This compound, (C10H12O3), shows strong, sharp absorption between 1700 and 1720 cm-1, and strong, broad absorption over the region 2500-3000 cm-1. Given this information and the following NMR data, please draw the structure of the compound in the box below.
1H-NMR: 2.49 ppm, t(2H); 2.80 ppm, t(2H); 3.72 ppm, s(3H); 6.78 ppm, d(2H); 7.11 ppm, d(2H); 12.4, s(1H) 13C-NMR: 173.89; 157.87; 132.62; 128.99; 113.55; 54.84; 35.75; 29.20
Answers
Answer:
Explanation:
The peak at 1700-17200 cm⁻¹ in the infrared spectrum shows the existence of a carbonyl group (C=O). The appearance of an OH peak is shown by the broad peak at 2500-3000 cm⁻¹. The peak at 12.4 ppm in 1H NMR identifies the existence of carboxylic acid. The peaks at 6.78 ppm and 7.11 ppm suggest that the prevalence existence of a benzene ring in the molecule. Because these peaks are doublets, the benzene is being para-substituted.
The existence of the CH2 group is shown by the peak at 2.49 ppm, which integrates 2 hydrogens. Provided that the breaks are doublets, It would be bound to another CH2 molecule as well as carbon that is devoid of hydrogen (benzene carbon).
The existence of the CH2 group, which is linked to the above-listed CH2 group, is also demonstrated by the next peak at 2.8 ppm. It must be bonded with carbonyl carbon so it breaks as a doublet. As a result, it has a greater chemical transition. The CH3 category is shown by the peak at 3.72 ppm. Its chemical change is strong, indicating that CH3 is linked to an oxygen atom that is linked to benzene.
NMR details at 13C. Carbonyl carbon of acid has a high (peak) at 173.89 ppm. Benzene carbon peaks range from 113.55 to 157.87 ppm. The peak at 64 is made up of CH3, while the other two are made up of CH2.
The structure of the diagram is shown below with its degree of unsaturation.
Related Questions
Identify the products formed in this Brønsted-Lowry reaction. HCO−3+HBrO↽−−⇀acid+base
Answers
Answer:
[tex]HCO^-_3+HBrO\rightleftharpoons H_2CO_3+BrO^-[/tex]
Explanation:
Hello there!
In this case, according to the Brønsted-Lowry theory of acids, it is possible to realize that HBrO acts as the Brønsted-Lowry acid as it has a free hydrogen to give away to HCO₃⁻ which acts as the Brønsted-Lowry base able to accept the incoming hydrogen; therefore, the Brønsted-Lowry reaction is:
[tex]HCO^-_3+HBrO\rightleftharpoons H_2CO_3+BrO^-[/tex]
Best regards!
In the Brønsted-Lowry reaction between HCO⁻₃ and HBrO, the formed acid is H₂CO₃ and the formed base is BrO⁻.
According to Brønsted-Lowry acid-base theory:
An acid is a substance that donates H⁺.A base is a substance that accepts H⁺.Let's consider the following Brønsted-Lowry reaction.
HCO⁻₃ + HBrO ⇄ acid + base
HBrO can only donate H⁺, so it is an acid.HCO⁻₃ can accept or donate H⁺. Here, it will accept the H⁺ donated by HBrO and behave as a base.The resulting reaction is:
HCO⁻₃ + HBrO ⇄ H₂CO₃ + BrO⁻
H₂CO₃ can donate H⁺ so it is an acid.BrO⁻ can accept H⁺ so it is a base.In the Brønsted-Lowry reaction between HCO⁻₃ and HBrO, the formed acid is H₂CO₃ and the formed base is BrO⁻.
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A hammer can be used to see how a mineral breaks. If you observe square chunks of the mineral when broken, what can you conclude?
a
The mineral is soft.
b
The mineral is hard.
c
The mineral has cleavage.
d
The mineral does not have cleavage.
