Through what basic mechanism is 2-methylcyclohexanol converted to 1-bromo-1-methylcyclohexane when treated with HBr

Answers

Answer 1

Answer:

Sn1 mechanism reaction

Explanation:

In this case, we have to start with the protonation of the "OH" group by the attack of the lone pairs in the alcohol group to the "H" in the HBr producing a positive charge in the oxygen. Then, water is produced and a carbocation is generated. This carbocation can be stabilized by a hydride shift. We can move a hydrogen atom to the positive charge and we will obtain a tertiary carbocation. Finally, the [tex]Br^- [/tex] will attack to produce the final halide.

See figure 1.

I hope it helps!

Through What Basic Mechanism Is 2-methylcyclohexanol Converted To 1-bromo-1-methylcyclohexane When Treated

Related Questions

Write the equilibrium constant expression for the experiment you will be studying this week. 2. If the equilibrium values of Fe3+, SCN- and FeSCN2+ are 9.5 x 10-4 M, 3.6 x 10-4 M and 5.7 x 10-5 M respectively, what is the value of Kc? 3. Write the general form of the dilution equation. 4. A solution is prepared by adding 18 mL of 0.200 M Fe(NO3)3 and 2 mL of 0.0020 M KSCN. Calculate the initial concentrations of Fe3+ and SCNin the solution.

Answers

Answer:

Kc = 166.7

[Fe³⁺] =  0.18 M

[SCN⁻] = 2×10⁻⁴ M

Explanation:

In the reaction of Fe³⁺ and SCN⁻, it is formed a complex:

Fe³⁺  +  SCN⁻  ⇄  FeSCN²⁺             Kc

Let's make the expression for Kc →  [FeSCN²⁺] / [Fe³⁺] . [SCN⁻]

5.7×10⁻⁵ / 9.5×10⁻⁴. 3.6×10⁻⁴  = 166.7

We determine the mmoles, we add from each reactant:

18 ml . 0.2M = 3.6 mmoles of Fe³⁺

2 ml . 0.002M = 4×10⁻³ mmoles of SCN⁻

General form of the dilution equation is:

Concentrated [C] . Concentrated Volume = Diluted [C] . Diluted Volume

Total volume = 20mL

[Fe³⁺]: 3.6 mmoles /20mL = 0.18 M

[SCN⁻]: 4×10⁻³ mmoles /20mL = 2×10⁻⁴ M

The value should be 1.67 x 10^2

The initial concentration should be 0.18 M and 2.0 x 10^(-4) M

Calculation of the value and initial concentration:

The value is

= 5.7 x 10^(-5)/(9.5 x 10^(-4) x 3.6 x 10^(-4))

= 167

= 1.67 x 10^2

we know that

Initial moles  = volume x concentration

So,

= 18/1000 x 0.200

= 0.0036 mol

Now

Initial moles  = volume x concentration

= 2/1000 x 0.0020

= 4.0 x 10^(-6) mol

So,

Total volume should be

= 18 + 2

= 20 mL

= 0.02 L

Now

Initial concentration   

= moles /total volume

= 0.0036/0.02

= 0.18 M

Now

Initial concentration

= moles  /total volume

= 4.0 x 10^(-6)/0.02

= 2.0 x 10^(-4) M

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How many milliliters of 0.0850 M NaOH are required to titrate 25.0 mL of 0.0720 M hydrobromic acid, HBr, to the equivalence point?

Answers

Answer:

21.2 mL

Explanation:

Step 1: Write the balanced equation.

NaOH + HBr ⇒ NaBr + H₂O

Step 2: Calculate the reacting moles of HBr

25.0 mL of 0.0720 M hydrobromic acid react.

[tex]0.0250 L \times \frac{0.0720mol}{L} = 1.80 \times 10^{-3} mol[/tex]

Step 3: Calculate the reacting moles of NaOH

The molar ratio of NaOH to HBr is 1:1. The reacting moles of NaOH are 1/1 × 1.80 × 10⁻³ mol = 1.80 × 10⁻³ mol.

Step 4: Calculate the required volume of NaOH

[tex]1.80 \times 10^{-3} mol \times\frac{1,000mL}{0.0850mol} = 21.2 mL[/tex]

30. What is the Bronsted base of H2PO4- + OH- ⟶HPO42- + H2O?

Answers

Answer:

OH⁻ is the Bronsted-Lowry base.

