Question
In which of the following processes will ΔS°
be negative?

a) C2H5OH(l)→C2H5OH(g)

b) NaCl(s)→NaCl(l)

c) CO2(s)→CO2(g)

d) Cl2(g)→Cl2(l)

Answers

Answer 1
The right response is (b).

The entropy of a framework is a proportion of its problem or irregularity. A framework with more confusion has a higher entropy. By and large, processes that include a lessening all together or an expansion in the quantity of potential states for the framework will have a negative ΔS°.

During the time spent dissolving sodium chloride (NaCl) in water, the strong NaCl breaks up into individual Na+ and Cl-particles. This outcomes in a lot more prominent number of potential states for the framework, as the particles can move around uninhibitedly in the arrangement. Hence, the entropy of the framework increments, and ΔS° is positive.

During the time spent freezing water (H2O), the fluid water particles organize themselves into a normal precious stone design. This outcomes in a diminishing in the quantity of potential states for the framework, as the particles are currently bound to a particular area in the gem. In this way, the entropy of the framework diminishes, and ΔS° is negative.

During the time spent sublimation, strong carbon dioxide (CO2) changes straightforwardly into vaporous carbon dioxide (CO2). This doesn't include an adjustment of the quantity of moles of gas, however it includes an adjustment of the condition of issue. Gases have a higher entropy than solids, so the entropy of the framework increments, and ΔS° is positive.

During the time spent gathering chlorine gas (Cl2) into fluid chlorine (Cl2), the vaporous chlorine particles orchestrate themselves into an ordinary fluid design. This outcomes in a reduction in the quantity of potential states for the framework, as the particles are currently restricted to a particular area in the fluid. Subsequently, the entropy of the framework diminishes, and ΔS° is negative.
Answer 2

Cl2(g)→Cl2(l): ∆S° will be negative because the disordered gas is converted to the ordered liquid. Therefore, option (D) is correct.

What is The entropy change (∆S°)?

The entropy change (∆S°) refers to the change in the degree of disorder or randomness of a system in a chemical reaction or physical change that occurs at a constant temperature and pressure. It is a thermodynamic function that measures the amount of energy that is unavailable to do useful work in a system.

If ∆S° is positive, it indicates an increase in entropy, which means that the system becomes more disordered, chaotic, and random. In contrast, if ∆S° is negative, it indicates a decrease in entropy, which means that the system becomes more ordered, organized, and predictable.

The ∆S° value is affected by several factors, such as the physical state of the reactants and products, the number of particles involved, and the temperature and pressure at which the reaction occurs. A negative ∆S° value suggests that the reaction favors the reactants, whereas a positive ∆S° value indicates that the reaction favors the products.

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Related Questions

Calculate the density of Sulfur dioxide gas at a temperature of 15oC and pressure of 300 torr. Convert to atm

Answers

The density of sulfur dioxide gas at a temperature of 15°C and pressure of 300 torr is 0.001022 g/cm³, or 0.001022 g/mL, or 1.022 kg/m³, or 0.01022 g/L when converted to atm.

What is density?

To calculate the density of sulfur dioxide gas at a temperature of 15°C and a pressure of 300 torr, we can use the ideal gas law:

PV = nRT

where P is the pressure in atmospheres, V is the volume in liters, n is the number of moles, R is the ideal gas constant (0.08206 L·atm/(mol·K)), and T is the temperature in Kelvin.

First, we need to convert the given temperature of 15°C to Kelvin:

T = 15°C + 273.15 = 288.15 K

Next, we can rearrange the ideal gas law to solve for the number of moles:

n = PV/RT

where we can use the given pressure of 300 torr and convert it to atm by dividing by 760 torr/atm:

P = 300 torr / 760 torr/atm = 0.3947 atm

Substituting the values into the equation, we get:

n = (0.3947 atm) V / (0.08206 L·atm/(mol·K) × 288.15 K)

Now, we can use the molar mass of sulfur dioxide, which is 64.06 g/mol, to convert the number of moles to mass:

mass = n × molar mass

Finally, we can calculate the density of sulfur dioxide gas using the mass and volume:

density = mass / V

To convert the density from g/L to g/cm³, we divide by 1000.

Putting it all together, we get:

n = (0.3947 atm) V / (0.08206 L·atm/(mol·K) × 288.15 K)

n = 0.01595 V

mass = n × molar mass = 0.01595 V * 64.06 g/mol = 1.022 gV

density = mass / V = 1.022 gV / V = 1.022 g/L = 0.001022 g/cm³

Therefore, the density of sulfur dioxide gas at a temperature of 15°C and pressure of 300 torr is 0.001022 g/cm³, or 0.001022 g/mL, or 1.022 kg/m³, or 0.01022 g/L when converted to atm.

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Complete question is: The density of Sulfur dioxide gas at a temperature of 15oC and pressure of 300 torr is 0.01022 atm.

CaCO3 + 2HCI=CaCl2 + H₂O + CO₂
6. If 6.32 grams of CaCO3 reacts with HCl, how many liters of water, H₂O, are formed?

Answers

Water produced by 6.32 grams of [tex]CaCO_{3}[/tex] reacts with [tex]HCl[/tex] reaction is 0.11376 L as the density of water is 1.