Answers
Answer:
a
Explanation:
it can not break that easily
The mineral has given square chunks when breaked with a hammer. This indicates that the mineral has a cleavage. Thus, option c is correct.
What is mineral?Minerals are naturally formed inorganic substances which are having a definite chemical composition and highly ordered crystalline structures. Minerals are deposited in many organic and inorganic matters.
Minerals have some peculiarities such as hardness, cleavage, color etc. Cleavage of a mineral is its tendency to break along crystallographic planes thereby the structural locations of ions and atoms in the crystal creates planes of relative weakness.
Cleavage of crystal results in pieces of square, cubic or other geometrical shapes. in The mineral here, broken into square pieces indicating that the mineral have some weaker crystallographic planes in comparison to other and they cleave. Thus, c is correct.
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5. What is the pH of a solution with p0H= 8.5? Is this an acid, base, or neutral?
Answers
Answer:
pH = 5.5 and it is an acid
Explanation:
Fr the question given above, the following data were obtained:
poH = 8.5
pH =?
pH + pOH = 14
pH + 8.5 = 14
Collect like terms
pH = 14 – 8.5
pH = 5.5
pH scale reads as follow:
0 to 6 => Acidic
7 => Neutral
8 to 14 => Basic
With the above pH scale, we can conclude that the solution with pH 5.5 is acidic.
What is the molarity of a 5 L solution that contains 7.5 moles of NaOH?
A. O 1500 M
В.
1.5 M
C
0.017M
D. O 0.015 M
Answers
The molarity of the solution will be:
B. 1.5 M, this can be calculated on adding the values of V and n in molarity formula.
What is Molarity?It is defined as the ratio of number of moles of solute by the Volume of the solution in liters.
It is given by:
Molarity = n/ V
What information do we have?
Volume = 5L
Moles of NaOH = 7.5 moles
On substituting the values
M= n/V
M= 7.5 moles / 5L
M= 1.5 M
Thus, the molarity of the solution is 1.5 M.
Hence, option B is correct.
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In the solution containing both 0.10 M acetic acid and 0.10 M sodium acetate, the acetic acid undergoes ionization. The chemical equation for this ionization reaction is the same as for a solution containing acetic acid alone. The difference is that the initial concentration of acetate ion (before any ionization reaction occurs) for the solution containing acetic acid alone is zero, whereas the initial concentration of acetate ion is 0.10 M in your solution containing both acetic acid and sodium acetate. Calculate the percent ionization and the expected initial pH for the solution that contained both 0.10 M acetic acid and 0.10 M sodium acetate. (Hint: Again, you will need to use Ka for acetic acid.)
Answers
Answer:
percent ionization = 50.01%; pH = 4.75
Explanation:
To solve this question we must write the acetic acid equilibrium (Where HX will be acetic acid and X⁻ the sodium acetate):
HX(aq) ⇄ H⁺(aq) + X⁻(aq)
Where equilibrium constant, Ka, is defined as:
Ka = 1.76x10⁻⁵ = [H⁺] [X⁻] / [HX]
Where the concentration of each ion is:
[H⁺] = X
[X⁻] = 0.10M + X
[HX] = 0.10M - X
Replacing in Ka expression:
1.76x10⁻⁵ = [X] [0.10-X] / [0.10+X]
1.76x10⁻⁶ + 1.76x10⁻⁵X = 0.10X - X²
X² - 0.0999824 X + 1.76×10⁻⁶ = 0
X ≈ 0.1M → False solution. Decreases a lot the concentration of HX
X = 0.0000176M → Right solution.
The concentration of each ion is:
[H⁺] = 0.0000176062M
[X⁻] = 0.10M + 0.0000176M = 0.1000176M
[HX] = 0.10M - 0.0000176M = 0.0999824M
Percent ionization:
[X-] / [X-] + [HX] * 100 =
0.1000176M / 0.2M =
50.01%And pH = -log [H+]
pH = 4.75As you can see, [H+]≈ Ka
How many atoms would fit across a human hair? *
Answers
The amount of atoms one million carbon atoms or so make up an average human hair.