Explanation:

A Bronsted-Lowry base is a substance that accepts protons. In the chemical equation, OH⁻ accepts a proton from H₂PO₄⁻ to become H₂O. H₂PO₄⁻ would be a Bronsted-Lowry acid because it donates a proton to OH⁻ and becomes HPO₄²⁻.

Hope that helps.

A sample of neon gas at a pressure of 0.609 atm and a temperature of 25.0 °C, occupies a volume of 19.9 liters. If the gas is compressed at constant temperature to a
volume of 12.7 liters, the pressure of the gas sample will be
atm.​

Answers

Answer:

The pressure of the gas sample will be  0.954 atm.​

Explanation:

Boyle's law states that the pressure of a gas in a closed container is inversely proportional to the volume of the container, when the temperature is constant. That is, if the pressure increases, the volume decreases; conversely if the pressure decreases, the volume increases.

Boyle's law is expressed mathematically as:

Pressure * Volume = constant

o P * V = k

To determine the change in pressure or volume during a transformation at constant temperature, the following is true:

P1 · V1 = P2 · V2

That is, the product between the initial pressure and the initial volume is equal to the product of the final pressure times the final volume.

In this case:

P1= 0.609 atmV1= 19.9 LP2=?V2= 12.7 L

Replacing:

0.609 atm* 19.9 L= P2* 12.7 L

Solving:

[tex]P2=\frac{0.609 atm* 19.9 L}{12.7 L}[/tex]

P2= 0.954 atm

The pressure of the gas sample will be  0.954 atm.​

Water (2190 g ) is heated until it just begins to boil. If the water absorbs 5.83×105 J of heat in the process, what was the initial temperature of the water?

Answers

Answer:

The initial temperature was  [tex]36.4^\circ \:C[/tex]

Explanation:

[tex]\Delta t=\frac{q}{m\cdot C_s}=\frac{5.83\times10^5}{2190\times 4.184}\\\\=63.6^\circ\:C[/tex]

The temperature difference [tex]=100-63.6=36.4^\circ\:C[/tex]

Best Regards!

After heating a sample of hydrated CuSO4, the mass of released H2O was found to be 2.0 g. How many moles of H2O were released if the molar mass of H2O is 18.016 g/mol

Answers

Answer:

0.1110 mol

Explanation:

Mass = 2g

Molar mass = 18.016 g/mol

moles = ?

These quantities are realted by the following equation;

Moles = Mass / Molar mass

Substituting the values of the quantities and solving for moles, we have;

Moles = 2 / 18.016 = 0.1110 mol

A reaction is performed in a lab whereby two solutions are mixed together. The products are a liquid and a solid precipitate. What procedures would facilitate measurement of actual yield of the solid

Answers

Answer:

filtration, drying, and weighing

Explanation:

The procedures that would facilitate the measurement of the actual yield of the solid would be filtration of the precipitate, drying of the precipitate, and weighing of the precipitate respectively.

The liquid/solid mixture resulting from the reaction can be separated by the process of filtration using a filter paper. The residue in the filter paper would be the solid while the filtrate would be the liquid portion of the reaction's product.

The residue can then be allowed to dry, and then weighed using a laboratory-grade weighing balance. The weight of the solid represents the actual yield of the solid.

A student obtained a clean flask. She weighed the flask and stopper on an analytical balance and found the total mass to be 34.232 g. She then filled the flask with water and found the new mass to be 60.167 g. The temperature of the water was measured to be

Answers

Answer:

25.99mL is the volume internal volume of the flask

Explanation:

To complete the question:

The temperature of the water was measured to be 21ºC. Use this data to find the internal volume of the stoppered flask

The flask was filled with water, that means the internal volume of the flask is equal to the volume that the water occupies.

To find the volume of the water you need to find the mass and by the use of density of water at 21ºC (0.997992g/mL), you can find the volume of the flask, thus:

Mass water = Mass filled flask - Mass of clean flask

Mass water = 60.167g - 34.232g

Mass water = 25.935g of water.

