the formation of the ___________ stressed/distorts chemical bonds to form a transition state, making the substrate more reactive and accelerating the reaction

The correct answer is (c) stays the same over time. This is because the presence of a solute (salt) in a solution reduces the vapor pressure of the solvent (water) and the concentration of the salt solution will not change over time assuming no evaporation or addition of more solute. The constant temperature and pressure conditions also ensure that there is no change in the equilibrium between the vapor and liquid phases, therefore the vapor pressure remains constant over time.

Since the temperature and pressure are held constant, there will be no changes in the system that would affect the vapor pressure. The presence of the salt may cause the vapor pressure to be lower than that of pure water, but it will not change over time under these conditions.

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Answer:

protons

Explanation:

The number of protons in the nucleus determines which element an atom is, while the number of electrons surrounding the nucleus determines which kind of reactions the atom will undergo.

The balanced titration reaction for the given reaction involving 0.0100 M Sn2+ in 1 M HCl with 0.0500 M Tl3+ is as follows:

2 Sn2+ (aq) + 3 Tl3+ (aq) → 2 Sn4+ (aq) + 3 Tl+ (aq)

The balanced titration reaction for the titration of 20.00 ml of 0.0100 m Sn2 in 1 m HCl with 0.0500 m Tl3 resulting in the formation of Sn4 and Tl can be written as:

2 Sn2+ + 2 Tl3+ + 2 H+ → 2 Sn4+ + 2 Tl+ + H2

The Pt indicator electrode and the saturated Ag|AgCl reference electrode are used to monitor the titration process.

1. Identify the reactants: Sn2+ and Tl3+
2. Identify the products: Sn4+ and Tl+
3. Balance the charges: 2 Sn2+ ions have a total charge of +4, while 3 Tl3+ ions have a total charge of +9. To balance the charges, multiply Sn2+ by 2 and Tl3+ by 3.
4. Write the balanced equation: 2 Sn2+ (aq) + 3 Tl3+ (aq) → 2 Sn4+ (aq) + 3 Tl+ (aq)

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The statement is true. Thiohemiacetals are thio analogs of hemiacetals, which are formed by the addition of a thiol (-SH) to a carbonyl group (C=O).

Thiohemiacetals can undergo hydrolysis to form an acyl thioester intermediate, which has a large free energy of hydrolysis. This is because the thioester bond is a high-energy bond, and the hydrolysis of this bond releases a large amount of energy. Therefore, the statement is true.

Thiohemiacetals are formed by the addition of a thiol (-SH) to a carbonyl group (C=O). This reaction is analogous to the formation of hemiacetals from aldehydes or ketones and alcohols. Thiohemiacetals are commonly used as intermediates in organic synthesis, particularly in the synthesis of sulfur-containing compounds.

Thiohemiacetals can undergo hydrolysis to form an acyl thioester intermediate. The hydrolysis reaction is catalyzed by an acid or a base. The acyl thioester intermediate has a large free energy of hydrolysis because the thioester bond is a high-energy bond.

The hydrolysis of this bond releases a large amount of energy, which can be harnessed by the cell to drive energy-requiring processes such as biosynthesis, muscle contraction, and nerve impulse transmission.

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All of the aluminum sulfide will be consumed in the reaction, and there will be no mass of it remaining.

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Both methods gave the same answer identifying hydrogen as the limiting reactant.

The second method is most usually used.

The second method seems easier because it involves only one step.

A limiting reactant in a chemical reaction is the reactant that is used up at the end of the reaction and subsequently, the reaction stops.

The limiting reactant produces the least amount of products among the other reactants.

Limiting reactants are important as they can serve as control points in chemical reactions.

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In a first order reaction, the rate of reaction is directly proportional to the concentration of the reactant.

In a first-order reaction, the rate of reaction is directly proportional to the concentration of the reactant raised to the power of 1. To express this relationship, you can use the following equation:

Rate = k[A]^1

Where:
- Rate is the rate of reaction
- k is the rate constant
- [A] is the concentration of the reactant

This means that as the concentration of the reactant increases, the rate of reaction also increases proportionally. Conversely, as the concentration of the reactant decreases, the rate of reaction decreases proportionally. This relationship is expressed mathematically as: rate of reaction = k[A], where k is the rate constant and [A] is the concentration of the reactant.

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To determine the pKa of MeC(O)CH2SPh, follow these steps:

Step 1: Identify the acidic group in the compound.
In MeC(O)CH2SPh, the acidic group is the hydrogen atom attached to the alpha-carbon (CH2) next to the carbonyl (C=O) group.