How to calculate volume of water?

[tex]CaCO_{3}[/tex]'s molar mass is equal to 100 g/mol (40 + 12 + 16 3 g/mol).

HCl's molar mass is (1 + 35.5) g/mol, or 36.5 g/mol.

Water's molecular weight is (12 + 16) g/mol, or 18 g/mol.

[tex]CaCO_{3}[/tex]initial mole number = (6.32g) / (100 g/mol) = 0.00632mol

Initial number of moles of HCl = (35.5 g/mol/36.8 g) = 1.04 mol

Mole ratio:  [tex]CaCO_{3}:HCl:CaCl_{2}:H_{2}O[/tex]= 1: 2: 1: 1. [tex]CaCO_{3}:HCl:CaCl_{2}:H_{2}O[/tex]

If [tex]CaCO_{3}[/tex] fully reacts, [tex]HCl[/tex] is required at a rate of (0.00632mol) x 2 (equals 0.01264mol <1.04 mol).

[tex]HCl[/tex] is hence abundant. As a reactant, [tex]CaCO_{3}[/tex] is the limiting one.

Total number of [tex]CaCO_{3}[/tex] reactions: 0.00632moles

No. of moles of water created / No. of moles of [tex]CaCO_{3}[/tex] reacting / 0.00632mol

0.11376 g of [tex]H_{2}O[/tex]were generated from (0.00632 mol) by (18 g/mol).

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C6H12O6 + 6 O₂ ---> 6CO₂ + 6 H₂O
How many moles of oxygen are needed to burn 5.00 moles of glucose (C6H12O6)?

Answers

Answer is 30 mol

Explanation
Ratio of C6H12O6:O2 IS 1:6
Mole of O2 = 5x6=30 mol

d. Addition of a catalyst
7) At 15 °C, a certain reaction is able to produce 0.80 moles of product per minute? At what rate might
the product be produced at 25 °C?
a. 0.80 moles per minute
b. 1.6 moles per minute
c. 0.40 moles per minute
d. 0.20 moles per minute

Answers

Addition of a catalyst, at 15 °C, a certain reaction is able to produce 0.80 moles of product per minute at 25 °C it will produce at a rate of 0.40 moles per minute. The correct option to this question is C.

Effect of temperatureAs the concentration of an enzyme rises, so does the rate of an enzyme-catalyzed reaction. An enzyme-catalyzed process moves more quickly at higher temperatures than it does at lower ones. The protein gets denatured at higher temperatures, which also noticeably slows down the rate of the reaction.With a reduced activation energy, a catalyst offers the reaction a different pathway. The rate will rise since there are more particles with activation energy today. The activation energy does not change as the temperature rises.The amount of energy that can be transformed into activation energy in a collision increases with temperature, which will speed up the reaction rate. The opposite would happen if the temperature dropped.

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To answer this question, you may need access to the periodic table of elements.

Which of these pairs of atoms would experience an ionic bond?

a.)
K and Br
b.)
S and O
c.)
H and S
d.)
Cl and Cl

Answers

K and Br since an halogen and a metal make a salt

Strong Acid/Strong Base Titration.
100 mL of 0.10M HNO3 titrated with 0.10M NaOH
a. Initial pH, 0.0 mL of NaOH
Circle one: Type of solution (strong acid, weak acid, strong base, weak base,
buffer, neither)
Reaction:

Answers

The compound NaOH as shown is a strong base.

Is NaOH a strong base?

NaOH (sodium hydroxide) is considered a strong base. A strong base is a base that dissociates completely in water to form hydroxide ions (OH-) and cations. NaOH is highly soluble in water and, when added to water, it completely dissociates into Na+ and OH- ions, which makes it a strong base.

The strength of a base depends on the extent of its dissociation in water. Strong bases dissociate completely in water, while weak bases dissociate only partially. The dissociation of a base is usually represented by its base dissociation constant (Kb), which is the equilibrium constant for the reaction of the base with water to form hydroxide ions.

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im struggling

What quantity of heat (in kJ) would be required to convert 13.4 g of ice to water at 0.00 °C? (∆Hfus = 6.01 kJ/mol for water)

Answers

Around 80.5 KJ

Multiply Heat of Fusion and Mass to get the q value.

What is a gas in the atmosphere that blocks high amount of infrared light?
What are these types of gases called?

Answers

The gases in the Earth's atmosphere that block a high amount of infrared light are called greenhouse gases.

These include carbon dioxide (CO₂), methane (CH₄), nitrous oxide (N₂O), and fluorinated gases, among others.

Greenhouse gases trap heat within the Earth's atmosphere and play a significant role in regulating the Earth's temperature.

However, when their concentration increases beyond natural levels, they can cause the Earth's temperature to rise, leading to global warming and climate change.

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In an experiment, 5 g of Copper was heated with excess Sulfur to yield 4 g of Copper(I)Sulfide. What is the % yield?

Answers

The percent yield of copper(I) sulfide in this experiment is 31.83%.

What is percent yield?

To calculate the percent yield, we need to compare the actual yield (the amount of product that was obtained in the experiment) with the theoretical yield (the amount of product that should have been obtained if the reaction had gone to completion).

