The work performed on the surroundings by the one-mole ideal gas, which is expanded from 1.00 liter to 3.23 liters against a constant external pressure of 1.00 atm, is -225.51 J.
To calculate the work performed on the surroundings by the ideal gas, we need to use the formula:
W = -PextΔV
where W is the work done on the surroundings, Pext is the external pressure, and ΔV is the change in the volume of the gas.
In this case, we have a one-mole ideal gas that is expanded from 1.00 liter to 3.23 liters against a constant external pressure of 1.00 atm. So, the change in volume is:
ΔV = 3.23 L - 1.00 L = 2.23 L
Since the pressure is constant, we can use the given value of 1.00 atm for Pext. Therefore, the work performed on the surroundings by the ideal gas is:
W = - (1.00 atm) (2.23 L) = -2.23 atm·L
To convert this value to joules, we need to use the following conversion factor:
1 atm·L = 101.325 J
So, the work performed on the surroundings by the ideal gas is:
W = (-2.23 atm·L) (101.325 J/atm·L) = -225.51 J
The negative sign in the answer indicates that the work is performed by the gas on the surroundings, which is consistent with the fact that the gas is expanding.
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ammonia is a weak electrolyte. which of the following is true about the behavior of ammonia in water? question 11 options: ammonia is insoluble in water ammonia forms no ions when it dissolves in water ammonia ionizes completely in water ammonia ionizes only partially in water
Ammonia ionizes only partially in water. Option 4 is correct.
When ammonia dissolves in water, it reacts with water to form ammonium ions (NH₄⁺) and hydroxide ions (OH⁻), according to the equation: NH₃ + H₂O ⇌ NH₄⁺ + OH⁻. However, this reaction is reversible and only a small fraction of ammonia molecules ionize to form ions. As a result, ammonia is classified as a weak electrolyte, meaning that it only conducts electricity weakly in solution.
Weak electrolytes are characterized by their partial ionization in solution, and they have relatively low electrical conductivity compared to strong electrolytes, which ionize completely in solution. Hence Option 4 is correct.
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The atmospheric pressure on top of Mt. Everest (elevation 29,028) is 250. torr. Calculate the atmospheric pressure in mmHg and atm. Round each of your answers to 3 significant digits.
The atmospheric pressure on top of Mt. Everest is 250 mmHg and 0.328 atm, when rounded to 3 significant digits.
What is Pressure?Pressure is a force that is exerted over a surface area. It is the amount of force applied to an object per unit area. Pressure is typically expressed in units of force per unit of area, such as pounds per square inch (psi) or pascals (Pa). Pressure is an important factor in many areas of engineering, physics, chemistry, and biology.
Atmospheric pressure can be measured in torr (1 Torr = 1mmHg), atm (1 atm = 760mmHg) or in kPa (1 atm = 101.3kPa).
250 torr = 250 mmHg
250 mmHg / 760 mmHg = 0.328 atm
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Why is cerium sulfate (Ce2(SO4)3) the only compound that experiences a dip in solubility as temperature increases?
Answer: Because its dissolution is exothermic
Explanation:
PLEASE HELPPPP
For each pair, predict which substance becomes more positively charged and which becomes more negatively charged when the two substances are rubbed together.
1. cotton, steel
2. cotton, silk
3. human hair, human hands (dry)
4. Teflon®,wood
5. glass, plastic wrap
1. Cotton is charged negatively while steel doesn't charge by rubbing. 2. cotton acquires negative while silk acquires positive charge. 3. human hair is negative charge while human hand is positively charged. 4. teflon gets negative charge while wood doesn't acquire charge. 5. glass acquires positive charge when rubbed with plastic wrap.
Triboelectric chargingThe transfer of electrons between two different materials occurs when they are rubbed together. The result is that the electron gainer becomes negatively charged and the electron loss becomes positively charged.Triboelectric effect, often referred to as triboelectric charging, is a form of contact electrification in which certain materials acquire an electrical charge after being cut off from another substance with which they had come into touch.According to a type of contact electrification known as the triboelectric effect, some materials acquire an electrical charge after being cut off from another substance with which they had come into touch.