Step 2: Understand the pKa concept.
The pKa is a measure of the acidity of a compound. A lower pKa value indicates a stronger acid, while a higher value indicates a weaker acid.

Step 3: Consult a pKa table or database.
To find the exact pKa value of MeC(O)CH2SPh, you would need to consult a pKa table or database that provides this information for various compounds.

Step 4: Interpret the pKa value.
Once you have found the pKa value for MeC(O)CH2SPh, you can use it to understand the acidity of the compound compared to other similar compounds.

In summary, the pKa of MeC(O)CH2SPh can be found by identifying the acidic group in the compound, understanding the pKa concept, consulting a pKa table or database, and interpreting the obtained value.

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In 1911, astronomers Hertzsprung and Russell independently plotted the spectral class (temperature) against the luminosity (energy emited) for known stars. They discovered that the stars were grouped together in different regions on the graph. This graph is now known as the Hertzsprung- Russell Diagram (see attached image).

The HR diagram shows us that there are different types of stars and that stars evolve in different ways depending on their initial mass. This can tell us what reactions are occurring in the stars' cores.

Stars follow a distinct path as seen on the diagram, and evolve in the following ways:

- Main Sequence > red giant > planetary nebula > white dwarf

- Main Sequence > supergiant > supernova > blackhole/neutron star

- Main Sequence > white dwarf

Temperature: surface temperature of stars

Absolute magnitude: measure of the luminosity or brightness of a star

Luminosity: the relative magnitude, relative to the magnitude of our sun

Spectral Class: temperature group of stars. categorised into OBAFGKM. Stars on the left the the hottest.

Main Sequence: Majority of stars lie in the main sequence, including our sun. These stars are fusing hydrogen to helium in their cores.

Red giants/Super giants: consists of a small minority of stars found at the top right of the HR diagram. These are very large and luminous, but have a much cooler temperature.

White Dwarfs: consists of a majority of stars, found at the bottom left of the HR diagram. These have very low luminosity, despite relatively high surface temp. and undergo fusion. These will not evolve anymore and will continue until all energy is used up in its core, and die out.

Blue Giants: rare, short-lived stars, and very luminous, hot, bright, and massive. These are found in the top left of HR diagrams, and are fusing heavier elements in their cores. They don't last long and will quickly evolve into white dwarfs.

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In the given reaction, ClO- is acting as the oxidizing agent. This is because ClO- is gaining electrons and getting reduced while I- is losing electrons and getting oxidized.

In the reaction: 2H+(aq) + ClO-(aq) + 2 I-(aq) → Cl-(aq) + I2(aq) + H2O(l), the oxidizing agent is ClO-(aq).

Here's how it was derived:

1. Identify the oxidation states of each element in the reactants and products.
  - H+ has an oxidation state of +1
  - Cl in ClO- has an oxidation state of +1
  - O in ClO- has an oxidation state of -2
  - I- has an oxidation state of -1
  - Cl- has an oxidation state of -1
  - I in I2 has an oxidation state of 0

2. Determine which species undergoes a change in oxidation state.
  - I- changes from -1 to 0 in I2 (oxidation)
  - Cl in ClO- changes from +1 to -1 in Cl- (reduction)

3. Identify the oxidizing agent, which is the species that gets reduced and causes the oxidation of another species.
  - ClO- gets reduced (from +1 to -1) and causes the oxidation of I-, so ClO- is acting as the oxidizing agent.

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The purpose of the brief scene with the clown and the musicians is to provide comic relief and lighten the mood in a play or story. This explain that such scenes often serve as a contrast to more serious or intense moments, adding depth and variety to the overall narrative.

In order to determine the purpose of this scene, it may be necessary to examine the overall plot of the work, the characters involved, and the themes or motifs present in the narrative. By analyzing these factors, one may be able to arrive at a detailed answer regarding the significance of the clown and musicians scene.

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Unit conversion is the process of converting the measurement of a given amount between various units. 135 mm Hg = 0.177atm.

Unit conversion is the process of converting the measurement of a given amount between various units, often by multiplicative conversion factors that alter the value of the measured quantity without altering its effects.

The factor-label method, sometimes referred to as the unit-factor technique or the unity parenthesis method, is a popular approach for converting units using algebraic formulas. The factor-label approach uses conversion factors that are stated as fractions and are placed sequentially.

