Answer:
The new volume will be 808 L
Explanation:
Charles's law is a law that says that the volume of gas at constant pressure is directly proportional to its absolute temperature (in degrees Kelvin), that is, when the amount of gas and pressure are kept constant, the quotient between volume and temperature will always have the same value:
[tex]\frac{V}{T}=k[/tex]
Having a certain volume of gas V1 that is at a temperature T1 at the beginning of the experiment, by varying the volume of gas to a new value V2, the temperature will change to T2 and the following will be fulfilled:
[tex]\frac{V1}{T1} =\frac{V2}{T2}[/tex]
In this case:
V1= 625 LT1= 273 KV2= ?T2= 353 KReplacing:
[tex]\frac{625 L}{273 K} =\frac{V2}{353 K}[/tex]
Solving:
[tex]V2=353 K*\frac{625 L}{273 K}[/tex]
V2= 808 L
The new volume will be 808 L
Hydrogen Bonding with Water - Your Drug Lotensin Directions: Show the structure of your molecule below. Illustrate all ways that your molecule could form hydrogen bonds with water, either as a hydrogen donor or as a target (receiver) of hydrogen bonds from water. Do this by drawing bent water molecules as necessary and representing hydrogen bonds between water and the drug using dashed RED lines (---). Be sure that it is exactly clear which atoms on each molecule are involved in the hydrogen bonds. If your drug molecule is not capable of forming hydrogen bonds with water, fully explain why not below.
Answer:
See figure 1
Explanation:
For this question, we have to remember that a hydrogen bond is an interaction in which we have a partial attraction between a positive dipole and a negative dipole, and in this attraction, we have in the middle a hydrogen atom.
In this interaction, we can have a donor (positive dipole) or a receptor (negative dipole). The receptor is a heteroatom (an atom different to carbon or hydrogen) with high electronegativity. The donor is usually hydrogen atom bonded to the heteroatom.
I hope it helps!
Calculate the [H+] and pH of a 0.0040 M hydrazoic acid solution. Keep in mind that the Ka of hydrazoic acid is 2.20×10−5. Use the method of successive approximations in your calculations or the quadratic formula.
Answer:
[tex][H^+]=0.000285[/tex]
[tex]pH=3.55[/tex]
Explanation:
In this, we can with the ionization equation for the hydrazoic acid ([tex]HN_3[/tex]). So:
[tex]HN_3~<->~H^+~+~N_3^-[/tex]
Now, due to the Ka constant value, we have to use the whole equilibrium because this is not a strong acid. So, we have to write the Ka expression:
[tex]Ka=\frac{[H^+][N_3^-]}{[HN_3]}[/tex]
For each mol of [tex]H^+[/tex] produced we will have 1 mol of [tex]N_3^-[/tex]. So, we can use "X" for the unknown values and replace in the Ka equation:
[tex]Ka=\frac{X*X}{[HN_3]}[/tex]
Additionally, we have to keep in mind that [tex]HN_3[/tex] is a reagent, this means that we will be consumed. We dont know how much acid would be consumed but we can express a subtraction from the initial value, so:
[tex]Ka=\frac{X*X}{0.004-X}[/tex]
Finally, we can put the ka value and solve for "X":
[tex]2.2X10^-^5=\frac{X*X}{0.004-X}[/tex]
[tex]2.2X10^-^5=\frac{X^2}{0.004-X}[/tex]
[tex]X= 0.000285[/tex]
So, we have a concentration of 0.000285 for [tex]H^+[/tex]. With this in mind, we can calculate the pH value:
[tex]pH=-Log[H^+]=-Log[0.000285]=3.55[/tex]
I hope it helps!
The [H+] and pH of a 0.0040 M hydrazoic acid solution is 0.000296648 and 3.527759
pH based problem:What information do we have?
Hydrazoic acid solution = 0.0040 M
Ka of hydrazoic acid = 2.20 × 10⁻⁵
We know that weak acids
[H+] = √( Ka × C)
[H+] = √( 2.2 × 10⁻⁵ × 0.0040)
[H+] = 0.000296648
So,
pH = -log [H+]
pH = -log [0.000296648]
Using log calculator
pH = 3.527759
Find more information about 'pH'.