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Name an ester that can be synthesized from propanol and methanoic acid?
Answer:
Propyl methanoate
Explanation:
The ester that can be synthesized from propanol and methanoic acid is propyl methanoate (also known as methyl propanoate or propyl formate). The reaction between propanol and methanoic acid, which is a carboxylic acid, is a classic example of an esterification reaction, which results in the formation of an ester and water.
true or false. napthelene and benzoic acid in a tlc as dichloromethane as the mobile phase
From top to bottom, the expected order would be naphthalene, phenyl acetate, and butyric acid on a silica gel TLC plate developed with dichloromethane.
Assuming that the TLC plate was properly developed with dichloromethane as the mobile phase, the order from top to bottom would likely be:
Naphthalene - Naphthalene is nonpolar and has a lower affinity for the polar stationary phase (silica gel), so it will move further up the TLC plate.
Phenyl acetate - Phenyl acetate is more polar than naphthalene but less polar than butyric acid. It will move up the plate but not as far as naphthalene.
Butyric acid - Butyric acid is polar and will have a higher affinity for the polar stationary phase (silica gel), so it will move the least distance and be closest to the bottom of the TLC plate.
It is important to note that the order may vary depending on the specific conditions of the experiment, such as the composition of the stationary and mobile phases and the relative concentrations of the compounds being analyzed.
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Full Question: In what order from top to bottom would you expect to find naphthalene, butyric acid and phenyl acetate on a silica gel TLC plate developed with dichloromethane?
The expected order from top to bottom would be naphthalene, butyric acid, and phenyl acetate.
On a silica gel TLC plate developed with dichloromethane, the order in which the compounds will appear from top to bottom depends on their polarity. Naphthalene is nonpolar due to its symmetrical structure, and it will travel the furthest up the plate. Butyric acid is a polar molecule because of the presence of the carboxylic acid group (-COOH) which is more polar than the naphthalene, so it will be positioned below the naphthalene spot. Phenyl acetate contains an ester group (-COO-) that is more polar than the carboxylic acid group, and thus, it is the most polar molecule in the group. It will travel the least distance up the plate, making it the bottommost spot.
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Note- Complete question
In what order from top to bottom would you expect to find naphthalene, butyric acid and phenyl acetate on a silica gel TLC plate developed with dichloromethane?
the decrease in the second ionization energy of alkali metals going down the group, as shown in the table above, can be best attributed to a decrease in the coulombic force of attraction due to
The decrease in the second ionization energy of alkali metals going down the group is due to the increase in atomic radius.
As the atomic radius increases, the distance between the nucleus and the outermost electron increases, which reduces the coulombic force of attraction between the nucleus and the electron.
This reduced coulombic force of attraction reduces the energy required to remove the electron, thus resulting in a decrease in the ionization energy. Additionally, due to the increased number of electrons, the effective nuclear charge decreases, which further reduces the force of attraction between the nucleus and the electron, thus resulting in a further decrease in the ionization energy.
Therefore, the decrease in the second ionization energy of alkali metals going down the group can be attributed to a decrease in the coulombic force of attraction due to the increase in atomic radius and the decrease in the effective nuclear charge.
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Which of the following is evidence for a chemical reaction?(a) Dropping sodium metal into water gives a yellow flame.(b) Dropping iron metal into acid produces gas bubbles.
Both options (a) and (b) are evidence for a chemical reaction.
In option (a), the yellow flame is an indication that a chemical reaction has occurred between the sodium metal and water, producing hydrogen gas and sodium hydroxide.
In option (b), the gas bubbles produced indicate that a chemical reaction has occurred between the iron metal and the acid, producing hydrogen gas and iron(II) ions. Based on the given options, evidence for a chemical reaction can be observed in both (a) and (b).
In (a), dropping sodium metal into water produces a yellow flame, indicating a chemical reaction as new substances are formed. In (b), dropping iron metal into acid produces gas bubbles, which also signifies a chemical reaction as a new product, in this case gas, is generated.
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extend the left chain as far as the simulation allows. what is the base name for an ester with a propyl group attached to the carbonyl carbon atom?