1 atm = 760.0 mm Hg,

135 mm Hg = 0.177atm

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The number of moles of H₂ gas used in the solar fuel cell experiment is approximately 0.00039 mol.

The ideal gas law can be used to solve this problem, which states that PV = nRT, where P is the pressure of the gas, V is the volume of the gas, n is the number of moles of gas, R is the gas constant, and T is the temperature of the gas in Kelvin.

We can rearrange this equation to solve for n:

n = PV/RT

The pressure of the gas is given as 1.00 atm and the temperature is 25°C, which is equivalent to 298 K. We need to convert the volume from milliliters to liters by dividing by 1000.

n = (1.00 atm)(9.0×10⁻⁶ m³)/(0.0821 L·atm/K·mol)(298 K) = 0.00039 mol

Therefore, approximately 0.00039 moles of H₂ gas were used in the solar fuel cell experiment.

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The boiling point of the 4 molal solutions of KBr would be increased by 2.048 °C from the boiling point of pure water.
The boiling point of a solution is dependent on the concentration of solute particles present in the solution. In this case, we are given that the solution contains a 4 molal concentration of KBr.

To determine the boiling point, we can use the equation ΔTb = Kb x molality, where ΔTb is the change in boiling point, Kb is the molal boiling point constant for water, and molality is the concentration of solute particles in mol/kg of solvent.

Substituting the given values, we get ΔTb = 0.512 °C/m x 4 molal = 2.048 °C.

This means that the solution would boil at a higher temperature than pure water. This concept is utilized in industries such as food processing and pharmaceuticals, where precise control of the boiling point of solutions is essential.

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Sanitary landfills are designed to create an interior environment where almost everything decomposes. However, due to the lack of oxygen in the landfill, decomposition is slow and often generates methane gas.

Sanitary landfills are not always simple to construct and maintain, as they require careful planning and management to prevent environmental damage. Overall, the goal of a sanitary landfill is to contain waste in a way that prevents contamination of surrounding soil and water while allowing for controlled decomposition. Sanitary landfills are built to create an interior environment where almost everything decomposes, which means that organic materials such as food waste, paper, and yard trimmings are broken down by bacteria and other microorganisms.

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The rate constant (k) of the first-order reaction is 0.0172 min^ -1, and the amount of hydrogen peroxide decomposed after 30 minutes is 29.7 ml.

a. To calculate the rate constant (k) of the first-order reaction, we can use the following formula:
    ln (Ct/Co) = -kt
    Where:
  - Ct is the concentration at time t
  - Co is the initial concentration
  - k is the rate constant
  - t is the time
    We can rearrange the formula to isolate k:
    k = - (ln (Ct/Co)) / t
    Substituting the given values, we get:
    k = - (ln (10.6/72.6)) / 50
    k = 0.0172 min^-1 (rounded to four significant figures)
    Therefore, the rate constant (k) of the first-order reaction is 0.0172 min^-1.

b. To calculate the amount of hydrogen peroxide decomposed after 30 minutes, we can use the first-order integrated     rate law:
ln (Co/Ct) = kt
Where:
- Co is the initial concentration
- Ct is the concentration at time t
- k is the rate constant
- t is the time
 We can rearrange the formula to isolate Ct:
 Ct = Co * e^(-kt)
 Substituting the given values, we get:

 Ct = 72.6 * e^(-0.0172*30)
 Ct = 42.9 ml (rounded to three significant figures)
 Therefore, the amount of hydrogen peroxide decomposed after 30 minutes is:
 72.6 ml - 42.9 ml = 29.7 ml (rounded to three significant figures)

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The nitro substituent preferentially occurs at the meta-position on methyl benzoate due to the electronic effects of the ester group present on the benzene ring. The ester group is a deactivating and meta-directing group.


In electrophilic aromatic substitution reactions, the substituents on the benzene ring can be classified as activating or deactivating, and ortho/para-directing or meta-directing. These classifications are based on the effect of the substituent on the electron density of the ring and the resonance structures formed during the reaction.

Methyl benzoate has an ester group (COOCH3) attached to the benzene ring. The carbonyl group (C=O) is electron-withdrawing due to its high electronegativity, and the resonance structures formed show electron density being pulled away from the ortho- and para-positions. As a result, the ester group is considered deactivating and meta-directing.



Due to the deactivating and meta-directing nature of the ester group, the nitro substituent preferentially occurs at the meta-position rather than the ortho- or para-positions, although some ortho- and para-substitution may still occur to a lesser extent.


the nitro substituent preferentially occurs at the meta-position on methyl benzoate because the ester group is a deactivating and meta-directing group. The electronic effects and resonance structures show that the ester group pulls electron density away from the ortho- and para-positions, directing the nitro group to the meta-position.

