO(g) ΔH₂° = -126 kJ

R₃ ClO (g) + O (g) → O₂ (g) + Cl (g) ΔH₃°= -268 kJ

By the sum 2R₂ + 2R₃:

(2R₂ + 2R₃) = 2O(g) + 2O₃(g) → 4O₂(g)

ΔH = 2ₓ(-126kJ) + (2ₓ-268kJ) = -788kJ

Now, this reaction + R₁

2O₃(g) → 3O₂(g)

ΔH = -768kJ + 449.2kJ

ΔH = -338.8kJ

Which resulted from the study of chemistry?

A) Alchemy to turn base metals into noble metals

B) The understanding of earth, air, fire, and water as the basic components of matter.

C) A supernatural, mystical view of the world.

D) Discovering the role of oxygen in combustion

Answers

the answer is C
A supernatural, mystical view of the world

11. How did the solubility product constant Ksp of KHT in pure water compare to its solubility product constant Ksp of KHT in KCl solution? Are these results what you would expect? Why?

Answers

Answer:

Explanation:

KHT is a salt which ionises in water as follows

KHT ⇄ K⁺ + HT⁻

Solubility product Kw= [ K⁺ ] [ HT⁻ ]

product of concentration of K⁺ and HT⁻ in water

In KCl solution , the solubility product of KHT will be decreased .

In KCl solution , there is already presence of K⁺  ion in the solution . So

in the equation  

[ K⁺ ] [ HT⁻ ]  = constant

when K⁺ increases [ HT⁻ ] decreases . Hence less of KHT dissociates due to which its  solubility decreases . It is called common ion effect . It is so because here the presence of common ion that is K⁺ in both salt to be dissolved and in solvent , results in decrease of solubility of the salt .

An acetic acid buffer solution is required to have a pH of 5.27. You have a solution that contains 0.010 mol of Acetic acid. What molarity of sodium acetate will you need to add to the solution

Answers

Answer:

Molarity of sodium acetate you will need to add is 0.0324M

Explanation:

Assuming volume of the buffer is 1L.

The pH of a buffer can be determined using Henderson-Hasselbalch equation:

pH = pKa + log [A⁻] / [HA]

Where pKa is pKa of the weak acid,  [A⁻] molar concentration of conjugate base and [HA] molar concentration of weak acid

Replacing for the acetic buffer (pKa = 4.76):

pH = 4.76 + log [Sodium Acetate] / [Acetic Acid]

As you have 0.010 moles of acetic acid in 1L:

[Acetic Acid] = 0.010mol / 1L = 0.010M

And you require a pH of 5.27:

5.27 = 4.76 + log [Sodium Acetate] / [0.010M]

0.51 = log [Sodium Acetate] / [0.010M]

10^0.51 = [Sodium Acetate] / [0.010M]

3.236 =  [Sodium Acetate] / [0.010M]

3.236 [0.010M] = [Sodium Acetate]

0.0324M = [Sodium Acetate]

Molarity of sodium acetate you will need to add is 0.0324M

Suppose you titrate 25.00 mL of 0.200 M KOBr with 0.200M H2SO4. The pH at half-equivalence point is 7.75 a). What is the initial pH of the 25.00mL of 0.200M KOBr mentioned above

Answers

Answer:

Approximately [tex]10.88[/tex].

Explanation:

Equilibrium constant

[tex]\rm OBr^{-}[/tex] can act as a weak Bronsted-Lowry base:

[tex]\rm OBr^{-}\; (aq) + H_2O\; (l) \rightleftharpoons HOBr\; (l) + OH^{-}\; (aq)[/tex].

(Side note: the state symbol of [tex]\rm HOBr[/tex] in this equation is [tex]\rm (l)[/tex] (meaning liquid) because [tex]\rm HOBr[/tex] is a weak acid.)

However, the equilibrium constant of this reaction, [tex]K_\text{eq}[/tex], isn't directly given. The idea is to find [tex]K_\text{eq}[/tex] using the [tex]\rm pH[/tex] value at the half-equivalence point. Keep in mind that this system is at equilibrium all the time during the titration. If temperature stays the same, then the same [tex]K_\text{eq}[/tex] value could also be used to find the [tex]\rm pH[/tex] of the solution before the acid was added.

At equilibrium:

[tex]\displaystyle K_\text{eq} = \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]}[/tex].

At the half-equivalence point of this titration, exactly half of the base, [tex]\rm OBr^{-}[/tex], has been converted to its conjugate acid, [tex]\rm HOBr[/tex]. Therefore, the half-equivalence concentration of [tex]\rm OBr^{-}[/tex] and [tex]\rm HOBr[/tex] should both be equal to one-half the initial concentration of [tex]\rm OBr^{-}[/tex].