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You are given a sample of metal and asked to determine its specific heat. You weigh the sample and find that its weight is 30.0 N. You carefully add 1.25×10^4 J of heat energy to the sample and find that its temperature rises 15.0 °C. What is the sample's specific heat?
Answer:
272.33 J/Kg°C
Explanation:
Data obtained from the question include the following:
Weight of metal = 30 N
Heat used (Q) = 1.25×10⁴ J
Change in temperature (ΔT) = 15.0 °C.
Specific heat capacity (C) =..?
Next, we shall determine the mass of the metal.
The mass of the metal can be obtained as follow:
Weight (W) = mass (m) x acceleration due to gravity (g)
W = mg
Weight of metal = 30 N
Acceleration due to gravity = 9.8 m/s²
Mass (m) =..?
W = mg
30 = m x 9.8
Divide both side by 9.8
m = 30/9.8
m = 3.06 Kg
Finally, we shall determine the specific heat capacity of the metal as show below:
Heat used (Q) = 1.25×10⁴ J
Change in temperature (ΔT) = 15.0 °C.
Mass (m) = 3.06 Kg
Specific heat capacity (C) =..?
Q = mCΔT
1.25×10⁴ = 3.06 x C x 15
Divide both side by 3.06 x 15
C = (1.25×10⁴) / (3.06 x 15)
C = 272.33 J/Kg°C
Therefore, the specific heat capacity of metal is 272.33 J/Kg°C.
What may be expected when K < 1.0? Choose the THREE correct statements. The concentration of one or more of the reactants is small. The concentration of one or more of the products is small. The reaction will not proceed very far to the right. The reaction will generally form more reactants than products.
Answer:
The concentration of one or more of the products is small.
The reaction will not proceed very far to the right.
The reaction will generally form more reactants than products
Explanation:
We often write
K =[Products]/[Reactants]
Thus, if K is small
We have fewer products than reactants We have more reactants than products The position of equilibrium lies to the leftA. is wrong. Usually, if K < 1, the concentration of reactants is greater than that of the products.
Zinc bromide is considered which of the following?
A) molecular compound
B) atomic element
C) molecular element
D) ionic compound
Answer:
D
Explanation:
soluble in water and acidic14. A piece of titanium at 100.0°C was dropped into 50.0 g of water at 20.0°C. The final temperature of the system was 22.6°C. What is the mass of the titanium? (Specific Heat of titanium = 0.54 J/g°C)
Answer:
[tex]m_{Ti}=13.0g[/tex]
Explanation:
Hello,
In this case, based on the given, we can infer that as titanium is hot and water cold, it cools down whereas the water is heated up, therefore, in terms of heat, we have that the heat lost by the titanium is gained by the water:
[tex]-Q_{Ti}=Q_{H_2O}[/tex]
That in terms of mass, specific heat and temperatures is:
[tex]-m_{Ti}Cp_{Ti}(T_2-T_{Ti})=m_{H_2O}Cp_{H_2O}(T_2-T_{H_2O})[/tex]
In such a way, for computing the mass of titanium, considering the heat capacity of water 4.18 J/g°C, we have:
[tex]m_{Ti}=\frac{m_{H_2O}Cp_{H_2O}(T_2-T_{H_2O})}{-Cp_{Ti}(T_2-T_{Ti})} \\\\m_{Ti}=\frac{50.0g*4.18\frac{J}{g\°C}(22.6-20.0)\°C}{-0.54\frac{J}{g\°C}*(22.6-100.0)\°C} \\\\m_{Ti}=13.0g[/tex]
Regards.
Heating carvone with aqueous sulfuric acid converts it into carvacrol. The mechanism involves the following steps:
1. The terminal alkene of carvone reacts with acid to form tertiary carbocation 1;
2. A hydride shift results in the formation of tertiary carbocation 2;
3. Deprotonation of the ring leads to conjugated diene 3;
4. Deprotonation at the α carbon leads to the product carvacrol.
Required:
Draw the mechanism and then draw the structure of tertiary carbocation 2.
Answer:
See figure 1
Explanation:
In this question, we have to start with the protonation of the double bond. In carvone we have two double bonds, so, we have to decide first which one would be protonated.