The base name for an ester with a propyl group attached to the carbonyl carbon atom is "propyl ester." In the context of a simulation, you would need to extend the left chain according to the given parameters within the simulation for the specific compound you are working with.
If we extend the left chain of an ester with a propyl group attached to the carbonyl carbon atom as far as the simulation allows, we would have the following structure:
CH3-(CH2)2-C(=O)-OR
Where R represents the rest of the ester molecule.The base name for an ester with a propyl group attached to the carbonyl carbon atom is propyl propanoate. This name is derived from the parent carboxylic acid, which is propanoic acid (also known as propionic acid), and the alcohol used to form the ester, which is propanol (also known as 1-propanol or n-propanol).The esterification reaction between propanoic acid and propanol yields propyl propanoate as the ester product, with the elimination of a molecule of water. The ester is commonly used as a flavor and fragrance ingredient in various food and cosmetic products.
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in this experiment you will build molecules with model axnem. what does the a, x and e stand for? question 3 options: e a x 1. central atom 2. terminal atoms 3. lone pairs 4. double pairs 5. covalent pairs 6. ionic pairs
In the context of building molecules using model kits such as AXNEM, A, X, and E are abbreviations used to represent the different parts of a molecule.
1) A stands for "central atom," which is usually the atom that has the lowest electronegativity in the molecule and is located at the center of the molecular structure.
2) X stands for "terminal atoms," which are the atoms that are bonded to the central atom. They can be identical or different from one another.
3) E stands for "lone pairs," which are pairs of electrons that are not involved in any bonding and are located on the outer shell of the central atom.
By using these abbreviations, it becomes easier to represent the molecular structure and to understand how the atoms are arranged and bonded to each other.
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what do you believe is more important for society to look at when determining what substance is more environmentally-friendly?
When determining what substance is more environmentally-friendly, it's important for society to look at both the substance's overall environmental impact and its sustainability.
The overall environmental impact of a substance includes its potential to contribute to climate change, pollution, and depletion of natural resources. This can be evaluated by examining the substance's production process, transportation, use, and disposal.
Sustainability, on the other hand, refers to the ability of a substance to meet the needs of the present generation without compromising the ability of future generations to meet their own needs. Sustainable substances are those that can be produced and used in a way that does not exhaust or degrade natural resources, or cause significant harm to the environment.
In evaluating the environmental-friendliness of a substance, it's important to consider both its immediate impact on the environment and its long-term sustainability. A substance may be environmentally-friendly in the short term, but if it's not sustainable, it may cause more harm than good in the long run. Therefore, a comprehensive approach that considers both environmental impact and sustainability is necessary to determine what substance is more environmentally-friendly.
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if he gas has an average kinetic energy of 6430 j/mol under certain conditions, what is the root mean square speed of f2 gas molecules under the same conditions?
The root mean square speed of F2 Gas molecules under the same conditions is approximately 582.19 m/s
Given: Average kinetic energy (E_k) = 6430 J/mol
Molar mass of F2 = 2 * Molar mass of F = 2 * 19 g/mol = 38 g/mol (since F has a molar mass of 19 g/mol)
First, let's convert the molar mass of F2 from grams to kilograms:
Molar mass of F2 = 38 g/mol * (1 kg/1000 g) = 0.038 kg/mol
Now, we can use the equation for the average kinetic energy to determine the root mean square speed (v_rms):
E_k = (3/2) * R * T = (1/2) * m * v_[tex]rms^{2}[/tex]
Where R is the universal gas constant (8.314 J/mol K) and T is the temperature in Kelvin.
Since we want to find v_rms, we can rearrange the equation as follows:
v_[tex]rms^{2}[/tex] = (2 * E_k) / m
Plugging in the given values:
v_[tex]rms^{2}[/tex] = (2 * 6430 J/mol) / 0.038 kg/mol = 338947.37[tex]m^{2}/ s^{2}[/tex]
Finally, we take the square root to find the root mean square speed: a
v_rms = √338947.37[tex]rms^{2}[/tex] = 582.19 m/s
So, the root mean square speed of F2 gas molecules under the same conditions is approximately 582.19 m/s.