What are atoms?The smallest unit of matter that may be divided without ejecting electrically charged particles is called an atom. It is also the smallest material with properties resembling chemical elements. As a result, the atom serves as the fundamental unit of chemistry. In a chemical reaction, atoms cannot be formed or destroyed since they are indivisible units.
One inch has 25,400,000 nanometers. The width of a human hair ranges between 80,000 and 100,000 nanometers. The thickest human hair is a million times smaller than an atom. An atom's diameter spans from 0.1 to 0.5 nanometers. The volume of the cells is typically 0.009 cubic microns. More than 150,000 of these germs could fit on the tip of a human hair, and about 150 of them could fit within one Escherichia coli cell.
Thus, the amount of atoms one million carbon atoms or so make up an average human hair.
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What are characteristics of absorption spectra? Check all that apply.
Light is absorbed, which produces characteristic lines.
| Light is emitted, which produces characteristic lines.
Lines are dark on a visible light background.
Lines are brightly colored on a black background.
Lines are produced by electrons being excited.
Lines are produced from electrons returning to a lower energy level.
Answers
Answer:
Light is absorbed, which produces characteristic lines.
Lines are dark on a visible light background.
Lines are produced by electrons being excited.
Explanation:
Edg
The characteristics of absorption spectra light is absorbed, which produces characteristic lines, lines are dark on a visible light background and Lines are produced by electrons being excited.
What is absorption spectra?The term "absorption spectroscopy" applies to spectroscopic methods that assess how much radiation interacts with a sample and is absorbed as a proportion of frequency or wavelength. The sample takes in photons, meaning energy, from the emitting field.
What are electrons?The electron would be a subatomic particle with a negative one fundamental charge electric charge. Due to their lack of components or substructure, electrons, which have become part of the lepton particle family's first generation, could be typically regarded to be elementary particles.
The percentage of incoming electromagnetic energy that a material absorbs across a variety of frequencies is displayed in the material's absorption spectrum. In a way, an emission spectrum would be the converse of an absorption spectrum.
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What is the total number of electrons in the valence shell of an atom of aluminum in the ground
state?
1)8 2)2 3)3 4)10
Answers
Answer:
This is a total of ten electrons in filled shells
Explanation:
X^2/3-5X^1/3+6=0
find x
Answers
Answer:
[tex]x=27,8[/tex]
Explanation:
The equation is
[tex]x^{\dfrac{2}{3}}-5x^{\dfrac{1}{3}}+6=0[/tex]
Let,
[tex]x^{\dfrac{1}{3}}=y[/tex]
So,
[tex]y^2-5y+6=0\\\Rightarrow y=\dfrac{-\left(-5\right)\pm \sqrt{\left(-5\right)^2-4\times 1\times 6}}{2\times 1}\\\Rightarrow y=3,2[/tex]
[tex]x^{\dfrac{1}{3}}=y\\\Rightarrow y^3=x\\\Rightarrow x=3^3\\\Rightarrow x=27[/tex]
[tex]x=2^3\\\Rightarrow x=8[/tex]
Hence, [tex]x=27,8[/tex].
Please disregard this
Answers
well i need points
Explanation:
thanks
what part of of the universe is less than 1 km in diameter
Answers
Answer:
Meteoroids
Explanation:
Meteoroids are the elements of the universe that have the smallest diameter among all elements, reaching less than 1 km in diameter. They are any rocky or metallic body, which exists in space and does not reach more than 100 meters. It is common for meteoroids to fall to earth, but their impact is not as destructive as the impact of other space bodies, due to their tiny size.
There are about 26 deuterium atoms for every million hydrogen atoms across the universe, but it is six times as prevalent in the water on Earth and in other solar system bodies. Deuterium has one more ———— than hydrogen.