The problem states that the terminal alkene is the one that would is protonated. Therefore, we have to do the protonation in the double bond at the bottom to produce the carbocation number 1. Then, a hydride shift takes place to produce the carbocation number 2. A continuation, an elimination reaction takes place to produce the conjugated diene. Then the diene is protonated at the carbonyl group and with an elimination reaction of an hydrogen in the alpha carbon we can obtain carvacol.
A solution containing lead(II) nitrate is mixed with one containing sodium bromide to form a solution that is 0.0630 M in Pb(NO3)2 and 0.0103 M in NaBr. What is the value of Q for the insoluble product? Express the reaction quotient to three significant figures.
Answer:
Q = 6.68x10⁻⁶
Explanation:
The initial solutions are Pb(NO₃)₂ and NaBr. As sodium and nitrates salts are soluble, the insoluble product must be the formed from the other ions, PbBr₂.
The soluble product equilibrium is written as:
PbBr₂(s) ⇄ Pb²⁺(aq) + 2Br⁻(aq)
Where Q is defined as:
Q = [Pb²⁺] [Br⁻]²
As:
[Pb²⁺] = 0.0630M
[Br⁻] = 0.0103M
Q = [Pb²⁺] [Br⁻]²
Q = [0.0630M] [0.0103M]²
Q = 6.68x10⁻⁶Water (2190 g ) is heated until it just begins to boil. If the water absorbs 5.83×105 J of heat in the process, what was the initial temperature of the water?
Answer:
The initial temperature was [tex]36.4^\circ \:C[/tex]
Explanation:
[tex]\Delta t=\frac{q}{m\cdot C_s}=\frac{5.83\times10^5}{2190\times 4.184}\\\\=63.6^\circ\:C[/tex]
The temperature difference [tex]=100-63.6=36.4^\circ\:C[/tex]
Best Regards!
Need help finding major products
Answer:
Explanation:
RX + AgNO₃ = R⁺ ( carbocation ) + AgX + NO₃⁻
C₂H₅OH ( a nucleophile ) + R⁺ = ROC₂H₅
C₅H₁₁X + AgNO₃ = C₅H₁₁⁺ + AgX + NO₃⁻
In the first case carbocation produced is CH₃CH₂CH₂CH₂CH₂⁺
CH₃CH₂CH₂CH₂CH₂⁺ ⇒ CH₃CH₂CH₂C⁺HCH₃ ( secondary carbocation more stable )
CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃
Hence option D is correct .
b )
In the second case carbocation produced is
CH₃CH₂CH₂CH⁺CH₃
CH₃CH₂CH₂C⁺HCH₃ + C₂H₅OH ⇒ CH₃CH₂CH₂CH(OC₂H₅)CH₃
The product formed is same as in case of first
Option B is correct
Charcoal from the dwelling level of the Lascaux Cave in France gives an average count of 0.97 disintegrations of ^14 C per minute per gram of sample. Living wood gives 6.68 disintegrations per minute per gram. Estimate the date of occupation and hence the probable date of the wall painting in the Lascaux Cave. Hint: Disintegrations per minute per gram" has the same units as the time-derivative of concentration for a radioactive decay model. (You may use the fact that the half-life of ^14C is 5568 years.)
Answer:
Explanation:
count given by old sample = .97 disintegrations per minute per gram
count given by fresh sample = 6.68 disintegrations per minute per gram
Half life of radioactive carbon = 5568 years
rate of disintegration
dN / dt = λ N
In other words rate of disintegration is proportional to no of radioactive atoms present . As number reduces rate also reduces .
Let initial no of radioactive be N₀ and after time t , number reduces to N
N₀ / N = 6.68 / .97
Now
[tex]N=N_0e^{-\lambda t}[/tex]
[tex]\frac{N}{N_0} =e^{-\lambda t}[/tex]
[tex]\frac{6.68}{.97} = e^{\lambda t}[/tex]
λ is disintegration constant
λ = .693 / half life
= .693 / 5568
= .00012446 year⁻¹
Putting the values in the equation above
[tex]\frac{6.68}{.97} = e^{.00012446\times t}[/tex]
[tex]6.8866 = e^{.00012446\times t}[/tex]
1.929577 = .00012446 t
t = 15503.6 years .