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Boyle's Law: If it takes 0.0500L of oxygen gas kept in a cylinder under pressure to fill an evacuated 4.00L reaction vessel in which the pressure is 0.980atm. What was the initial pressure of the gas in the cylinder?
The cloud droplets in a cloud are formed by water vapor molecules and: A) protons. B) ions. C) molecules of air. D) condensation nuclei.
Answer:
condensation nuclei
Explanation:
collision theory states that as molecules or ions bump into each other, a reaction will only occur if the collision has the correct amount of energy and impact is at the right angle and location. describe how collision theory helps predict how temperature, pressure, and concentration impact reaction rates. pipes will react with air to oxidize. on a house that had two pipes installed for the hot water and cold water, which pipe will oxidize faster?
In general, a higher temperature and/or concentration of the oxidizing agent could increase the rate of oxidation for both pipes.
Collision theory helps us understand how temperature, pressure, and concentration can impact the rate of a chemical reaction. An increase in temperature provides more energy to the molecules, increasing their speed and the number of collisions, thus increasing the rate of reaction.
Similarly, an increase in pressure can also increase the rate of reaction by forcing more molecules closer together, increasing the frequency of collisions. Finally, an increase in concentration increases the number of molecules present, thus increasing the chances of collision and the rate of reaction.
Regarding the pipes on the house, it is difficult to determine which pipe will oxidize faster without further information. Factors such as the material of the pipes and the specific oxidizing agent present would need to be considered.
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the solvent choice in a nucleophilic substitution reaction would affect which of the following? (select all that apply.) multiple select question. product functional group stereochemical outcomes mechanism of substitution product structure rate of reaction
The solvent choice in a nucleophilic substitution reaction would affect stereochemical outcomes, the product structure ,the rate of reaction.
The Nucleophilic substitution reactions are the type of the reactions in which the electron rich nucleophile will attacks the positively charged electrophile and to replace the leaving group.
The more polar the solvents are helpful in the nucleophilic substitutions. In the nucleophile the ionic compound itself, and the more polar solvent helps to dissolve. Therefore, the polar solvents may be provide the additional stability to the ions. The Polar solvents will either decrease the nucleophilicity and it will not affect it, but do not increase the nucleophilicity.
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in an alternative version of this experiment, the h2o ligands are instead replaced with co ligands (not nh3). based on your knowledge of the spectrochemical series what would you expect to happen to the ligand field splitting?
Answer:
The splitting is going to be larger for CO.
Explanation:
"The ligand field splitting in a coordination complex is determined by the strength of the interaction between the metal center and the ligands, which is affected by various factors, including the ligands' identity. CO ligands are stronger field ligands than H2O ligands, meaning that they interact more strongly with the metal center and cause a larger ligand field splitting. Therefore, if H2O ligands are replaced with CO ligands in this experiment, we would expect the ligand field splitting to be larger for CO."
consider the pictured structure of a dipeptide. dipeptide structure with labels a through d. the a label is at the end of the molecule with the positively charged nh3 group. the b label is placed by the bond between the carbonyl group and the amine. the c label is next to a carbon with shown single bonds to the carboxylate, a ch2oh, and the rest of the molecule. the d label is next to the carboxylate at the end of the molecule. what does each label on the structure represent?
The dipeptide structure with labels a through d represents the different functional groups and atoms present in the molecule.
Label a is located at the end of the molecule with the positively charged NH3 group, indicating the presence of an amino group. The b label is placed by the bond between the carbonyl group and the amine, indicating the presence of a peptide bond.
Label c is next to a carbon with shown single bonds to the carboxylate, a CH2OH, and the rest of the molecule, indicating the presence of a side chain. Finally, the d label is next to the carboxylate at the end of the molecule,
indicating the presence of a carboxylic acid functional group. Understanding the different functional groups and atoms present in the dipeptide structure is important in understanding its properties and behavior in chemical reactions and biological processes.
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a solution containing 20.0 g of an unknown non-electrolyte liquid and 110.0 g water has a freezing point of -1.32 °c. given kf = 1.86°c/m for water, the molar mass of the unknown liquid is ____g/mol.