To convert this mass to volume:

25.935g × (1mL / 0.997992g) =

25.99mL is the volume internal volume of the flask

What was one idea Dalton taught about atoms?
A. Atoms contained negatively charged particles scattered inside.
B. Atoms of one type would not react with atoms of another type.
C. All atoms of one type were identical in mass and properties.
D. Atoms changed into new elements when they formed compounds.

Answers

Answer:

C

Explanation:

I had this question and C is the right answer

One idea that Dalton taught about atoms was that all atoms of one type were identical in mass and properties.

What is an atom?

An atom is defined as the smallest unit of matter which forms an element. Every form of matter whether solid,liquid , gas consists of atoms . Each atom has a nucleus which is composed of protons and neutrons and shells in which the electrons revolve.

The protons are positively charged and neutrons are neutral and hence the nucleus is positively charged. The electrons which revolve around the nucleus are negatively charged and hence the atom as a whole is neutral and stable due to presence of oppositely charged particles.

Atoms of the same element are similar as they have number of sub- atomic particles which on combination do not alter the chemical properties of the substances.

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Charcoal from the dwelling level of the Lascaux Cave in France gives an average count of 0.97 disintegrations of ^14 C per minute per gram of sample. Living wood gives 6.68 disintegrations per minute per gram. Estimate the date of occupation and hence the probable date of the wall painting in the Lascaux Cave. Hint: Disintegrations per minute per gram" has the same units as the time-derivative of concentration for a radioactive decay model. (You may use the fact that the half-life of ^14C is 5568 years.)

Answers

Answer:

Explanation:

count given by old sample = .97 disintegrations per minute per gram

count given by fresh sample = 6.68 disintegrations per minute per gram

Half life of radioactive carbon = 5568 years

rate of disintegration

dN / dt = λ N

In other words rate of disintegration is proportional to no of radioactive atoms present . As number reduces rate also reduces .

Let initial no of radioactive be N₀ and after time t , number reduces to N

N₀ / N = 6.68 / .97

Now

[tex]N=N_0e^{-\lambda t}[/tex]

[tex]\frac{N}{N_0} =e^{-\lambda t}[/tex]

[tex]\frac{6.68}{.97} = e^{\lambda t}[/tex]

λ is disintegration constant

λ = .693 / half life

= .693 / 5568

= .00012446 year⁻¹

Putting the values in the equation above

[tex]\frac{6.68}{.97} = e^{.00012446\times t}[/tex]

[tex]6.8866 = e^{.00012446\times t}[/tex]

1.929577 = .00012446 t

t = 15503.6 years .  

You are given a sample of metal and asked to determine its specific heat. You weigh the sample and find that its weight is 30.0 N. You carefully add 1.25×10^4 J of heat energy to the sample and find that its temperature rises 15.0 °C. What is the sample's specific heat?

Answers

Answer:

272.33 J/Kg°C

Explanation:

Data obtained from the question include the following:

Weight of metal = 30 N

Heat used (Q) = 1.25×10⁴ J

Change in temperature (ΔT) = 15.0 °C.

Specific heat capacity (C) =..?

Next, we shall determine the mass of the metal.

The mass of the metal can be obtained as follow:

Weight (W) = mass (m) x acceleration due to gravity (g)

W = mg

Weight of metal = 30 N

Acceleration due to gravity = 9.8 m/s²

Mass (m) =..?

W = mg

30 = m x 9.8

Divide both side by 9.8

m = 30/9.8

m = 3.06 Kg

Finally, we shall determine the specific heat capacity of the metal as show below:

Heat used (Q) = 1.25×10⁴ J

Change in temperature (ΔT) = 15.0 °C.

Mass (m) = 3.06 Kg

Specific heat capacity (C) =..?

Q = mCΔT

1.25×10⁴ = 3.06 x C x 15

Divide both side by 3.06 x 15

C = (1.25×10⁴) / (3.06 x 15)

C = 272.33 J/Kg°C

Therefore, the specific heat capacity of metal is 272.33 J/Kg°C.

5.00 mol of ammonia are introduced into a 5.00 L reactor vessel in which it partially dissociates at high temperatures. 2NH 3(g) 3H 2(g) + N 2(g) At equilibrium and a particular temperature, 1.00 mole of ammonia remains. Calculate K c for the reaction.

Answers

Explanation:

system at equilibrium, will the reaction shift towards reactants ~

--?'

2. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). The production of ammonia is an

exothermic reaction. Will heating the equilibrium system increase o~e amount of

ammonia produced? . .co:(

3. (2 Pts) Consider the reaction N2(g) + 3H2(g) =; 2NH3(g). Ifwe use a catalyst, which way will

the reaction shift? ':'\

.1.+- w~t s~,H (o')l r'eo.c. e~ ei~i"liht-,·u.fn\ P~~,

4. (3 Pts) ff 1ven th e o £ 11 owmg d t a a £ or th ere action: A(g) + 2B(s) =; AB2(g)

Temperature (K) Kc

300 1.5x104

600 55 k ' pr, cl l<..J~

e- ~ r fee, ct o. ~ 1<

900 3.4 X 10-3

Is the reaction endothermic or exothermic (explain your answer)?

t d- IS o.,;r-. \4\a..i~1f't~ °the te.Y'il(lf1,:J'u.r-a a•~S. j lrvdu..c,,.) +~H~to{' '\

exothe-rnh't.-- ,.. ..,. (/.., ,~.

5. (4 Pts) Consider the reaction, N2(g) + 3H2(g) =; 2NH3(g). Kc= 4.2 at 600 K.

What is the value of Kc for 4 NH3(g) =; 2N2(g) + 6H2(g)

N ... ~l + 3 H~(ri ~ ~Nli3~) kl,= ~:s;H,J3 # 4. J..

~ ;)N~~) ~ ~ H ~) ~\-_ == [A!;J:t D~~Jb

J. [,v 1+3] ~

I

4,:i.~ = 0,05

5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.

Initially, there are 5.00 mol of ammonia in a 5.00 L reactor vessel. The initial concentration of ammonia is:

[tex][NH_3]_i = \frac{5.00mol}{5.00L} = 1.00 M[/tex]

At equilibrium, there is 1.00 mole of ammonia in the 5.00 L vessel. The concentration of ammonia at equilibrium is:

[tex][NH_3]eq = \frac{1.00mol}{5.00L} = 0.200 M[/tex]

We can calculate the concentrations of all the species at equilibrium using an ICE chart.

       2 NH₃(g) ⇄ 3 H₂(g) + N₂(g)

I          1.00              0          0

C         -2x              +3x        +x

E       1.00-2x          3x          x

Since the concentration of ammonia at equilibrium is 0.200 M,

[tex]1.00-2x = 0.200\\\\x = 0.400 M[/tex]

The concentrations of all the species at equilibrium are:

[tex][NH_3] = 0.200 M\\[H_2] = 3x = 1.20 M\\[N_2] = x = 0.400 M[/tex]

The concentration equilibrium constant (Kc) is:

[tex]Kc = \frac{[H_2]^{2} [N_2]}{[NH_3]^{2} } = \frac{(1.20^{3})(0.400) }{0.200^{2} } = 17.3[/tex]

5.00 mol of ammonia are introduced into a 5.00 L reactor vessel and when the equilibrium is reached, 1.00 mole remains. The concentration equilibrium constant is 17.3.

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An acetic acid buffer solution is required to have a pH of 5.27. You have a solution that contains 0.010 mol of Acetic acid. What molarity of sodium acetate will you need to add to the solution

Answers

Answer:

Molarity of sodium acetate you will need to add is 0.0324M

Explanation:

Assuming volume of the buffer is 1L.

The pH of a buffer can be determined using Henderson-Hasselbalch equation:

pH = pKa + log [A⁻] / [HA]

Where pKa is pKa of the weak acid,  [A⁻] molar concentration of conjugate base and [HA] molar concentration of weak acid

Replacing for the acetic buffer (pKa = 4.76):

pH = 4.76 + log [Sodium Acetate] / [Acetic Acid]

As you have 0.010 moles of acetic acid in 1L:

[Acetic Acid] = 0.010mol / 1L = 0.010M

And you require a pH of 5.27:

5.27 = 4.76 + log [Sodium Acetate] / [0.010M]

0.51 = log [Sodium Acetate] / [0.010M]

10^0.51 = [Sodium Acetate] / [0.010M]

3.236 =  [Sodium Acetate] / [0.010M]

3.236 [0.010M] = [Sodium Acetate]

0.0324M = [Sodium Acetate]