What was one idea Dalton taught about atoms?
A. Atoms contained negatively charged particles scattered inside.
B. Atoms of one type would not react with atoms of another type.
C. All atoms of one type were identical in mass and properties.
D. Atoms changed into new elements when they formed compounds.
Answer:
C
Explanation:
I had this question and C is the right answer
One idea that Dalton taught about atoms was that all atoms of one type were identical in mass and properties.
What is an atom?
An atom is defined as the smallest unit of matter which forms an element. Every form of matter whether solid,liquid , gas consists of atoms . Each atom has a nucleus which is composed of protons and neutrons and shells in which the electrons revolve.
The protons are positively charged and neutrons are neutral and hence the nucleus is positively charged. The electrons which revolve around the nucleus are negatively charged and hence the atom as a whole is neutral and stable due to presence of oppositely charged particles.
Atoms of the same element are similar as they have number of sub- atomic particles which on combination do not alter the chemical properties of the substances.
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A chemist adds of a M barium chlorate solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.
The given question is incomplete, the complete question is:
A chemist adds 200.0 ml of a 0.52M barium chlorate (Ba(CIO3)2) solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.
Answer:
The correct answer is 32 grams.
Explanation:
Based on the given solution, the molarity of barium chlorate solution given is 0.52 M, this shows that the solution will comprise 0.52 moles in 1 L or 1000 ml of the solution.
Therefore, in 200 ml, it will comprise 0.52/1000 × 200 moles of Ba(ClO₃)₂,
= 0.52/1000 × 200 = 0.104 moles
The molecular mass of Ba(ClO₃)₂ is 304.23 gram per mole
So, the mass of Ba(ClO₃)₂ in 0.104 moles will be,
= 304.23 g/mol × 0.104
= 31.639 grams or 32 grams.
What mass of Si, in grams, can be produced from the reaction below starting with 225 g SiCl4 and 101 g Mg? SiCl4 + Mg Si + MgCl2 Given: 1 mol SiCl4 = 169.8963 g SiCl4 1 mol Mg = 24.3050 g Mg 1 mol Si = 28.0855 g Si
Answer:
[tex]m_{Si}=37.2gSi[/tex]
Explanation:
Hello,
In this case, for the undergoing balanced chemical reaction:
[tex]SiCl_4 + 2Mg \rightarrow Si + 2MgCl_2[/tex]
We must first identify the limiting reactant given the 225 g of SiCl4 and 101 g of Mg. Thus, we compute the available moles of SiCl4:
[tex]n_{SiCl_4}=225gSiCl_4*\frac{1molSiCl_4}{169.8963gSiCl_4}=1.324molSiCl_4[/tex]
Next, by using the 1:2 mole ratio between SiCl4 and Mg, we compute the moles of SiCl4 consumed by 101 g of Mg:
[tex]n_{SiCl_4}^{consumed}=101gMg*\frac{1molMg}{24.3050gMg} *\frac{1molSiCl_4}{2molMg} =2.08molSiCl_4[/tex]
Thus, since less moles of SiCl4 are available, we can infer it is the limiting reactant whereas the Mg is in excess. In such a way, the produced grams of Si are computed considering the 1:1 molar ratio between SiCl4 and Si:
[tex]m_{Si}=1.324molSiCl_4*\frac{1molSi}{1molSiCl_4} *\frac{28.0855gSi}{1molSi} \\\\m_{Si}=37.2gSi[/tex]
Best regards.
A radioactive isotope of mercury, 197Hg, decays togold, 197Au, with a disintegration constant of 0.0108 h-1. What fraction of a sample will remain at the end of three half-lives (
Answer:
THE FRACTION OF THE SAMPLE REMAINING AFTER THREE HALF LIVES IS 0.125 OR 125/1000
Explanation:
A radioactive isotope of mercury decay to gold with a disintegration constant of 0.0108 h^-1
To calculate the fraction of sample remaining after three half life, we first calculate the half life of the decay.