The balanced chemical equation for the reaction between copper and sulfur to form copper(I) sulfide is:

Cu + S →  [tex]Cu_{2}S[/tex]

The molar mass of Cu is 63.55 g/mol, and the molar mass of S is 32.06 g/mol. The molar mass of  [tex]Cu_{2}S[/tex]  is 159.17 g/mol.

First, we need to calculate the theoretical yield of copper(I) sulfide using the amount of copper used in the experiment:

5 g Cu × (1 mol Cu / 63.55 g Cu) × (1 mol [tex]Cu_{2}S[/tex] / 1 mol Cu) × (159.17 g  [tex]Cu_{2}S[/tex] / 1 mol [tex]Cu_{2}S[/tex] ) = 12.57 g  [tex]Cu_{2}S[/tex]

So the theoretical yield of copper(I) sulfide is 12.57 g.

The actual yield obtained in the experiment is 4 g.

The percent yield is then:

percent yield = (actual yield / theoretical yield) × 100%

percent yield = (4 g / 12.57 g) × 100%

percent yield = 31.83%

Therefore, the percent yield of copper(I) sulfide in this experiment is 31.83%.

What is theoretical yield ?

The theoretical yield is the amount of product that would be obtained in a chemical reaction if it went to completion, meaning that all the limiting reactant was used up and no product was lost. It is calculated using stoichiometry, which involves balancing the chemical equation for the reaction and using the coefficients to determine the mole ratio between the reactants and products.

Theoretical yield is often used as a reference value to compare with the actual yield obtained in an experiment, which is the amount of product actually obtained from the reaction. The percent yield can then be calculated by dividing the actual yield by the theoretical yield and multiplying by 100%.

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Which state of matter - solid, liquid, or gas- tends to have unique factors (different from the other two) to consider when discussing solubility

Answers

The state of matter that tends to have unique factors to consider when discussing solubility compared to the other two states (solid and gas) is the liquid state.

Which state has unique factors?

Solubility refers to the ability of a substance (solute) to dissolve in a particular solvent to form a homogeneous mixture (solution). Various factors can affect the solubility of a substance, including temperature, pressure, and the nature of the solute and solvent.

In the case of liquids, the unique factor to consider when discussing solubility is often temperature. The solubility of many solid solutes in liquids generally increases with increasing temperature. This is because higher temperatures provide more energy to break the intermolecular forces between solute particles, allowing them to disperse more evenly throughout the solvent.

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Consider the following reaction at 298 K.

C(graphite)+2Cl2(g)⟶CCl4(l)Δ∘=−139 kJ

Calculate the following quantities. Refer to the standard entropy values as needed.

Δsys= ? J/K

Δsurr= ? J/K

Δuniv= ? J/K

Answers

System entropy = -80.8 J/K Surrounding entropy = 253.7 J/K The universe's entropy is 172.9 J/K. The reaction is unplanned. The procedure is a natural one.

In layman's terms, what is entropy?

Entropy is a measure of energy quality in the way that as lower the entropy, the more desirable the energy. Energy stored in a well-organized manner (the efficient library has a lower entropy. The entropy of energy contained in a chaotic manner (the random-pile library) is high.

What is another name for entropy?

Entropy is a gauge of a system's randomness or disorder. Entropy is greater in gases than in liquids, and greater in liquids than in solids. Order and disorder are important concepts in physical systems also known as randomness.

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A sample with the phase diagram below starts at room temperature (25oC) and 1 atm. What phase change would the sample go through if it was cooled to 80 K?

a)Condensation (gas to liquid)

B)Fusion (solid to liquid)

C)Deposition (gas to solid)

D)Vaporization (liquid to gas)

E)Sublimation (solid to gas)

F)Freezing (liquid to solid)

Answers

Answer: C)Deposition (gas to solid)

Explanation: According to the phase diagram, at room temperature (25°C) and 1 atm, the sample is in the gas phase.  As the temperature decreases to 80 K, it falls below the sublimation curve. T he sublimation curve represents the conditions at which a substance can change directly from a solid to a gas or from a gas to a solid without passing through the liquid phase.

Since the sample is in the gas phase at room temperature, cooling it to 80 K would cause it to go through the process of deposition, where the gas particles directly transform into a solid without first becoming a liquid.  This is indicated by the section of the phase diagram below the sublimation curve.

If 14.5 kJ of heat were added to 485 g of liquid water, how much would its temperature increase?