Molarity of sodium acetate you will need to add is 0.0324M

The following initial rate data apply to the raction
F2(g) + 2Cl2O(g) ---> 2FClO2(g) +Cl2(g)
Expt. [F2] (M) [Cl2O] (M) Intitial rate (M/s)
1 0.05 0.010 5 x 10^-4
2 0.05 0.040 2.0 x 10^-3
3 0.10 0.010 1.0 x 10^-3
Which of the following is the rate law (rate equation) for this reaction?
A. rate= k[F2]^2 [Cl2O]^4
B. rate= k[F2]^2 [Cl2O]
C. rate= k[F2] [Cl2O]
D. rate= k[F2] [Cl2O]^2
E. rate= k[F2]^2 [Cl2O]^2

Answers

Answer:

C. rate = k[F₂] [Cl₂O]

Explanation:

Based on the reaction, rate law can be obtained from the initial concentration of reactants thus:

rate = k[F₂]ᵃ [Cl₂O]ᵇ

Where the exponents a and b can be finded doing a experiment changing initial concentrations and seeing how a variation contribute in rate law.

If you analize experiments 1 and 2, the only change is [Cl₂O] (From 0.010 to 0.040, four times more) that changes its concentration in four times. This change produce rate law change from 5x10⁻⁴ to 2.0x10⁻³, also four times. That means the exponent b of [Cl₂O] is 1.

rate = k[F₂]ᵃ [Cl₂O]ᵇ

rate = k[F₂]ᵃ [Cl₂O]¹

Now, comparing experiments 1 and 3, the [F₂] change from 0.05 to 0.10, (Twice), and initial rate change from 5x10⁻⁴ to 1x10⁻³ (Also, twice). That means a = 1 and rate law is:

rate = k[F₂]¹ [Cl₂O]

rate = k[F₂] [Cl₂O]

Thus, right answer is:

C. rate = k[F₂] [Cl₂O]

A chemistry student weighs out of chloroacetic acid into a volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with solution. Calculate the volume of solution the student will need to add to reach the equivalence point. Round your answer to significant digits.

Answers

Answer:

11.6mL of the 0.1400M NaOH solution

Explanation:

0.154g of chloroacetic acid diluted to 250mL. Titrated wit 0.1400M NaOH solution.

The reaction of chloroacetic acid, ClCH₂COOH (Molar mass: 94.5g/mol) with NaOH is:

ClCH₂COOH + NaOH → ClCH₂COO⁻ + Na⁺ + H₂O

Where 1 mole of the acid reacts per mole of the base.

That means the student will reach equivalence point when moles of chloroacetic acid = moles NaOH.

You will titrate the 0.154g of ClCH₂COOH. In moles (Using molar mass) are:

0.154g ₓ (1mol / 94.5g) = 1.63x10⁻³ moles of ClCH₂COOH

To reach equivalence point, the student must add 1.63x10⁻³ moles of NaOH. These moles comes from:

1.63x10⁻³ moles of NaOH ₓ (1L / 0.1400moles NaOH) = 0.0116L of the 0.1400M NaOH =

11.6mL of the 0.1400M NaOH solution

A chemist adds of a M barium chlorate solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.

Answers

The given question is incomplete, the complete question is:

A chemist adds 200.0 ml of a 0.52M barium chlorate (Ba(CIO3)2) solution to a reaction flask. Calculate the mass in grams of barium chlorate the chemist has added to the flask. Round your answer to significant digits.

Answer:

The correct answer is 32 grams.

Explanation:

Based on the given solution, the molarity of barium chlorate solution given is 0.52 M, this shows that the solution will comprise 0.52 moles in 1 L or 1000 ml of the solution.  

Therefore, in 200 ml, it will comprise 0.52/1000 × 200 moles of Ba(ClO₃)₂,  

= 0.52/1000 × 200 = 0.104 moles

The molecular mass of Ba(ClO₃)₂ is 304.23 gram per mole

So, the mass of Ba(ClO₃)₂ in 0.104 moles will be,  

= 304.23 g/mol × 0.104

= 31.639 grams or 32 grams.  