Half life = ln 2 / Y
Y = disintegration constant
So therefore,
half life = ln 2 / 0.0108
half life = 0.693 / 0.0108
half life = 64.18 hours.
So a decay occurs after 64.18 hours.
To calculate the fraction remaining after 3 half life:
N(t) = N(o) e ^-Yt
where t = 3 half life
So, N / No = e^-Y ( 3 t1/2)
Since t 1/2 = ln 2 / Y, so we can re-write the formula as:
Nt / No = e^-Y ( 3 ln 2/ Y)
Nt / No = e^-3 ln2
Nt / No = e^-3 * 0.693
Nt / No = e^-2.079
Nt / No = 0.125
So the fraction of the sample remaining after 3 half lives is 125/ 1000 or 0.125
5.00 mol of ammonia are introduced into a 5.00 L reactor vessel in which it partially dissociates at high temperatures. 2NH 3(g) 3H 2(g) + N 2(g) At equilibrium and a particular temperature, 1.00 mole of ammonia remains. Calculate K c for the reaction.
Explanation:
system at equilibrium, will the reaction shift towards reactants ~
--?'
2. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). The production of ammonia is an
exothermic reaction. Will heating the equilibrium system increase o~e amount of
ammonia produced? . .co:(
3. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). Ifwe use a catalyst, which way will
the reaction shift? ':'\
.1.+- w~t s~,H (o')l r'eo.c. e~ ei~i"liht-,·u.fn\ P~~,
4. (3 Pts) ff 1ven th e o £ 11 owmg d t a a £ or th ere action: A(g) + 2B(s) =; AB2(g)
Temperature (K) Kc
300 1.5x104
600 55 k ' pr, cl l<..J~
e- ~ r fee, ct o. ~ 1<
900 3.4 X 10-3
Is the reaction endothermic or exothermic (explain your answer)?
t d- IS o.,;r-. \4\a..i~1f't~ °the te.Y'il(lf1,:J'u.r-a a•~S. j lrvdu..c,,.) +~H~to{' '\
exothe-rnh't.-- ,.. ..,. (/.., ,~.
5. (4 Pts) Consider the reaction, N2(g) + 3H2(g) =; 2NH3(g). Kc= 4.2 at 600 K.
What is the value of Kc for 4 NH3(g) =; 2N2(g) + 6H2(g)
N ... ~l + 3 H~(ri ~ ~Nli3~) kl,= ~:s;H,J3 # 4. J..
~ ;)N~~) ~ ~ H ~) ~\-_ == [A!;J:t D~~Jb
J. [,v 1+3] ~
I
4,:i.~ = 0,05
5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.
Initially, there are 5.00 mol of ammonia in a 5.00 L reactor vessel. The initial concentration of ammonia is:
[tex][NH_3]_i = \frac{5.00mol}{5.00L} = 1.00 M[/tex]
At equilibrium, there is 1.00 mole of ammonia in the 5.00 L vessel. The concentration of ammonia at equilibrium is:
[tex][NH_3]eq = \frac{1.00mol}{5.00L} = 0.200 M[/tex]
We can calculate the concentrations of all the species at equilibrium using an ICE chart.
2 NH₃(g) ⇄ 3 H₂(g) + N₂(g)
I 1.00 0 0
C -2x +3x +x
E 1.00-2x 3x x
Since the concentration of ammonia at equilibrium is 0.200 M,
[tex]1.00-2x = 0.200\\\\x = 0.400 M[/tex]
The concentrations of all the species at equilibrium are:
[tex][NH_3] = 0.200 M\\[H_2] = 3x = 1.20 M\\[N_2] = x = 0.400 M[/tex]
The concentration equilibrium constant (Kc) is:
[tex]Kc = \frac{[H_2]^{2} [N_2]}{[NH_3]^{2} } = \frac{(1.20^{3})(0.400) }{0.200^{2} } = 17.3[/tex]
5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.
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Identify a process that is NOT reversible. A. melting of steel B. freezing water C. melting of ice D. frying an egg E. deposition of carbon dioxide (gas to solid)
A process that is not a reversible reaction is frying an egg.
What are reversible reactions?Reversible reactions are those reactions in which product will again change into the reactant.