2.94 x 10⁴ °C

0.00715 °C

7.15 °C

7.15 x 10³ °C

Answers

[tex] \ddots[/tex] The heat energy can be deduced as -

[tex] \odot\sf \footnotesize{Heat \:energy = Mass\: of\: substance\times Specific \:heat\times Change\: in \:temperature}\\[/tex]

[tex] \qquad :\implies\sf \boxed{\sf Q = mS\Delta T}\\[/tex]

Where-

Q = Heat energy (Joules, J)

m = Mass of a substance (g or,kg)

S = Specific heat ( J/g∙°C or, J/kg.°C)For liquid water, this value is 4.18J/g∙°C∆ is a symbol meaning "the change in"

∆T = Change in temperature (Kelvins, K)

In this instant, we are given -

Heat energy,Q = 14.5 KJ = 14500JMass of substant, m = 485 g

[tex] \ddots[/tex] Now that we have all the required values except ∆T,so we can plug the rest of the known values into the formula and solve for ∆T -

[tex] \qquad :\implies\sf \underline{Q = mS\Delta T}\\[/tex]

[tex] \qquad :\implies\sf 14500 = 485 \times 4.18 \times \Delta T\\[/tex]

[tex] \qquad :\implies\sf 14500 = 2027.3\times \Delta T\\[/tex]

[tex] \qquad :\implies\sf \Delta T = \dfrac{14500}{2027.3}\\[/tex]

[tex] \qquad :\implies\sf \Delta T = 7.152370........\:°C\\[/tex]

[tex] \qquad :\implies\sf \underline{\boxed{\sf \Delta T=7.15\:°C}}\\[/tex]

[tex] \ddots[/tex]Correct answer - [tex]\boxed{\sf \Delta T=7.15\:°C}.[/tex]

The water would increase its temperature by approximately 7.15°C if 14.5 kJ of heat were added. The third option is correct.

This is an exercise in specific heat and thermal conductivity which are two important physical properties that describe how materials interact with heat. Specific heat refers to the amount of energy required to raise the temperature of a material by a given amount, while thermal conductivity refers to a material's ability to transfer heat through itself.

The formula for specific heat is Q = mcΔT, where Q is the amount of heat transferred, m is the mass of the material, c is the specific heat, and ΔT is the change in temperature. The unit of measure for specific heat is J/(g*°C).

On the other hand, thermal conductivity is measured in terms of the amount of heat that is transferred through a material per unit time and area, given a temperature difference. It is expressed as the amount of heat transferred per second, per square meter, per meter of material thickness, when the temperature difference between the extremes is one Kelvin. Its formula is Q/t = -kA(∆T/∆x), where Q/t is the heat transfer rate, k is the thermal conductivity, A is the cross-sectional area, ∆T is the temperature difference, and ∆ x is the thickness of the material.

These properties are useful for understanding how materials interact with heat in a variety of situations, from building design to heating and cooling equipment manufacturing.

We solve the exercise, for the temperature change:

Now to calculate the temperature rise of 485 g of liquid water when 14.5 kJ of heat is added to it, we can use the formula:

Q = mcΔT

We must know that it has a quantity of heat of 14.5 Kj, with a mass of 485 g. The specific heat capacity of water is 4.18 J/(g °C).

First, we need to convert the heat added to joules:

Q = 14.5 KJ × (1000 J/1 KJ)

Q = 14500 J

We can then solve for ΔT. We clear the formula.

ΔT = Q / (m × c)

We substitute our data in the formula and solve the temperature change:

ΔT = Q / (m × c)

ΔT = (14500 J)/(485 g × 4.18 J/(g·°C))

ΔT ≈ 7.15 °C

The water would increase its temperature by approximately 7.15°C if 14.5 kJ of heat were added.

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Aspirin (acetylsalicylic acid) has a pKa of 2.97
a. Draw the structure the conjugate base of aspirin.
b. Calculate the percentage of aspirin (acetylsalicylic
acid) available for absorption in the stomach (pH = 2.0
and in the duodenum at (pH = 4.5).

Answers

a)  The conjugate base of aspirin (acetylsalicylic acid) is formed when the acidic proton (H+) is removed from the carboxylic acid group (-COOH) in the molecule.

b)  More aspirin will be available for absorption in the duodenum (97%) compared to the stomach (12%).

Percentage of aspirin for absorption

a. The conjugate base of aspirin (acetylsalicylic acid) is formed when the acidic proton (H+) is removed from the carboxylic acid group (-COOH) in the molecule.

b. The percentage of aspirin available for absorption depends on the degree of ionization of the molecule, which is related to the pH of the surrounding medium. At pH values below the pKa (2.97), most of the molecules exist in the protonated form (HA), while at pH values above the pKa, most of the molecules exist in the deprotonated form (A-).

Using the Henderson-Hasselbalch equation:

pH = pKa + log([A-]/[HA])

We can calculate the ratio of deprotonated (A-) to protonated (HA) forms at different pH values. At pH 2.0, the ratio is:

2.0 = 2.97 + log([A-]/[HA])

log([A-]/[HA]) = -0.97

[A-]/[HA] = 0.12

So, at pH 2.0, only 12% of the aspirin molecules are in the deprotonated form and available for absorption.

At pH 4.5, the ratio is:

4.5 = 2.97 + log([A-]/[HA])

log([A-]/[HA]) = 1.53

[A-]/[HA] = 31.6

So, at pH 4.5, 97% of the aspirin molecules are in the deprotonated form and available for absorption.

Therefore, more aspirin will be available for absorption in the duodenum (97%) compared to the stomach (12%).

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what is the awnser for these

Answers

7a. Using the mole ratio from the balanced chemical equation, we can set up the following proportion:

n(N₂)/n(NH₃) = 1/2

where n(N₂) is the number of moles of N₂ and n(NH₃) is the number of moles of NH₃. Solving for n(N₂), we get:

n(N₂) = (10.0 mol NH₃) / (2 mol N₂/mol NH₃) = 5.00 mol N2

Therefore, 5.00 moles of nitrogen would be needed to make 10.0 moles of ammonia.