2) 2.5 mol of an ideal gas at 20 oC under 20 atm pressure, was expanded up to 5 atm pressure via; (a) adiabatic reversible and (b) adiabatic irreversible process. Calculate the values of w, q, ΔU, ΔH for each process. (Cv = 5 cal / mol.K ≈ 5/2 R; R ≈ 2 cal / mol.K) (Please find the desired values by making the corresponding derivations

Answers

Answer:

a) for adiabatic reversible, ΔU(internal energy is constant) = 0, ΔH = 0(no heat is entering or leaving the surrounding)

workdone (w) = -8442.6 J  ≈ -8.443 KJ

heat transferred (q) of the ideal gas = - w

q = 8.443 KJ

b) For ideal gas at adiabatic reversible, Internal energy (ΔU) = 0 and enthalpy (ΔH) = 0

the workdone(w) in the ideal gas= - 4567.5 J  ≈ - 4.57 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

Explanation:

given

mole of an ideal gas(n) = 2.5 mol

Temperature (T) = 20°C

= (20°C + 273) K  = 293 K

Initial pressure of the ideal gas(P₁) = 20 atm

Final pressure of the ideal gas(P₂) = 5 atm.

2) (a)for adiabatic reversible process,

note: adiabatic process is a process by which no heat or mass is transferred between the system and its surrounding.

Work done (w) = nRT ln[tex]\frac{P_{1} }{P_{2} }[/tex]

= 2.5 mol × 8.314 J/mol K × 293 K × ln[tex]\frac{5atm}{20atm}[/tex]

= 6090.01 J × [-1.3863]

= -8442.6 J  ≈ -8.443 KJ

So, the work done (w) of ideal gas = -8.443 KJ

For ideal gas at adiabatic reversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-8.443 KJ)

q = 8.443 KJ

heat transfer (q) of the ideal gas = 8.443 KJ

(b) For adiabatic irreversible, the temperature T remains constant because the internal energy U depends only on temperature T. Since at constant temperature, the entropy is proportional to the volume, therefore, entropy will increase.

Work done (w) = -nRT(1 - ln[tex]\frac{P_{1} }{P_{2} }[/tex] )

= - 2.5 mol × 8.314 J / mol K× 293 K × [1- (5 atm /20 atm)]

= - 6090.01 J × 0.75

= - 4567.5 J  ≈ - 4.57 KJ

∴work done(w) of an ideal gas = - 4.57 KJ

For ideal gas at adiabatic Irreversible, Internal energy (U) = 0 and Enthalpy (H) = 0

From first law of thermodynamics:-

U = q + w

0 = q + w

q = - w

q = - (-4.5675 KJ)

q = 4.5675 KJ

the heat transfer (q) of an ideal gas = 4.5675 KJ

Identify a process that is NOT reversible. A. melting of steel B. freezing water C. melting of ice D. frying an egg E. deposition of carbon dioxide (gas to solid)

Answers

I’m pretty sure it would be D. Frying an egg

A process that is not a reversible reaction is frying an egg.

What are reversible reactions?

Reversible reactions are those reactions in which product will again change into the reactant.

Melting of steel and ice are reversible reaction as after cooling again we get the original state of steel and ice.Freezing of water is also reversible reaction as at normal temperature we get the original state of water.Deposition of carbon dioxide is also a reversible reaction.Frying an egg is a non reversible reaction as after frying an egg we didn't get the original egg again.

Hence option (D) is correct.

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1. In the simple cubic unit cell, the centers of ____________ identical particles define the ____________ of a cube. The particles do touch along the cube's ____________ but do not touch along the cube's ____________ or through the center. There is/are ____________ particle per unit cell and the coordination number is ____________ .
2. In the body-centered cubic unit cell, the centers of ____________ identical particles define the ____________ of the cube plus ____________ particle at the ____________ of ____________ . The particles do not touch along the cube's ____________ or faces but do touch along the cube's ____________ . There is/are ____________ particles per unit cell and the coordination number is ____________ .
3. In the face-centered cubic cell, the centers of ____________ identical particles define the ____________ of the cube plus ____________ particle in the ____________ of ____________ . The particles on the ____________ do not touch each other but do touch those on the ____________ . There is/are ____________ particles per unit cell and the coordination number is ____________ .

Answers

Answer:please see below for answers in the spaces given.

Explanation:

There are three types of cubic-unit cells of a cubic system which include Simple cubic unit cell, body-centered cubic unit cell and face-centered cubic-unit cell and Thier characteristics are completed below.