Melting of steel and ice are reversible reaction as after cooling again we get the original state of steel and ice.Freezing of water is also reversible reaction as at normal temperature we get the original state of water.Deposition of carbon dioxide is also a reversible reaction.Frying an egg is a non reversible reaction as after frying an egg we didn't get the original egg again.Hence option (D) is correct.
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A 8.22-g sample of solid calcium reacted in excess fluorine gas to give a 16-g sample of pure solid CaF2. The heat given off in this reaction was 251 kJ at constant pressure. Given this information, what is the enthalpy of formation of CaF2(s)
Answer:
The enthalpy of formation of CaF₂ is -1224.4 kJ.
Explanation:
The enthalpy of formation of CaF₂ can be calculated as follows:
[tex] \Delta H_{f} = \frac{q}{n_{CaF_{2}}} [/tex]
Where:
q: is the heat liberated in the reaction = -251 kJ
The number of moles of CaF₂ is:
[tex] n_{CaF_{2}} = \frac{m}{M} [/tex]
Where:
m: is the mass of CaF₂ = 16 g
M: is the molar mass of CaF₂ = 78.07 g/mol
[tex] n_{CaF_{2}} = \frac{m}{M} = \frac{16 g}{78.07 g/mol} = 0.205 moles [/tex]
Now, the enthalpy of formation of CaF₂ is:
[tex]\Delta H_{f} = \frac{q}{n_{CaF_{2}}} = \frac{-251 \cdot 10^{3} J}{0.205 moles} = -1224.4 kJ/mol[/tex]
Therefore, the enthalpy of formation of CaF₂ is -1224.4 kJ.
I hope it helps you!
Select the correct answer. A certain reaction has this form: aA bB. At a particular temperature and [A]0 = 2.00 x 10-2 Molar, concentration versus time data were collected for this reaction and a plot of ln[A]t versus time resulted in a straight line with a slope value of -2.97 x 10-2 min-1. What is the half-life of this reaction? A. 23.33 seconds B. 0.043 minutes C. 0.0043 seconds D. 23.33 minutes E. 1680 minutes
Answer:
[tex]\large \boxed{\text{D. 23.34 min}}[/tex]
Explanation:
1. Find the order of reaction
Use information from the graph to find the order.
If a plot of ln[A] vs time is linear, the reaction is first order and the slope = -k.
2. Find the half-life
[tex]k = \dfrac{\ln2}{ t_{\frac{1}{2}}}\\\\k = \text{-slope} = -(-2.97 \times 10^{-2} \text{ min}^{-1}) =2.97 \times 10^{-2} \text{ min}^{-1} \\ t_{\frac{1}{2}} =\dfrac{\ln 2}{k} = \dfrac{\ln 2}{2.97 \times 10^{-2}\text{ min}^{-1}} =\textbf{23.34 min}\\\\\text{The half-life is $\large \boxed{\textbf{23.34 min}}$}[/tex]
The half life of the reaction is 23.33 minutes.
We know that for a first order reaction;
ln[A]t = ln[A]o - kt
A plot of ln[A]t against time (t) will yield a straight line graph with a slope of -k.
From the question, the slope is -2.97 x 10-2 min-1.
So, -2.97 x 10-2 min-1 = - k
k = 2.97 x 10-2 min-1
The half life of a first order reaction is obtained from;
t1/2 = 0.693/k
t1/2 = 0.693/2.97 x 10-2 min-1
t1/2 = 23.33 minutes
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what is the difference between acidic and basic protein
Answer:
Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.
Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10 genes.
Answer:
Acidic proteins are proteins that move faster than serum albumin on zone electrophoresis (starch or acrylamide gel) and which bind most strongly to the basic ion exchangers used in protein chromatography.
Basic protein is a late gene product associated with the viral DNA within the nucleocapsid. The harnessing of this promoter allows the expression of foreign genes at earlier times than those using the very late phase promoters of the polyhedron and p10
Explanation:
what is the meaning of the word tetraquark?
Answer:
A tetraquark in physics is an exotic meson composed of four valence quarks.
Explanation:
It has been suspected to be allowed by quantum chromodynamics, the modern story of strong interactions.
Hope it helps.