The molar mass of the unknown non-electrolyte liquid is given as
256 g/mol, option A.
The ratio between the mass and the amount of substance (measured in moles) of any sample of a chemical compound is known as the molar mass (M) in chemistry. The molar mass of a material is a bulk attribute rather than a molecular one.
ΔTemp.f = i x Kf x b
where,
ΔTemp.f = the freezing-point depression;
i = the Van't Hoff factor
Kf = the cryoscopic constant of the solvent;
b = the molality of the solution.
Solving for the molality, b = ΔTemp.f/( i * Kf)= 1.32/(1*1.86)
= 0.71 mol/kg
Converting from mol/kg to mol/g,0.71 mol/kg * 1kg/1000g
= 0.00071 mol/g.
Mass of solvent = 110gNumber of moles = mass * molality
= 0.00071 * 110
= 0.078 mol.
To calculate molar mass,Molar mass (g/mol) = mass/number of moles
Mass of solute (liquid) = 20g
Molar mass = 20/0.078
= 256.2 g/mol. ≈ 256 g/mol
Therefore, molar mass of the unknown liquid is 256.2 g/mol.
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Complete question:
A solution containing 20.0 g of an unknown non-electrolyte liquid and 110.0 g water has a freezing point of -1.32 °c. given kf = 1.86°c/m for water, the molar mass of the unknown liquid is ____g/mol.
A)256B) 69.0 C) 619 D) 78.1
The molar mass of the unknown liquid is 256.5 g/mol.To solve this problem, we can use the formula for calculating the freezing point depression: ΔTf = Kf·m·i
where ΔTf is the change in freezing point (in °C), Kf is the freezing point depression constant (in °C/m), m is the molality of the solution (in mol/kg), and i is the van't Hoff factor (which is 1 for non-electrolytes).
First, we need to calculate the molality of the solution:
molality = moles of solute / mass of solvent (in kg)
We know that the mass of the solvent (water) is 110.0 g, which is 0.1100 kg. To find the moles of solute (the unknown liquid), we need to divide its mass (20.0 g) by its molar mass (which we don't know yet). Let's call the molar mass "M":
moles of solute = 20.0 g / M
So, the molality is:
molality = (20.0 g / M) / 0.1100 kg
molality = (20.0 / M) / 0.1100 mol/kg
Now, we can plug this into the formula for freezing point depression:
ΔTf = Kf·m·i
-1.32 = 1.86·[(20.0 / M) / 0.1100]·1
Simplifying this equation, we get:
-1.32 = 1.86·(181.8 / M)
-1.32 = 338.628 / M
M = 338.628 / 1.32
M = 256.5 g/mol
Therefore, the molar mass of the unknown liquid is 256.5 g/mol.
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the density of pure propionic acid is 0.9930 g.cm-3 and its molecular mass is 74.08g.mol-1. a. calculate the mass of propionic acid required to make 250ml of 0.50m propionic acid solution
The density of pure propionic acid is 0.9930 g.cm-3 and its molecular mass is 74.08g.mol-1.
a. The mass of propionic acid required to make 250ml of 0.50m propionic acid solution is 9.26 grams.
To calculate the mass of propionic acid required to make 250ml of 0.50m propionic acid solution, we need to use the formula:
m = n x M
where:
m = mass of propionic acid required (in grams)
n = number of moles of propionic acid (in moles)
M = molecular mass of propionic acid (in grams per mole)
First, we need to calculate the number of moles of propionic acid required for a 250ml solution of 0.50m concentration:
Molarity = moles of solute/litres of solution
0.50m = n / 0.250 L
n = 0.50m x 0.250 L
n = 0.125 moles
Now we can substitute the values in the formula:
m = n x M
m = 0.125 moles x 74.08 g/mol
m = 9.26 g
Therefore, the mass of propionic acid required to make 250ml of 0.50m propionic acid solution is 9.26 grams.
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If 120 cm3 of oxygen gas is collected at 27 oC and 713.3 mm Hg pressure, what will the volume (in cm3) of the dry gas be at STP?
If 120 cm³ of oxygen gas is collected at 713.3 mm Hg pressure, the volume of the dry gas at STP is 0.102 cm³.