7b. Using the same mole ratio as above, we can set up the following proportion:

n(NH₃)/n(H₂) = 2/3

where n(H₂) is the number of moles of H₂. Solving for n(NH₃), we get:

n(NH₃) = (9.00 mol H2) x (2 mol NH3/3 mol H₂) = 6.00 mol NH₃

Therefore, 6.00 moles of ammonia could be made by completely reacting 9.00 moles of hydrogen.

7c. Again, using the same mole ratio as above, we can set up the following proportion:

n(N₂)/n(H₂) = 1/3

where n(N₂) is the number of moles of N₂. Solving for n(H₂), we get:

n(H₂) = (7.41 mol N2) x (3 mol H₂/1 mol N₂) = 22.2 mol H₂

Therefore, 22.2 moles of hydrogen would be needed to react completely with 7.41 moles of nitrogen.

8a. The amounts of reactants consumed and the amount of product made can be calculated using stoichiometry, which is based on the mole ratio from the balanced chemical equation. However, the mole ratio from the balanced chemical equation cannot be interpreted as a ratio of masses, since the molar mass (and thus the mass) of each substance is different.

8b. The mole ratio from the balanced chemical equation is based on the number of moles of each substance, which is proportional to the mass of each substance. Therefore, by using the molar mass of each substance, we can convert the mole ratio to a mass ratio. However, the mole ratio itself cannot be interpreted as a ratio of masses.

9a. Yes, the mole ratio from a balanced chemical equation can be interpreted as a ratio of masses. This is because the mole ratio is determined based on the stoichiometric coefficients in the balanced equation, which represent the number of moles of each substance involved in the reaction. Since the molar mass (mass per mole) of each substance is known, the mole ratio can be used to determine a mass ratio.

9b. The mathematical concept that explains how the mole ratio from a balanced chemical equation can be interpreted as a ratio of masses is the mole-to-mole conversion factor. This conversion factor is based on the stoichiometric coefficients in the balanced equation, which represent the mole ratio between the reactants and products. By multiplying the mole ratio by the molar mass of a substance, the ratio can be converted to a mass ratio.

To solve the problem "What mass of nitrogen is needed to produce 30.0 g of ammonia?", we would need to use the concept of stoichiometry and mole-to-mole conversions. We can start by writing the balanced chemical equation for the reaction:

N₂(g) + 3H₂(g) → 2NH₃(g)

From the equation, we can see that the mole ratio of N2 to NH₃ is 1:2. We can use this ratio to determine the number of moles of N2 needed to produce 1 mole of NH₃:

1 mole N₂ : 2 moles NH₃

Next, we can use the molar mass of NH₃ to convert the moles of NH₃ to grams:

2 moles NH₃ x 17.03 g NH₃/mole = 34.06 g NH₃

So, for every 34.06 g of NH₃ produced, we need 1 mole of N₂. Using this information, we can set up a proportion to solve for the mass of N₂ needed to produce 30.0 g of NH₃:

1 mole N₂ : 34.06 g NH₃ = x moles N₂ : 30.0 g NH₃

Solving for x, we get:

x moles N₂ = (30.0 g NH₃ x 1 mole N₂) / 34.06 g NH₃ = 0.881 moles N₂

Finally, we can convert the moles of N₂ to grams using the molar mass of N₂:

0.881 moles N₂ x 28.01 g N₂/mole = 24.67 g N₂

Therefore, we would need 24.67 g of nitrogen to produce 30.0 g of ammonia.

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6. What is the pH of a 0.25 M solution of NH4Cl? [Kb(NH3) = 1.8  10–5

Answers

The Ammonium Chloride solution at 0.25 M has a pH of 2.67.

Why is the pH of Ammonium Chloride below 7?

As a result, the weak basic (Chlorine) in the solution is overpowered by the conjugate acid (Ammonium cation), making the solution mildly acidic. According to the equation pH =log[Hydrogen ion], an acidic solution has a pH lower than 7. Aqueous ammonium chloride solution has a pH that is less than 7.

Ammonium cation + Water ⇌ Nitrogen trihydride + Hydronium ion

Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]

[Nitrogen trihydride] = [Hydronium ion] = x

[Ammonium cation] = 0.25 - x

Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]

1.8 × 10–5 = x² / (0.25 - x)

1.8 × 10–5 = x² / 0.25

x² = 4.5 × 10–6

x = 2.12 × 10–3

pH = -log[Hydronium ion] = -log(2.12 × 10–3) = 2.67

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9) For the balanced equation (with hypothetical
2A + 3B
[B] (mol/L)
0.100
0.100
0.200
Exp#
1
2
3
[A](mol/L)
0.100
0.200
0.100
a. What is the order for each reactant?
b. What is the overall order for the reaction?
C + 4D
initial rate (M/sec)
0.022
0.176
0.044

Answers

The order for reactant A is 2 and the order for reactant B is 1. For the first reaction, the overall order of the reaction is 3 and for the second reaction, the overall order of the reaction is 5.