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The use of a mixture of solvents instead of only ether or only hexanes is often necessary to achieve the desired solubility and separation properties in organic chemistry experiments.

The choice of solvent(s) in an organic chemistry experiment is critical to the success of the reaction and the separation of products. Each solvent has different properties, such as polarity, boiling point, and solubility, that can affect the reaction and product formation.

For example, polar solvents like ether are good for dissolving polar compounds, while nonpolar solvents like hexanes are good for dissolving nonpolar compounds. In some cases, a single solvent may not provide the desired solubility or separation properties for a particular reaction.

In such cases, a mixture of solvents may be used to achieve the desired properties. For example, a mixture of ether and hexanes can provide both polar and nonpolar solubility, making it useful for reactions involving both polar and nonpolar compounds.

Additionally, a mixture of solvents can provide improved separation properties, as different solvents can selectively dissolve different compounds and allow for easier separation.

Overall, the use of a mixture of solvents instead of a single solvent is often necessary for organic chemistry experiments to achieve the desired solubility and separation properties and to optimize the reaction conditions.

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In the proper set-up for a conductivity titration, the end of the conductivity probe should be immersed in the reaction mixture.

Conductivity titration is a method used to determine the equivalence point of a reaction by measuring the change in conductivity of the reaction mixture. In this method, a conductivity probe is used to measure the electrical conductivity of the reaction mixture, which changes as the reaction progresses towards the equivalence point.

To set up the conductivity titration, a buret is set up with the solution of known concentration, and the solution of unknown concentration is placed in a beaker. The conductivity probe is then immersed in the solution in the beaker, and the buret is slowly titrated into the beaker until the equivalence point is reached.

During the titration, the conductivity probe should be continuously immersed in the solution to accurately measure the change in conductivity. The conductivity probe should not touch the bottom or sides of the beaker, as this could cause errors in the measurement. By properly setting up the conductivity probe, accurate measurements can be obtained to determine the equivalence point of the reaction.

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The molar absorption coefficient and color intensity are closely related.

The molar absorption coefficient refers to the measure of how much light is absorbed by a solution at a particular wavelength, and it is directly proportional to the concentration of the absorbing species in the solution. On the other hand, the color intensity of a solution is a measure of the strength of the color perceived by the human eye. The more light absorbed by a solution, the stronger the color intensity will be. Therefore, the higher the molar absorption coefficient, the more intense the color of the solution will appear to the human eye.

the relationship between the molar absorption coefficient and color intensity can be explained using the Beer-Lambert law. The Beer-Lambert law states that the absorbance (A) of a solution is directly proportional to its molar concentration (c) and the path length (l) through which light passes. The molar absorption coefficient (ε) is a constant that relates these variables: A = εcl.

In this equation, color intensity is represented by absorbance (A). A higher molar absorption coefficient (ε) means that a substance absorbs more light and appears more intensely colored at a given concentration. Therefore, the molar absorption coefficient and color intensity are directly related.

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We would need 2.635 moles of AIPO₄ to produce 168.6g of oxygen.

To calculate the number of moles of AIPO₄ required to produce 168.6g of oxygen, we need to use stoichiometry. From the balanced chemical equation, we know that 1 mole of AIPO₄ produces 2 moles of O₂. We can use the molar mass of O2 to convert the given mass of oxygen to moles:

Molar mass of O₂ = 32 g/mol

Moles of O₂ = mass of O2 / molar mass of O2

                     = 168.6 g / 32 g/mol

Moles of O₂ = 5.27 mol

Since 1 mole of AIPO₄ produces 2 moles of O₂, we can use the mole ratio to calculate the number of moles of AIPO4 needed:

Moles of AIPO₄ = Moles of O₂ / 2

Moles of AIPO₄ = 5.27 mol / 2

Moles of AIPO₄ = 2.635 mol

As a result, 2.635 moles of AIPO₄ are required to create 168.6g of oxygen.

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According to the information, the five most important criteria for selecting appropiate foods to grow in the Martial colony are water, space, yield, post haverst process, and kilocalories provided.

The five most important criteria for selecting appropriate foods to grow in the Martian colony are:

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I apologize, but you have not provided any specific information regarding the reaction, so I am unable to answer your question. Please provide more details or context so I can assist you better. electrochemical reaction. Based on the terms you provided, I will explain the process of electrolysis of water as an example.