How do you calculate the volume of the dry gas to be at STP?To solve this problem, we will use the ideal gas law, which relates the pressure, volume, temperature, and number of moles of a gas:
PV = nRT
First, we need to convert the given conditions to the correct units. The temperature is already in Celsius, so we need to convert it to kelvins by adding 273.15:
T = 27 + 273.15 = 300.15 K
The pressure is given in millimeters of mercury (mm Hg), so we need to convert it to atmospheres (atm) to use in the ideal gas law. There are 760 mm Hg in 1 atm, so:
P = 713.3 mm Hg / 760 mm Hg/atm = 0.938 atm
Next, we can use the ideal gas law to find the number of moles of oxygen gas:
n = PV/RT = (0.938 atm)(120 cm³)/(0.08206 L·atm/(mol·K))(300.15 K) = 0.00454 mol
Finally, we can use the molar volume of a gas at STP (standard temperature and pressure) to find the volume of the dry gas at STP. At STP, the temperature is 273.15 K and the pressure is 1 atm. The molar volume of a gas at STP is 22.4 L/mol, so:
V = n(22.4 L/mol) = (0.00454 mol)(22.4 L/mol) = 0.102 cm³
Therefore, the volume of the dry gas at STP is 0.102 cm³.
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which of the following statements are true about entropy process? multiple select question. entropy generation can be used as a quantitative measure of irreversibilities. the performance of engineering systems is degraded by the presence of irreversibilities. entropy is a thermodynamic property. processes can occur in any direction without any restriction. the greater the extent of irreversibilities during a process, the smaller the entropy generation.
It is true that the greater the extent of irreversibilities during a process, the smaller the entropy generation will be. This is because irreversibilities cause energy losses that are not available to increase the entropy of the system.
This means that the more irreversible a process is, the higher the entropy generation will be. Second, the presence of irreversibilities in engineering systems degrades their performance. This is because irreversibilities cause energy losses and inefficiencies in the system.
Third, entropy is indeed a thermodynamic property that is related to the disorder or randomness of a system. Fourth, processes can occur in any direction, but the direction that increases the entropy of the system is the most probable one
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Help what's the answer?
The partial pressure of helium in the flask is 1.12 atm and the total pressure in the flask is 1.99 atm.
What is the partial pressure of the gas?To find the partial pressure of helium, we need to first find the moles of each gas present in the mixture.
Moles of methane:
n(CH4) = mass / molar mass = 2.68 g / 16.04 g/mol = 0.167 mol
Moles of helium:
n(He) = mass / molar mass = 0.864 g / 4.00 g/mol = 0.216 mol
Total moles of gas:
n(total) = n(CH4) + n(He) = 0.167 mol + 0.216 mol = 0.383 mol
To find the total pressure in the flask, we can use the ideal gas law:
PV = nRT
where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin. Rearranging this equation to solve for P:
P = nRT / V
where R = 0.0821 L·atm/mol·K is the gas constant.
Converting temperature to Kelvin:
T = 65°C + 273.15 = 338.15 K
Plugging in the values:
P = (0.383 mol) x (0.0821 L·atm/mol·K) x (338.15 K) / (5.93 L) = 1.99 atm
To find the partial pressure of helium, we can use the mole fraction of helium:
X(He) = n(He) / n(total) = 0.216 mol / 0.383 mol = 0.563
The partial pressure of helium is then:
P(He) = X(He) x P = 0.563 x 1.99 atm = 1.12 atm
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if a glass manufacturer has only a few of reducing pollutants, it will .
If a glass manufacturer has only a few costly ways of reducing pollutants, it will end up paying the pollution tax, option A.
A chemical or energy that is introduced into the environment and has negative consequences or reduces the usability of a resource is referred to as a pollutant or new entity. These can be either anthropogenic in origin (i.e., produced materials or results of biodegradation) or naturally formed (i.e., minerals or extracted chemicals like oil). When pollutants are present in sufficient quantities to have noticeable detrimental effects on the environment or public health, pollution results.
By altering the development rate of plant or animal species, or by affecting human amenities, comfort, health, or property values, a pollution may inflict long- or short-term damage.