As a result, the half-equivalence concentration of [tex]\rm OBr^{-}[/tex] and [tex]\rm HOBr[/tex] should be the same. The expression for [tex]K_\text{eq}[/tex] can thus be simplified:

[tex]\begin{aligned}& K_\text{eq} \\&= \frac{\left(\text{half-equivalence $[\rm HOBr\; (l)]$}\right)\cdot \left(\text{half-equivalence $[\rm OH^{-}\; (aq)]$}\right)}{\text{half-equivalence $[\rm OBr^{-}\; (l)]$}}\\ &=\text{half-equivalence $[\rm OH^{-}\; (aq)]$}\end{aligned}[/tex].

In other words, the [tex]K_\text{eq}[/tex] of this system is equal to the [tex]\rm OH^{-}[/tex] concentration at the half-equivalence point. Assume that [tex]\rm p\mathnormal{K}_\text{w}[/tex] the self-ionization constant of water, is [tex]14[/tex]. The concentration of [tex]\rm OH^{-}[/tex] can be found from the [tex]\rm pH[/tex] value:

[tex]\begin{aligned}& \text{half-equivalence $[\rm OH^{-}\; (aq)]$} \\ &= 10^{\rm pH - p\mathnormal{K}_\text{w}}\;\rm mol \cdot L^{-1} \\ &= 10^{7.75 - 14}\; \rm mol \cdot L^{-1}\\ &= 10^{-6.25}\; \rm mol \cdot L^{-1}\end{aligned}[/tex].

Therefore, [tex]\begin{aligned} K_\text{eq} &= 10^{-6.25}\end{aligned}[/tex].

Initial pH of the solution

Again, since [tex]\rm KOBr[/tex] is a soluble salt, all that [tex]0.200\; \rm M[/tex] of [tex]\rm KOBr[/tex] in this solution will be in the form of [tex]\rm K^{+}[/tex] and [tex]\rm OBr^{-}[/tex] ions. Before any hydrolysis takes place, the concentration of [tex]\rm OBr^{-}[/tex] should be equal to that of [tex]\rm KOBr[/tex]. Therefore:

[tex]\text{$[\rm OBr^{-}\; (aq)]$ before hydrolysis} = 0.200\; \rm M[/tex].

Let the equilibrium concentration of [tex][\rm OH^{-}\; (aq)][/tex] be [tex]x\; \rm M[/tex]. Create a RICE table for this reversible reaction:

[tex]\begin{array}{c|ccccccc} & \rm OBr^{-}\; (aq) &+&\rm H_2O\; (l)& \rightleftharpoons & \rm HOBr\; (l)& + & \rm OH^{-}\; (aq) \\ \textbf{I}& 0.200\; \rm M & & & & 0 \; \rm M & & 0\; \rm M \\ \textbf{C} & -x\; \rm M & & & & +x \; \rm M & & +x\; \rm M \\ \textbf{E}& (0.200 + x)\; \rm M & & & & x \; \rm M & & x\; \rm M \end{array}[/tex].

Assume that external factors (such as temperature) stays the same. The [tex]K_\text{eq}[/tex] found at the half-equivalence point should apply here, as well.

[tex]\displaystyle K_\text{eq} = \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]}[/tex].

At equilibrium:

[tex]\displaystyle \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]} = \frac{x^2}{0.200 + x}[/tex].

Assume that [tex]x[/tex] is much smaller than [tex]0.200[/tex], such that the denominator is approximately the same as [tex]0.200[/tex]:

[tex]\displaystyle \frac{[\rm HOBr\; (l)]\cdot [\rm OH^{-}\; (aq)]}{[\rm OBr^{-}\; (aq)]} = \frac{x^2}{0.200 + x} \approx \frac{x^2}{0.200}[/tex].

That should be equal to the equilibrium constant, [tex]K_\text{eq}[/tex]. In other words:

[tex]\displaystyle \frac{x^2}{0.200} \approx K_\text{eq} = 10^{-6.25}[/tex].

Solve for [tex]x[/tex]:

[tex]x \approx 3.35\times 10^{-4}[/tex].

In other words, the [tex]\rm OH^{-}[/tex] before acid was added was approximately [tex]3.35\times 10^{-4}\; \rm M[/tex], which is the same as [tex]3.35\times 10^{-4}\; \rm mol \cdot L^{-1}[/tex]. Again, assume that [tex]\rm p\mathnormal{K}_\text{w} = 14[/tex]. Calculate the [tex]\rm pH[/tex] of that solution:

[tex]\begin{aligned}\rm pH &= \rm p\mathnormal{K}_\text{w} + \log [\mathrm{OH^{-}}] \approx 10.88\end{aligned}[/tex].