Electrolysis of water, Equation of the reaction: 2H2O l → 2H2 g + O2 g Two half-reactions with voltages Oxidation anode half-reaction: 2H2O(l) → O2(g) + 4H+(aq) + 4e- ; E° = -1.23 V Reduction cathode half-reaction: 4H+(aq) + 4e- → 2H2(g)  E° = 0 Economics and environment concerns Electrolysis of water is an energy-intensive process, which means it can be expensive to perform on a large scale. Using renewable energy sources such as solar or wind power can help reduce the economic and environmental impact. Additionally, the production of hydrogen through electrolysis can be a clean and sustainable alternative to fossil fuels if the electricity used is derived from renewable sources.

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The ratio of [C₅H₅N]/[C₅H₅NH⁺] for pH  4.50, 5.00, 5.23, 5.50 are 0.19, 0.37, 1 and infinity, under the condition a solution that contains both C₅H₅N and C₅H₅NHNO₃.

The ratio [C₅H₅N]/[C₅H₅NH⁺] can be evaluated using the Henderson-Hasselbalch equation

pOH = pKb + log([C₅H₅NH⁺]/[C₅H₅N])

pOH = 14 - pH

pKb = -log(Kb)

Here

Kb = base dissociation constant of C₅H₅N.

For pH = 4.50:

pOH = 14 - 4.50 = 9.50

pKb = -log(1.7 x 10⁻⁹) = 8.77

[C₅H₅NH+]/[C₅H₅N] = [tex]10^{(pOH - pKb) }[/tex] = 5.4

[C₅H₅N]/[C₅H₅NH⁺] = 1/[C₅H₅NH⁺]/[C₅H₅N] = 1/5.4 = 0.19

For pH = 5.00:

pOH = 14 - 5.00 = 9.00

pKb = -log(1.7 x 10⁻⁹) = 8.77

[C₅H₅NH⁺]/[C₅H₅N]  = [tex]10^{(pOH - pKb) }[/tex] = 2.7

[C₅H₅N]/[C₅H₅NH⁺] = 1/[C₅H₅NH⁺]/[C₅H₅N] = 1/2.7 = 0.37

For pH = 5.23:

pOH = 14 - 5.23 = 8.77

pKb = -log(1.7 x 10⁻⁹) = 8.77

[C₅H₅NH⁺]/[C₅H₅N] = [tex]10^{(pOH - pKb) }[/tex] = 1

[C₅H₅N]/[C₅H₅NH⁺] = 1

For pH = 5.50:

pOH = 14 - 5.50 = 8.50

pKb = -log(1.7 x 10⁻⁹) = 8.77

[C₅H₅NH⁺]/[C₅H₅N] = [tex]10^{(pOH - pKb) }[/tex] ≈ 0

[C₅H₅N]/[C₅H₅NH⁺] ≈ infinity

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we would need 0.0025 moles of NaOH to reach the endpoint of the titration of the acetic acid unknown.
To determine the number of moles of NaOH necessary to reach the endpoint of the titration of acetic acid, you'll need some information from the experiment, such as the concentration of the NaOH solution and the volume of NaOH used.

To answer this question, we need to know the volume and concentration of the NaOH used in the titration of the acetic acid unknown. Once we have this information, we can calculate the number of moles of NaOH that were added to reach the endpoint of the titration.

Assuming that we have this information, we can use the following formula to calculate the number of moles of NaOH used:

moles NaOH = concentration of NaOH (in M) x volume of NaOH (in L)

For example, if we used 0.1 M NaOH and added 25 mL to reach the endpoint of the titration, the calculation would be:

moles NaOH = 0.1 M x 0.025 L
moles NaOH = 0.0025 moles

Moles of NaOH = (Concentration of NaOH) × (Volume of NaOH used)

After obtaining the moles of NaOH, you can use the stoichiometry of the reaction to find the moles of acetic acid. In the case of the reaction between NaOH and acetic acid, the ratio is 1:1.

Moles of acetic acid = Moles of NaOH

Knowing the moles of acetic acid, you can then determine the concentration of the unknown acetic acid solution using the volume of the solution titrated.

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The phosphonate group is acidic because it contains a hydrogen atom that is attached to an electronegative oxygen atom. This hydrogen atom can easily be removed in the presence of a weak base like potassium carbonate, which can deprotonate the phosphonate group.