30. What is the Bronsted base of H2PO4- + OH- ⟶HPO42- + H2O?
Answer:
OH⁻ is the Bronsted-Lowry base.
Explanation:
A Bronsted-Lowry base is a substance that accepts protons. In the chemical equation, OH⁻ accepts a proton from H₂PO₄⁻ to become H₂O. H₂PO₄⁻ would be a Bronsted-Lowry acid because it donates a proton to OH⁻ and becomes HPO₄²⁻.
Hope that helps.
A chemistry student weighs out of chloroacetic acid into a volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with solution. Calculate the volume of solution the student will need to add to reach the equivalence point. Round your answer to significant digits.
Answer:
11.6mL of the 0.1400M NaOH solution
Explanation:
0.154g of chloroacetic acid diluted to 250mL. Titrated wit 0.1400M NaOH solution.
The reaction of chloroacetic acid, ClCH₂COOH (Molar mass: 94.5g/mol) with NaOH is:
ClCH₂COOH + NaOH → ClCH₂COO⁻ + Na⁺ + H₂O
Where 1 mole of the acid reacts per mole of the base.
That means the student will reach equivalence point when moles of chloroacetic acid = moles NaOH.
You will titrate the 0.154g of ClCH₂COOH. In moles (Using molar mass) are:
0.154g ₓ (1mol / 94.5g) = 1.63x10⁻³ moles of ClCH₂COOH
To reach equivalence point, the student must add 1.63x10⁻³ moles of NaOH. These moles comes from:
1.63x10⁻³ moles of NaOH ₓ (1L / 0.1400moles NaOH) = 0.0116L of the 0.1400M NaOH =
11.6mL of the 0.1400M NaOH solutionHow many milliliters of 0.0850 M NaOH are required to titrate 25.0 mL of 0.0720 M hydrobromic acid, HBr, to the equivalence point?
Answer:
21.2 mL
Explanation:
Step 1: Write the balanced equation.
NaOH + HBr ⇒ NaBr + H₂O
Step 2: Calculate the reacting moles of HBr
25.0 mL of 0.0720 M hydrobromic acid react.
[tex]0.0250 L \times \frac{0.0720mol}{L} = 1.80 \times 10^{-3} mol[/tex]
Step 3: Calculate the reacting moles of NaOH
The molar ratio of NaOH to HBr is 1:1. The reacting moles of NaOH are 1/1 × 1.80 × 10⁻³ mol = 1.80 × 10⁻³ mol.
Step 4: Calculate the required volume of NaOH
[tex]1.80 \times 10^{-3} mol \times\frac{1,000mL}{0.0850mol} = 21.2 mL[/tex]
A reaction is performed in a lab whereby two solutions are mixed together. The products are a liquid and a solid precipitate. What procedures would facilitate measurement of actual yield of the solid
Answer:
filtration, drying, and weighing
Explanation:
The procedures that would facilitate the measurement of the actual yield of the solid would be filtration of the precipitate, drying of the precipitate, and weighing of the precipitate respectively.
The liquid/solid mixture resulting from the reaction can be separated by the process of filtration using a filter paper. The residue in the filter paper would be the solid while the filtrate would be the liquid portion of the reaction's product.
The residue can then be allowed to dry, and then weighed using a laboratory-grade weighing balance. The weight of the solid represents the actual yield of the solid.
A sample of neon gas at a pressure of 0.609 atm and a temperature of 25.0 °C, occupies a volume of 19.9 liters. If the gas is compressed at constant temperature to a
volume of 12.7 liters, the pressure of the gas sample will be
atm.
Answer:
The pressure of the gas sample will be 0.954 atm.
Explanation:
Boyle's law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; conversely if the pressure decreases, the volume increases.
Boyle's law is expressed mathematically as:
Pressure * Volume = constant
o P * V = k
To determine the change in pressure or volume during a transformation at constant temperature, the following is true:
P1 · V1 = P2 · V2
That is, the product between the initial pressure and the initial volume is equal to the product of the final pressure times the final volume.