What is the order of a reaction?

The order of a reaction is the sum of the exponents in the rate law expression that relates the rate of a chemical reaction to the concentrations of the reactants.

To determine the order of each reactant, we need to compare the initial rates of reaction at different concentrations while keeping the concentration of the other reactant constant.

For reactant A:

Exp#1 (0.100 M A, 0.100 M B): initial rate = k(0.100)^2(0.100) = 0.001 k

Exp#2 (0.200 M A, 0.100 M B): initial rate = k(0.200)^2(0.100) = 0.004 k

Exp#3 (0.100 M A, 0.200 M B): initial rate = k(0.100)^2(0.200) = 0.002 k

We can see that when the concentration of A doubles (Exp#1 to Exp#2), the initial rate quadruples, which indicates that A is second order. When the concentration of B doubles (Exp#1 to Exp#3), the initial rate doubles, which indicates that B is first order.

Therefore, the order for reactant A is 2 and the order for reactant B is 1.

To determine the overall order of the reaction, we add the orders of the reactants:

Overall order = 2 (order of A) + 1 (order of B) = 3

Therefore, the overall order of the reaction is 3.

For the second reaction, we can see that the rate depends on the concentration of both reactants, and we cannot determine their individual orders without further information or experiments. However, we can determine the overall order of the reaction by adding the exponents of the concentration terms in the rate law:

Overall order = 1 + 4 = 5

Therefore, the overall order of the reaction is 5.

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Write the structure of the product. If no reaction occurs write NR.
a. H3C-C=CH₂ + Br2
O.
+ KMnO4 (aq)
d.

b.
C. H3C-CH=CH-CH3 + H₂SO4 (conc.) —
+ KMnO4 (aq) -

Answers

a. The product of the reaction between [tex]H_{3}C[/tex]-C=CH₂ and [tex]Br_{2}[/tex] is 1,2-dibromo-2-methylpropane:  [tex]H_{3}C[/tex]-C=CH₂ + [tex]Br_{2}[/tex]  → BrCH₂ -CH(Br)-[tex]CH_{3}[/tex]

b. The product of the reaction between  [tex]H_{3}C[/tex]-CH=CH-[tex]CH_{3}[/tex] and conc.  [tex]H_{2}SO _{4}[/tex] is 2-methylpropene:

[tex]H_{3}C[/tex]-CH=CH-[tex]CH_{3}[/tex] + [tex]H_{2}SO _{4}[/tex] →  [tex]H_{3}C[/tex]-C([tex]CH_{3}[/tex])=CH₂ + H₂O

c. The product of the reaction between [tex]KMnO_{4}[/tex] (aq) and any organic compound is typically a mixture of products, depending on the specific organic compound being reacted. Therefore, the structure of the product cannot be determined without additional information about the organic compound being reacted.

d. NR means that no reaction occurs.

What is product of the reaction ?

In chemistry, the product of a reaction refers to the substances that are formed as a result of a chemical reaction. These substances are formed by the rearrangement of atoms and molecules in the reactants. The products of a chemical reaction are typically represented by a chemical equation, which shows the reactants on the left side of the equation and the products on the right side of the equation. In many cases, the products of a chemical reaction have different properties than the reactants, and they can be used in a variety of applications in chemistry, biology, and other fields.

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write the correct IUPAC for this molecule.
I need help please

Answers

I think it is 2,4-dimethylpentane

Question 5(Multiple Choice Worth 3 points)
(07.02 LC)

The substances below are listed by increasing specific heat capacity value. Starting at 30.0 °C, they each absorb 100 kJ of thermal energy. Which one do you expect to increase in temperature the least?

a) Cadmium, 0.230 J/(g °C)
b) Sodium, 1.21 J/(g °C)
c) Water, 4.184 J/(g °C)
d) Hydrogen, 14.267 J/(g °C)

Answers

Component form of the vector v is as follows: 4 3 1.5 1 Using the standard basis vectors I and j), express the vector w as follows: 3 two 1 4 pp . 1 3 w 3.5 C. V plus w= d. Determine the vector v's magnitude

What does "vector" mean?

Latin word for "carrier" is "vector." Point A is transported to point B by vectors. The orientation of the vectors AB is the direction in which point A is moved in relation to point B, and the amplitude of the vector is the width of the line connecting the two locations A and B. The terms Euclidean vectors and spatial vectors are also used to refer to vectors.

A vector space is what?

A vector space, also known as a linear space, is a collection of things called vectors that can be added to and multiplied ("scaled") by figures called scalars in the fields of mathematics, physics, and engineering.

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How many mathib are there?

Answers

The main branches of mathematics are algebra, number theory, geometry and arithmetic.

20. Calculate the mole fractions (X) of each compound in each of the following solutions:

a. 19.4 g of H2SO4 in 0.251 L of H20 (density of water is 1.00 g/mL)

b.35.7 g of KBr in 16.2 g of water

C.233 g of CO2 in 0.409 L of water

Answers

[tex]CO_{2}[/tex]The following compounds' mole fractions (X) are (a)0.986 (b)0.750 (c)0.811 for the given solutions.

How can the mole fraction of 19.4 g of H2SO4 in 0.251 L of water be determined?