(Rounded to two decimal places.)

cetylene gas is often used in welding torches because of the very high heat produced when it reacts with oxygen gas, producing carbon dioxide gas and water vapor. Calculate the moles of oxygen needed to produce of water.

Answers

Answer:

0.60 mol

Explanation:

There is some info missing. I think this is the original question.

Acetylene gas is often used in welding torches because of the very high heat produced when it reacts with oxygen gas, producing carbon dioxide gas and water vapor. Calculate the moles of oxygen needed to produce 1.5 mol of water.

Step 1: Given data

Moles of water required: 1.5 mol

Step 2: Write the balanced equation

C₂H₂(g) + 2.5 O₂(g) ⇒ 2 CO₂(g) + H₂O(g)

Step 3: Calculate the moles of oxygen needed to produce 1.5 mol of water

The molar ratio of O₂ to H₂O is 2.5:1. The moles of oxygen needed to produce 1.5 mol of water are (1/2.5) × 1.5 mol = 0.60 mol

how salt solution can be determined by using hydrometer​

Answers

Answer:

Salt solution may be calculated by measuring the specific gravity of a sample of water using a hydrometer.

Hope this answer correct (^^)....

Identify a homogeneous catalyst:

a. SO2 over vanadium (V) oxide
b. H2SO4 with concentrated HCl
c. Pd in H2 gas
d. N2 and H2 catalyzed by Fe
e. Pt with methane

Answers

Answer:

b, H2SO4 with HCl, as they are both liquid acids

A sample of neon gas at a pressure of 0.609 atm and a temperature of 25.0 °C, occupies a volume of 19.9 liters. If the gas is compressed at constant temperature to a
volume of 12.7 liters, the pressure of the gas sample will be
atm.​

Answers

Answer:

The pressure of the gas sample will be  0.954 atm.​

Explanation:

Boyle's law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; conversely if the pressure decreases, the volume increases.

Boyle's law is expressed mathematically as:

Pressure * Volume = constant

o P * V = k

To determine the change in pressure or volume during a transformation at constant temperature, the following is true:

P1 · V1 = P2 · V2

That is, the product between the initial pressure and the initial volume is equal to the product of the final pressure times the final volume.

In this case:

P1= 0.609 atmV1= 19.9 LP2=?V2= 12.7 L

Replacing:

0.609 atm* 19.9 L= P2* 12.7 L

Solving:

[tex]P2=\frac{0.609 atm* 19.9 L}{12.7 L}[/tex]

P2= 0.954 atm

The pressure of the gas sample will be  0.954 atm.​

A student mixes wants to prepare 24.1 mmol of benzamide from benzoyl chloride and NH4OH. If the student uses excess 15 M NH4OH, how many mL of Benzoyl chloride must be used

Answers

Answer:

2.81mL

Explanation:

Based on the reaction:

C₆H₃COCl + 2NH₃ → C₆H₅CONH₂ + NH₄Cl

Benzoyl chloride + ammonia → Benzamide

1 mole of benzoyl chloride in excess of ammonia produce 1 mole of Benzamide.

Thus, assuming a theoretical yield, to produce 24.1mmoles of benzamide you require 24.1mmoles of benzoyl chloride.

As molar mass of benzoyl chloride is 141g/mol, mg you require are:

mg Benzoyl chloride: 24.1mmol × (141mg / 1mmol) = 3398.1mg = 3.3981g of benzoyl chloride.

to convert this mass to mL, you require density of Benzoyl chloride (1.21g/mL). Thus, mL you need are:

3.3981g × (1mL / 1.21g) =

2.81mL

A student obtained a clean flask. She weighed the flask and stopper on an analytical balance and found the total mass to be 34.232 g. She then filled the flask with water and found the new mass to be 60.167 g. The temperature of the water was measured to be

Answers

Answer:

25.99mL is the volume internal volume of the flask

Explanation:

To complete the question:

The temperature of the water was measured to be 21ºC. Use this data to find the internal volume of the stoppered flask

The flask was filled with water, that means the internal volume of the flask is equal to the volume that the water occupies.

To find the volume of the water you need to find the mass and by the use of density of water at 21ºC (0.997992g/mL), you can find the volume of the flask, thus:

Mass water = Mass filled flask - Mass of clean flask

Mass water = 60.167g - 34.232g

Mass water = 25.935g of water.

To convert this mass to volume:

25.935g × (1mL / 0.997992g) =

25.99mL is the volume internal volume of the flask
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