In this case:
P1= 0.609 atmV1= 19.9 LP2=?V2= 12.7 LReplacing:
0.609 atm* 19.9 L= P2* 12.7 L
Solving:
[tex]P2=\frac{0.609 atm* 19.9 L}{12.7 L}[/tex]
P2= 0.954 atm
The pressure of the gas sample will be 0.954 atm.
After the reaction between sodium borohydride and the ketone is complete, the reaction mixture is treated with water and H2SO4 to produce the desired alcohol. Explain the reaction by clearly indicating the source of the hydrogen atom that ends up on the oxygen
Answer:
The hydrogen can be gotten from the added Acid or water during "workup".
Explanation:
Basically we can say that the reaction describe in this question is a Reduction reaction because of the chemical compound called sodium borohydride. In the reaction described above we can see that there is a Reduction of ketone to alcohol by the compound; sodium borohydride.
For the reduction Reaction to occur the C-O bond must break so as to enable the formation of O-H bond and C-H bond.
So, "the reaction mixture is treated with water and H2SO4 to produce the desired alcohol", thus, the oxygen will definitely pick up the hydrogen from H2SO4 or H2O.
Applied Exercises (40 points) Answer the following questions in complete sentences. 1) In molecules with the same number of electron groups but different molecular geometries, discuss what happens to the bond angle? 2) What happens to the bond angle as you increase the number of bonding groups? 3) In 5 electron group molecules, what is the difference between axial and equatorial positions? Which groups are removed as lone pairs are added? 4) What is the difference between tetrahedral bent and
Answer:
See explanation
Explanation:
In molecules with the same number of electron groups but different molecular geometries, the bond angles differ markedly owing to the presence of lone pairs on the central atom. Recall that lone pairs of electrons take up more space around the central atom and causes more repulsion thus squeezing the bond angle and making it less than the value expected on the basis of the Valence Shell Electron Pair Repulsion Theory.
As the number of bonding groups increases, the bond angle increases since the repulsion due to lone pairs of electrons is being progressively removed by increase in the number of bonding groups.
For 5 electron group molecules, the axial groups are oriented at a bond angle of 90° while the equatorial groups are oriented at a bond angle of 120°. In the presence of lone pairs, the equatorial bonds are removed because the equatorial bonds often have a greater bond length than the axial bonds.
In the tetrahedral geometry, four groups are bonded to the central atom while in a bent molecular geometry, only two groups are bonded to the central atom with two lone pairs present in the molecule.
Calculate the volume in liters of a M mercury(II) iodide solution that contains of mercury(II) iodide . Round your answer to significant digits.
Answer:
41L
Explanation:
Of a 4.8x10⁻⁵M mercury (II) iodide that contains 900mg of mercury (II) iodide. 2 significant digits
Molarity, M, is an unit of concentration in chemistry defined as the ratio between moles of solute (Mercury (II) iodide in this case) per Liter of solution.
A 4.8x10⁻⁵M solution contains 4.8x10⁻⁵ moles of solute per liter.
Now, 900mg = 0.900g of mercury (II) iodide (Molar mass: 454.4g/mol) are:
0.900g × (1mol / 454.4g) = 1.98x10⁻³moles of HgI₂
If in 1L there are 4.8x10⁻⁵ moles of HgI₂, There are 1.98x10⁻³moles of HgI₂ in:
1.98x10⁻³moles of HgI₂ ₓ (1L / 4.8x10⁻⁵moles) =
41L11. How did the solubility product constant Ksp of KHT in pure water compare to its solubility product constant Ksp of KHT in KCl solution? Are these results what you would expect? Why?
Answer:
Explanation:
KHT is a salt which ionises in water as follows
KHT ⇄ K⁺ + HT⁻
Solubility product Kw= [ K⁺ ] [ HT⁻ ]
product of concentration of K⁺ and HT⁻ in water
In KCl solution , the solubility product of KHT will be decreased .
In KCl solution , there is already presence of K⁺ ion in the solution . So
in the equation
[ K⁺ ] [ HT⁻ ] = constant
when K⁺ increases [ HT⁻ ] decreases . Hence less of KHT dissociates due to which its solubility decreases . It is called common ion effect . It is so because here the presence of common ion that is K⁺ in both salt to be dissolved and in solvent , results in decrease of solubility of the salt .