[tex]H_{2}SO_{4}[/tex] mass is 19.4 g.

[tex]H_{2}SO_{4}[/tex]'s molecular weight is 98.08 g/mol.

It's molecular weight is 19.4 g/98.08 g/mol, or 0.1979 mol.

Density times volume is 1.00 g/mL times 0.251 L and 251 g for water mass.

[tex]H_{2} O[/tex] has a molecular weight of 18.02 g/mol.

Water moles are equal to 251 g / 18.02 g/mol, or 13.93 mol.

The solution's total moles are equal to 0.1979 mol plus 13.93 mol, or 14.13 mol.

Sulphuric Acid's mole fraction is equal to 0.1979 mol/14.13 mol, or 0.014.

Water mole fraction is equal to 13.93 mol / 14.13 mol, or 0.986 mol.

How can the mole fraction of 35.7 g of KBr in 16.2 g of water be determined?

KBr's mass is 35.7 g.

KBr has a molecular weight of 119 g/mol.

The formula for KBr is 35.7 g/119 g/mol, which equals 0.300 mol.

16.2 g of water in mass

Water has a molecular weight of 18.02 g/mol.

Water moles are equal to 16.2 g / 18.02 g/mol, or 0.899 mol.

The solution has a total of 1.199 moles (0.300 mol + 0.899 mol).

The mole fraction of KBr is equal to 0.300 mol/1.199 mol, or 0.250

Water mole fraction is equal to 0.899 mol / 1.199 mol, or 0.750 moles.

How can the mole fraction of 233 g of CO2 in 0.409 L of water be determined?

[tex]CO_{2}[/tex] mass = 233 g

It has a molecular weight of 44.01 g/mol.

Its moles are equal to 233 g / 44.01 g/mol, or 5.291 mol.

Water volume equals 0.409 L.

Water has a molecular weight of 18.02 g/mol.

(density × volume) / molecular weight (1.00 g/mL 409 mL) / 18.02 g/mol = 22.71 mol = number of moles of water

The solution's total moles are equal to 5.291 mol plus 22.71 mol, or 28.00 mol.

[tex]CO_{2}[/tex] mole fraction = 5.291 moles / 28.00 moles = 0.189

[tex]H_{2} O[/tex] mole fraction is 22.71 mol/28.00 mol, or 0.811 moles.

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Where does aluminum metal form during the electrolysis of aluminum ore?
at the positive anode
at the positive cathode
at the negative cathode
at the negative anode

Answers

At the anode:
During the process of electrolysis, Aluminium ions that are positively charged gain electrons from the cathode and form molten aluminium

A mixture of 80.0 g of chromium(III) oxide (Cr2O3) and 8.00 g of carbon (C) is used t produce elemental chromium (Cr) by the reaction Cr2O3 + 3 C 2 Cr+3 CO (a) What is the theoretical yield of Cr that can be obtained from the reaction mixture! (b) The actual yield is 21.7 g Cr. What is the percent yield for the reaction?​

Answers

Here's a more detailed step-by-step calculation for the theoretical yield and percent yield of chromium (Cr) in the given reaction:

Given: Mass of chromium(III) oxide (Cr2O3) = 80.0 g Mass of carbon (C) = 8.00 g Actual yield of Cr = 21.7 g

Step 1: Calculate the molar mass of Cr2O3 and C. Molar mass of Cr2O3 = 2 x (51.996 g/mol) + 3 x (15.999 g/mol) = 151.996 g/mol Molar mass of C = 12.011 g/mol

Step 2: Convert the masses of Cr2O3 and C to moles. Moles of Cr2O3 = Mass of Cr2O3 / Molar mass of Cr2O3 = 80.0 g / 151.996 g/mol = 0.527 mol (rounded to three decimal places)

Moles of C = Mass of C / Molar mass of C = 8.00 g / 12.011 g/mol = 0.666 mol (rounded to three decimal places)

Step 3: Determine the limiting reactant. The limiting reactant is the one that is completely consumed and determines the maximum amount of product that can be formed. In this case, we compare the moles of Cr2O3 and C to see which one is limiting.

From the balanced equation: Cr2O3 + 3C -> 2Cr + 3CO

We can see that 1 mol of Cr2O3 requires 3 moles of C to react completely and produce 2 moles of Cr. Therefore, the limiting reactant is C, as we have 0.666 mol of C, which is less than the 0.527 mol of Cr2O3.

Step 4: Calculate the theoretical yield of Cr. The theoretical yield of Cr is the maximum amount of Cr that can be obtained based on the limiting reactant.

Moles of limiting reactant (C) = 0.666 mol Molar mass of Cr = 51.996 g/mol

Theoretical yield of Cr = Moles of limiting reactant (C) x Molar mass of Cr = 0.666 mol x 51.996 g/mol = 34.65 g (rounded to two decimal places)

Step 5: Calculate the percent yield of Cr. The percent yield is a measure of how much of the theoretical yield was actually obtained.

Actual yield of Cr = 21.7 g Theoretical yield of Cr = 34.65 g

Percent yield = (Actual yield / Theoretical yield) x 100% = (21.7 g / 34.65 g) x 100% = 62.7% (rounded to three significant figures)

Therefore, the percent yield for the reaction is approximately 62.7%.