A. Ionic pair
B. Hydrogen bond
C. Proton
D. Electron
E. Neutron
Answers
Answer:
Option E
Deuterium has one more neutron than hydrogen
Explanation:
Deuterium is an isotope of Hydrogen and hence there will variation in the number of neutron
Hydrogen has 0 neutron
Deuterium has 1 neutron and
Tritium has 2 neutron
Thus option E is correct
In the universe, there are approximately 26 deuterium atoms for every million hydrogen atoms. Deuterium has one more neutron than hydrogen.
The correct option is E.
What is deuterium?Deuterium is a stable isotope of hydrogen, whose atomic weight is 2.014.
It is also called heavy hydrogen, and it contains one neutron and one proton.
In nuclear fusion reactors, deuterium is employed as a tracer, while in heavy water moderated fission reactors, it is utilized to slow down neutrons.
Thus, the correct option is E.
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A common ancestor is an organism that is the
O direct ancestor of two or more different organisms
O direct ancestor of one organism.
O indirect ancestor of two or more different organisms.
O indirect ancestor of one organism.
Answers
Hope that is right XD
A common ancestor is an organism that is the direct ancestor of two or more different organisms.
A common ancestor refers to an organism that is shared by multiple organisms, serving as the direct predecessor to those organisms. It is the point in evolutionary history where two or more distinct lineages diverged from a single ancestral lineage. This means that the common ancestor is the starting point from which different species or groups of organisms evolved over time.
In the context of evolution, organisms share common ancestry due to the process of descent with modification. Through genetic inheritance and gradual changes in traits over generations, new species arise from a common ancestor. As these species undergo divergent evolution, they develop distinct characteristics and adaptations, eventually becoming separate lineages.
Hence, the correct option is the direct ancestor of two or more different organisms.
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What is the pH of 0.42M aniline?
Answers
Answer:
Kb=x^2/0.42-x (eqn to calculate)
basicity (pkb) 9.3
Explanation:
Why is there not a constant molar volume for solids and
liquids?
a Solid and liquid particles are packed close together,
b The densities of solids and liquids are variable.
с
The volume of a solid or a liquid has very little
empty space.
d All of the above
Answers
Answer:
all of the above
Explanation:
i got the answer right on cK-12
Sally has constructed a concentration cell to measure Ksp for MCln. She constructs the cell by adding 2 mL of 0.05 M M(NO3)n to one compartment of the microwell plate. She then makes a solution of MCln by adding KCl to M(NO3)n. She adds 6.380 mL of the resulting mixture to a second compartment of the microwell plate.
Sally knows n (the charge on the metal ion) = +2
She has already calculated [Mn+] in the prepared MCln solution using the Nernst equation. [Mn+] = 8.279 M
Required:
How many moles of [Cl-] must be dissolved in that compartment?
Answers
Answer:
0.1056 mole
Explanation:
As Sally knows that the charge on the metal ion is n = +2
[tex]$MCl_n=MCl_2$[/tex]
In that compartment [tex]$[M^{n+}]=[m^{2+}]=8.279 \ M$[/tex]
The volume of the [tex]$MCl_n$[/tex] taken in that compartment = 6.380 mL
So, the number of moles of [tex]$M^{2+} = 8.279 \times 6.380$[/tex]
= 52.82 m mol
= 0.05280 mol
[tex]$MCl_n \rightarrow M^{n+}+nCl^-$[/tex]
But n = 2
Therefore, moles of [tex]$Cl^-$[/tex] = 2 x moles of [tex]$M^{n+}$[/tex]
= 2 x 0.05282
= 0.1056 mole
सच्याउंन आधानिक परियोडिक तालिका सफल भयो वा भएन, मूल्याङ्कन गनुहोस्
List out two demerits of Mendeleev's period table. Analyses modern penodic
table is able to overcome these dements or not.
दिदाको तालिका अध्ययन गरी सोधिएका प्रश्नहरुका उत्तर लेख्नुहोस्
Answers
Answer:llllIIII
Explanation:
A car accelerates away from the starting line at 3.6 m/s2 and has the mass of 2400 kg. What is the net force acting on the vehicle?