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Complete question:
If a glass manufacturer has only a few ________________ of reducing pollutants, it will ____________________ .
A. costly ways; end up paying the pollution tax.
B. inexpensive ways; incur the pollution tax instead.
C. costly ways; do so to minimize its pollution taxes.
D. inexpensive ways; buy the most expensive technology.
Consider the energy diagram
Forward Reverse
Energy (kJ) −36
−7
48
Find ∆Eforward.
Answer in units of kJ/mol.
038 (part 2 of 4) 10.0 points
Find ∆Ereverse.
Answer in units of kJ/mol.
039 (part 3 of 4) 10.0 points
Find Ea.
Answer in units of kJ/mol.
040 (part 4 of 4) 10.0 points
Find E
′
a
.
Answer in units of kJ/mol.
E'a (also known as reverse activation energy) is the (Ea = +7 kJ/mol) energy barrier for the reverse reaction, which is the energy difference between the products and the transition state in the reverse direction.
What is Energy?
Energy is a fundamental concept in physics and refers to the ability or capacity to do work or cause change. It is a scalar quantity, typically measured in joules (J) or other units such as kilocalories (kcal) or electron volts (eV).
In general, the activation energy (Ea) is the energy barrier that must be overcome for a chemical reaction to occur. It is the energy difference between the reactants and the transition state or activated complex of the reaction. The activation energy can be determined from the energy diagram by subtracting the energy of the reactants from the peak energy of the transition state.
∆Eforward = -36 kJ/mol
∆Ereverse = +48 kJ/mol
Ea = +7 kJ/mol
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When baking soda is heated it decomposes according to the following reaction:
2 NaHCO3(s) ⇌ Na2CO3(s) + H2O(g) + CO2(g)
If sufficient baking soda is placed in a container and heated to 90°C, the total pressure of the gases is 0. 5451 atm. What is the value of Kp at that temperature?
The value of Kp at 90°C is zero. This indicates that the decomposition of baking soda at this temperature is essentially complete, and the equilibrium lies far to the right.
We can use the expression for the equilibrium constant Kp, which is given by:
Kp = (P([tex]CO_{2}[/tex] ) × P([tex]H_{2} O[/tex])) / (P([tex]Na_{2} CO_{3}[/tex] ))
where P([tex]CO_{2}[/tex]), P([tex]H_{2} O[/tex]), and P([tex]Na_{2} CO_{3}[/tex]) are the partial pressures of carbon dioxide, water vapor, and sodium carbonate, respectively, at equilibrium.
From the balanced equation, we know that for every 2 moles of [tex]NaHCO_{3}[/tex]that decompose, 1 mole of [tex]CO_{2}[/tex] is produced. Therefore, the partial pressure of [tex]CO_{2}[/tex] can be calculated as:
P([tex]CO_{2}[/tex] ) = (1/2) × (total pressure) = 0.2726 atm
Similarly, for every 2 moles of [tex]NaHCO_{3}[/tex] that decompose, 1 mole of Na2CO3 is produced. Therefore, the partial pressure of [tex]Na_{2} CO_{3}[/tex]can be calculated as:
P([tex]Na_{2} CO_{3}[/tex]) = (1/2) × (total pressure) = 0.2726 atm
Finally, the partial pressure of water vapor can be calculated as the difference between the total pressure and the partial pressures of CO2 and [tex]Na_{2} CO_{3}[/tex]:
P([tex]H_{2} O[/tex]) = (total pressure) - P([tex]CO_{2}[/tex]) - P([tex]Na_{2} CO_{3}[/tex]) = 0.5451 - 0.2726 - 0.2726 = 0.0 atm
This means that there is no water vapor present at equilibrium, and we can assume that its partial pressure is zero. Substituting these values into the expression for Kp, we get:
Kp = (P([tex]CO_{2}[/tex]) × P([tex]H_{2} O[/tex])) / (P([tex]Na_{2} CO_{3}[/tex]))
= (0.2726 × 0.0) / 0.2726
= 0.0
Therefore, the value of Kp at 90°C is zero. This indicates that the decomposition of baking soda at this temperature is essentially complete, and the equilibrium lies far to the right.