When ΔH > 0, the reaction is considered to be ________.


endothermic

combustion

exothermic

expansion

Answers

Endothermic since it requires heat from the surrounding

What is eutectic temperature

Answers

The eutectic point is the lowest temperature at which the liquid phase is constant at a particular pressure.

What does the word "eutectic" mean?

A melting composition known as a eutectic consists of at least two components that melt and freeze at the same rates. The components combine during the crystallisation phase, operating as a single component as a result.

What are eutectic pressure and temperature?

The eutectic is the system's lowest melting point under its own pressure; it has a matching temperature called the eutectic temperature and produces the eutectic liquid as a result. In terms of composition, eutectic liquids are located between the system's solid phases.

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For a gaseous reaction, standard conditions are 298 K and a partial pressure of 1 atm for all species.

For the reaction

N2(g)+3H2(g)↽−−⇀2NH3(g)

the standard change in Gibbs free energy is Δ°=−32.8 kJ/mol
. What is ΔG for this reaction at 298 K when the partial pressures are N2=0.350 atm
, H2=0.300 atm
, and NH3=0.750 atm
?

Answers

We can use the following equation to calculate the Gibbs free energy change at non-standard conditions:

ΔG = Δ°G + RT ln(Q)

where Δ°G is the standard Gibbs free energy change, R is the gas constant (8.314 J/mol-K), T is the temperature in Kelvin, and Q is the reaction quotient.

First, we need to calculate Q for the given partial pressures:

Q = (P(NH3))^2 / (P(N2) * P(H2)^3)
= (0.750 atm)^2 / (0.350 atm * 0.300 atm^3)
= 4.08

Next, we can substitute the values into the equation:

ΔG = -32.8 kJ/mol + (8.314 J/mol-K * 298 K) * ln(4.08)
= -32.8 kJ/mol + (2471 J/mol) * 1.407
= -32.8 kJ/mol + 3476 J/mol
= -29.3 kJ/mol

Therefore, the Gibbs free energy change for the reaction at 298 K and the given partial pressures is -29.3 kJ/mol.

CAN SOMEONE HELP WITH THIS QUESTION?

Answers

The percent transmittance (%T) and absorbance (A) of a solution are related by an equation which can be used to solve this question.

What is the absorbance of this solution?

The percent transmittance (%T) and absorbance (A) of a mixture are associated by the following equation:

%T = 100 x 10^(-A)

We are given that the %T value of the solution is 51.6% at a wavelength of 550 nm. To find the absorbance (A), we can rearrange the equation above:

A = -㏒(%T / 100)

On substituting the value in the given %T value, we get:

A = -㏒(51.6 / 100) = -㏒(0.516) = 0.286

Therefore, the absorbance of the solution at a wavelength of 550 nm is 0.286.

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A balloon holds 60.0 kg of helium. What is the volume of the balloon if the final pressure is 1.20 atm and the temperature is 22°C?

Answers

Answer:

Explanation:

Use the formula PV=nRT

P is pressure in atm

V is volume in whatever unit you're working in as long as everything is in that unit (anything volume related)

n is the number of moles

R is the constant so 0.08206

and T is temperature and this MUST be in Kelvin which is 173.15 + C

the equation can be shifted depending on what you need to solve

For the reaction: N₂(g) + 3H₂(g) + 2NH3(g) AH = -76.4 KJ/mol. Determine the heat energy when 5.0g of hydrogen burns.​

Answers

Answer:

-191 kJ

Explanation:

The given reaction is:

N₂(g) + 3H₂(g) → 2NH₃(g) ΔH = -76.4 kJ/mol

From the balanced equation, we can see that the stoichiometric ratio between hydrogen (H₂) and ammonia (NH₃) is 3:2. This means that 3 moles of hydrogen react to produce 2 moles of ammonia.

To determine the heat energy when 5.0 g of hydrogen (H₂) burns, we need to follow these steps:

Step 1: Calculate the moles of hydrogen (H₂)

Using the molar mass of hydrogen (H₂), which is 2 g/mol, we can calculate the moles of hydrogen (H₂) in 5.0 g of hydrogen:

Moles of H₂ = Mass of H₂ / Molar mass of H₂

Moles of H₂ = 5.0 g / 2 g/mol

Moles of H₂ = 2.5 mol

Step 2: Use the stoichiometry of the reaction

Based on the stoichiometry of the reaction, we know that 3 moles of hydrogen (H₂) react to produce 2 moles of ammonia (NH₃), and the enthalpy change (ΔH) is -76.4 kJ/mol.

Step 3: Calculate the heat energy

The heat energy for 2.5 moles of hydrogen (H₂) can be calculated using the given enthalpy change (ΔH) and the stoichiometry of the reaction:

Heat energy = Moles of H₂ x ΔH

Heat energy = 2.5 mol x -76.4 kJ/mol

Heat energy = -191 kJ (rounded to three significant figures)

So, the heat energy when 5.0 g of hydrogen (H₂) burns is -191 kJ (rounded to three significant figures), and the negative sign indicates that the reaction is exothermic, releasing heat.

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