Phosphonates are acidic because they contain phosphorus-oxygen (P=O) double bonds and P-OH groups. When a relatively weak base like potassium carbonate is used, the phosphonate gets deprotonated, and the acidic hydrogen from the P-OH group is removed. The resulting negative charge on the oxygen atom is stabilized through resonance with the P=O double bond, making the phosphonate acidic in nature.

Once deprotonated, the phosphonate group becomes negatively charged and more stable. This property of the phosphonate group makes it a useful functional group in many chemical reactions and biological processes.

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The step(s) that compose rationale for the cation Ag+ being absent in an unknown (but Pb+2 is present) are:

Step 1 involves adding KCl and HCl to the unknown solution, which should result in the formation of white precipitates of AgCl and PbCl2 if Ag+ and Pb+2 are present.

The absence of a white precipitate in step 1-A suggests that Ag+ may not be present, and this is supported by the fact that the precipitate dissolves in hot water, indicating it is not AgCl, which is insoluble in water.

In step 1-B, the addition of H2S produces a black precipitate of PbS, indicating the presence of Pb+2. The absence of a black precipitate in step 1-B also suggests that Ag+ may not be present.

Step 1-C involves adding K2CrO4 to the unknown solution to test for the presence of Pb+2, which should result in the formation of a yellow precipitate of PbCrO4. The absence of a yellow precipitate indicates that Pb+2 may not be present.

Step 2-B involves adding NH3 to the unknown solution, which should result in the formation of a dark blue solution if Ag+ is present. The absence of a dark blue color suggests that Ag+ may not be present.

The remaining steps (4, 5, 6, 7) involve the use of additional reagents to further differentiate between Ag+ and Pb+2. For example, the addition of KFe(CN)6 to the unknown solution should result in the formation of a reddish-brown precipitate if Ag+ is present, but not if Pb+2 is present.

Overall, by observing the results of these specific reactions with various reagents, it is possible to determine the presence or absence of specific cations in the unknown solution. In this case, the results suggest that Pb+2 is present, but Ag+ is not.

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The new volume of the sample of a gas in a balloon is 2.62 L.

To solve this problem, we will use Boyle's Law, which states that at a constant temperature, the pressure and volume of a gas are inversely proportional. The equation for Boyle's Law is P₁V₁ = P₂V₂, where P₁ and V₁ represent the initial pressure and volume, and P₂ and V₂ represent the final pressure and volume.

In our case,
P₁ = 749 torr
V₁ = 2.2 L
P₂ = 629 torr

We need to find V₂. To do this, we will rearrange the Boyle's Law equation to solve for V₂: V₂ = (P₁V₁) / P₂.

Now, we can plug in the given values:

V₂ = (749 torr × 2.2 L) / 629 torr

V₂ ≈ 2.62 L

The new volume of the gas in the balloon is approximately 2.62 liters. So, the correct answer from the provided choices is 2.62.

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The molar mass of the diprotic acid is 87.3 g/mol.

The equation we can use to solve this problem is:

m = mm * mol

where m is the mass of the diprotic acid (2.00 g), mm is the molar mass of the diprotic acid (what we're trying to find), and mol is the number of moles of the diprotic acid.

To find mol, we first need to find the number of moles of NaOH used in the titration. We can use the equation:

mol NaOH = M * V

where M is the concentration of NaOH (1.35 M) and V is the volume of NaOH used (34.0 mL or 0.034 L). Plugging in these values, we get:

mol NaOH = 1.35 M * 0.034 L = 0.0459 mol NaOH

Since the diprotic acid (H2A) reacts with two moles of NaOH, the number of moles of H2A is half of the number of moles of NaOH used in the titration:

mol H2A = 0.0459 mol NaOH / 2 = 0.0229 mol H2A

Now that we have mol, we can plug in all the values into the original equation:

2.00 g = mm * 0.0229 mol

Solving for mm, we get:

mm = 2.00 g / 0.0229 mol = 87.3 g/mol

Therefore, the molar mass is 87.3 g/mol.

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The correct pKa values for the substances are:
- CH₃CH₂COOH: 4.78
- NH₂CH₂COOH: 2.45
- SO₃H: 1.68

To assign the correct pKa value to each of the substances, we can match them as follows:

1. CH₃CH₂COOH: This is ethanoic acid (acetic acid), which has a pKa value of 4.78.
2. NH₂CH₂COOH: This is glycine, an amino acid, which has a pKa value of 2.45 for its carboxyl group.
3. SO₃H: This is a sulfonic acid group, which has a pKa value of 1.68.

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