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what characteristic of carbohydrates is not commonly found in the previously studied classes of compounds?
Answer:
Their ability to act as a source of energy.
Explanation:
One characteristic of carbohydrates that are not commonly found in previously studied classes of compounds is their ability to act as a source of energy. Carbohydrates are considered the primary source of energy for living organisms and are broken down through cellular respiration to release energy for use in metabolic processes. In contrast, lipids, proteins, and nucleic acids have other primary functions in living organisms such as membrane structure, enzyme activity, and genetic information storage and expression.
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6Na + Fez0g -> 3NazO + 2Fe
If you are provided 200g of sodium and 250 grams of iron(Ill) oxide, how much of excess reagent is left?
The amount of excess reagent that will remain would be 11.76 g.
Stoichiometric problemTo determine the excess reagent in the reaction, we need to first determine which reactant is limiting and which reactant is in excess.
The balanced chemical equation for the reaction is:
6Na + Fe2O3 -> 3Na2O + 2Fe
The molar mass of Na is 23 g/mol, and the molar mass of Fe2O3 is 159.69 g/mol (2 x 55.85 g/mol for Fe + 3 x 16 g/mol for O).
Using the given masses, we can calculate the number of moles of each reactant:
Number of moles of Na = 200 g / 23 g/mol = 8.70 molNumber of moles of Fe2O3 = 250 g / 159.69 g/mol = 1.57 molAccording to the balanced chemical equation, 6 moles of Na react with 1 mole of Fe2O3. Therefore, the number of moles of Na required to react with 1.57 mol of Fe2O3 is:
(1.57 mol Fe2O3) x (6 mol Na/1 mol Fe2O3) = 9.42 mol Na
Since we only have 8.70 mol of Na available, it is the limiting reagent. This means that Fe2O3 is in excess.
To determine the amount of excess Fe2O3, we need to calculate how much Fe2O3 is required to react with 8.70 mol of Na:
(8.70 mol Na) x (1 mol Fe2O3/6 mol Na) x (159.69 g/mol Fe2O3) = 238.24 g Fe2O3
Since we only have 250 g of Fe2O3, the amount of excess Fe2O3 is:
250 g - 238.24 g = 11.76 g
Therefore, the amount of excess Fe2O3 left after the reaction is 11.76 g.
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consider a silicon crystal containing 10 12 phosphorous atoms per cubic centimeter. is the conductivity increasing or decreasing when the temperature is raised from 300 ? c to 350 ? c? explain by giving numerical values for the mechanisms involved.
The silicon crystal becomes an n-type semiconductor at normal temperature when the phosphorous atoms contribute an extra electron, producing an overabundance of negative charge carriers.
The conductivity of the crystal will rise as the temperature is raised from 300°C to 350°C. This is because a greater temperature results in a higher concentration of free charge carriers since there is more thermal energy available to promote electrons from the valence band to the conduction band.
We can use the following equation to calculate the conductivity change:
σ = nqμ
When the charge of an electron is q, the number of charge carriers is n, the conductivity is, and the mobility of the charge carriers. If the number of charge carriers increases by 10% as a result of the temperature increase.
As a result, we can see that raising the temperature from 300°C to 350°C causes the conductivity to increase by about 14%.
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what causes the release of energy from a chemical bond? group of answer choices atoms having an uneven number of electrons in their outer shell the sharing of electrons between atoms the breaking of the bond the damage from free radicals
Option b. The breaking of the chemical bond causes the release of energy from a chemical bond.
The arrival of energy from a substance bond happens when the bond is broken, either through synthetic responses or actual cycles. Compound bonds result from the sharing or move of electrons among particles, and the energy expected to frame a bond is put away inside the actual bond. At the point when the bond is broken, this put away energy is delivered as dynamic energy, intensity, or light. How much energy delivered relies upon the strength of the bond and the particular synthetic responses included. In this way, the breaking of the bond is the reason for energy discharge, while different choices - iotas having a lopsided number of electrons, harm from free revolutionaries, and the sharing of electrons between molecules - don't straightforwardly connect with the arrival of energy from a bond.
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