Answers
Answer:
F = m x a
F = 2400 kg x 3.6 m/s2
F = 8,640 N
Explanation:
(d) Other
sugar molecules become
_____ and are carried away from the crystal.
the force of attraction is
Answers
Answer:
liquid
Explanation:
defiantly
Which of the following is an base?
OK₂CO₃
ОНЕ
NaCl
NaOH
Answers
Answer:
NaOH
Explanation:
NaOH is called base because it dissociates completely in aqueous solution to form hydroxide ion(OH-) and sodium cation (Na+). When it react with an acid , it produce sodium salt and water. It is a strong base because it dissociates completely.
what is the formula for fluoride?
Answers
Answer:Chemical formula F −
Molar mass 18.998403163 g·mol−1
Conjugate acid Hydrogen fluoride
Explanation:
what is the speed of the electromagnetic waves please solve using correct units ill give brainliest.
Answers
Answer:
3 m
Explanation:
We'll begin by converting 99.9 MHz to Hz. This can be obtained as follow:
1 MHz = 10⁶ Hz
Therefore,
99.9 MHz = 99.9 MHz × 10⁶ Hz / 1 MHz
99.9 MHz = 99.9×10⁶ Hz
Finally, we shall determine the wavelength. This can be obtained as follow:
Frequency (f) = 99.9×10⁶ Hz
Velocity (v) = 3×10⁸ m/s
Wavelength (λ) =?
Velocity = wavelength × frequency
v = λf
3×10⁸ = λ × 99.9×10⁶
Divide both side by 99.9×10⁶
λ = 3×10⁸ / 99.9×10⁶
λ = 3 m
Thus, the wavelength of the electromagnetic wave is 3 m.
2. Seed color--- a. Yellow is dominant (Y) b. Green is recessive (y) c. A yy father and a yy mother d. What color(s) are the parents? e. What color(s) are the children?
Answers
Answer:
The parents are green and the children are green.
Explanation:
They all have the green recessive (y). So, the parents are green and the children are green.
If 75 g. of Potassium Chloride (ionic compound) is dissolved in 250 grams of
water, what will be the freezing point of the solution? Kf = 1.86
Answers
Answer:
[tex]T_{f,sol}=-15.0\°C[/tex]
Explanation:
Hello there!
In this case, for these problem about the colligative property of freezing point depression, it is possible set up the following equation:
[tex]T_{f,sol}-T_{f,water}=-i*m*Kf[/tex]
Whereas the van't Hoff's factor, i, is 2 since KCl is ionized in two ions (K+ and Cl-); and the molality (m) of the solution is computed by:
[tex]m=\frac{75g*\frac{1mol}{74.55g} }{250g*\frac{1kg}{1000g} } \\\\m=4.02mol/kg[/tex]
Thus, since the freezing point of water (ice) is 0°C, we obtain the following freezing point of the solution by plugging in:
[tex]T_{f,sol}=-(2)(4.02mol/kg)(1.86\°C/mol*kg)\\\\T_{f,sol}=-15.0\°C[/tex]
Best regards!
If 10.00 moles of copper are reacted with 6.00 moles of sulfur according to the following balanced equation, which reactant is the limiter and how many moles of excess reactant would remain after the reaction is completed? 2 Cu + S --> Cu2S
Cu is limiting and 1.00 mole of excess S remain
S is limiting and 1.00 moles of excess Cu remain
S is limiting and 4.00 moles of excess Cu remain
Cu is limiting and 4.00 moles of excess S remain
Answers
Answer: Cu is limiting and 1.00 mole of excess S remain
Explanation:
The chemical balanced reaction is:
[tex]2Cu+S\rightarrow Cu_2S[/tex]
According to stoichiometry :
2 moles of [tex]Cu[/tex] require 1 mole of [tex]S[/tex]
Thus 10.00 moles of [tex]Cu[/tex] will require=[tex]\frac{1}{2}\times 10.00=5.00moles[/tex] of [tex]S[/tex]
Thus [tex]Cu[/tex] is the limiting reagent as it limits the formation of product and [tex]S[/tex] is the excess reagent.
Moles of S left = (6.00-5.00) moles = 1.00 mole
Thus Cu is limiting and 1.00 mole of excess S remain.
How much energy is needed to evaporate 100g of water
Answers
Answer: you would have to remove 80 calories from 1 g of pure water at the freezing point, 0˚ C, to convert it to 1 g of ice at 0˚ C. Explanation:However, 540 calories of energy are required to convert that 1 g of water at 100˚ C to 1 g of water vapor at 100˚ C. This is called the latent heat of vaporization. On the other hand, you would have to remove 80 calories from 1 g of pure water at the freezing point, 0˚ C, to convert it to 1 g of ice at 0˚ C.
How many atoms of Bi are there in a 41.8 g sample?
Answers
Answer:
The number of particles in the 41.8g sample of Bismuth is 12.044 × 10²³
NH4OH+HCLO4
Total ionic
Answers
Answer:
[tex]OH^-(aq)+H^+(aq)\rightarrow H_2O(l)[/tex]
Explanation:
Hello there!
In this case, according to the given reactants, it is firstly necessary to set up the complete molecular reaction:
[tex]NH_4OH(aq)+HClO_4(aq)\rightarrow NH_4ClO_4(aq)+H_2O(l)[/tex]
Now, by knowing that ionic species are able to ionize, we are able to write the complete ionic equation:
[tex]NH_4^++OH^-+H^++ClO_4^-\rightarrow NH_4^++ClO_4^-+H_2O(l)[/tex]
Whereas ammonium and chlorate ions are spectator ions because they remain the same on both sides of the equation. Therefore the total or net ionic equation would be:
[tex]OH^-(aq)+H^+(aq)\rightarrow H_2O(l)[/tex]
Best regards!
A rectangular block has dimension 20m x10mx5m and mass of 400kg calculate the density of the rectangular block
Answers
Answer:
0.4 kg/m^3
Explanation:
v (volume) = 20m x 10m x 5m = 1000 m^3
w (weight) = 400 kg
d (density) = w / v
d = 400 / 1000 = 0.4 kg per cubic meter (kg/m^3)
I apologize if this is a little complex, however all of the math is there, if you're interested then look it over. Otherwise I've provided the answer in the units used for the dimensions and weight provided.
Graphite, an allotrope of carbon, is converted into cubic diamond through a process that may take a billion years or longer. As illustrated above, scientists can make synthetic diamonds using a certain process in about one week. However, these synthetic diamonds have carbon atoms in a hexagonal lattice. Diamonds with a carbon atoms in a cubic lattice are not produced even though they are thermodynamically more stable than hexagonal diamond. Which of the following best justifies why the synthetic process produces hexagonal diamond and not the more thermodynamically stable cubic diamond?
a. The amount of energy required to create new bonds between carbon atoms in cubic diamond is much greater than the amount of energy required to create hexagonal diamond.
b. The amount of energy required to create new bonds between carbon atoms in cubic diamond is much smaller than the amount of energy required to create hexagonal diamond.
c. The activation energy needed to form cubic diamond is much less than the activation energy needed to form hexagonal diamond.
d. The activation energy needed to form cubic diamond is much greater than the activation energy needed to form hexagonal diamond.
Answers
Answer:
The activation energy needed to form cubic diamond is much greater than the activation energy needed to form hexagonal diamond.
Explanation:
The activation energy refers to the minimum energy that reacting species must possess before they can undergo a particular chemical reaction.
This implies that if species do not possess the activation energy, they hardly undergo a given reaction. The activation energy is the barrier between reactants and products.
Hence, a reaction that has a very high activation energy occurs slowly or may not even occur. The activation energy needed to form cubic diamond is much greater than the activation energy needed to form hexagonal diamond hence the synthetic process produces hexagonal diamond and not the more thermodynamically stable cubic diamond.