1) In the simple cubic unit cell, the centers of _______eight _____ identical particles define the _________corners___ of a cube. The particles do touch along the cube's _______edges_____ but do not touch along the cube's ____diagonal_______ or through the center. There is/are _______one_____ particle per unit cell and the coordination number is

__six______ .

2. In the body-centered cubic unit cell, the centers of _______eight _____ identical particles define the _______corners_____ of the cube plus ______one______ particle at the _______center_____ of ______the cube______ . The particles do not touch along the cube's _______edges_____ or faces but do touch along the cube's ____diagonal________ . There is/are _____two_______ particles per unit cell and the coordination number is _____eight_______ .

3. In the face-centered cubic cell, the centers of ______eight______ identical particles define the _______corner____ of the cube plus ________one____ particle in the _____center_______ of ______each face______ . The particles on the _____corners_______ do not touch each other but do touch those on the ______faces____ . There is/are ________four___ particles per unit cell and the coordination number is _____twelve_______ .

Calculate the [H+] and pH of a 0.0040 M hydrazoic acid solution. Keep in mind that the Ka of hydrazoic acid is 2.20×10−5. Use the method of successive approximations in your calculations or the quadratic formula.

Answers

Answer:

[tex][H^+]=0.000285[/tex]

[tex]pH=3.55[/tex]

Explanation:

In this, we can with the ionization equation for the hydrazoic acid ([tex]HN_3[/tex]). So:

[tex]HN_3~<->~H^+~+~N_3^-[/tex]

Now, due to the Ka constant value, we have to use the whole equilibrium because this is not a strong acid. So, we have to write the Ka expression:

[tex]Ka=\frac{[H^+][N_3^-]}{[HN_3]}[/tex]

For each mol of [tex]H^+[/tex] produced we will have 1 mol of [tex]N_3^-[/tex]. So, we can use "X" for the unknown values and replace in the Ka equation:

[tex]Ka=\frac{X*X}{[HN_3]}[/tex]

Additionally, we have to keep in mind that [tex]HN_3[/tex] is a reagent, this means that we will be consumed. We dont know how much acid would be consumed but we can express a subtraction from the initial value, so:

[tex]Ka=\frac{X*X}{0.004-X}[/tex]

Finally, we can put the ka value and solve for "X":

[tex]2.2X10^-^5=\frac{X*X}{0.004-X}[/tex]

[tex]2.2X10^-^5=\frac{X^2}{0.004-X}[/tex]

[tex]X= 0.000285[/tex]

So, we have a concentration of 0.000285 for [tex]H^+[/tex]. With this in mind, we can calculate the pH value:

[tex]pH=-Log[H^+]=-Log[0.000285]=3.55[/tex]

I hope it helps!

The [H+] and pH of a 0.0040 M hydrazoic acid solution is 0.000296648 and  3.527759

pH based problem:

What information do we have?

Hydrazoic acid solution = 0.0040 M

Ka of hydrazoic acid = 2.20 × 10⁻⁵

We know that weak acids

[H+] = √( Ka × C)

[H+] = √( 2.2 × 10⁻⁵ × 0.0040)

[H+] = 0.000296648

So,

pH = -log [H+]

pH = -log [0.000296648]

Using log calculator

pH = 3.527759

Find more information about 'pH'.

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Give the formulas for all of the elements that exist as diatomic molecules under normal conditions. See if you can do this without looking anything up.

Answers

Answer:

They are:

H2, N2, O2, F2, Cl2, Br2, and I2.

Note: whether the element At molecule is monoatomic or diatomic is incredibly arguable. While some say it exists as diatomic because it is a halogen like bromine, iodine etc, At is in fact extremely unstable and no one has ever really studied the molecules on it, so, when others say it is monoatomic, this is also based on calculations. But the other 7 elements listen above is for sure diatomic.

Hydrogen (H2) , Nitrogen (N2) , Oxygen (O2) , Fluorine (F2) , Chlorine (Cl2) , Iodine (I2) , carbonmonoxide (CO) and Bromine (Br2).

Hydrogen (H2) , Nitrogen (N2) , Oxygen (O2) , Fluorine (F2) , Chlorine (Cl2) , Iodine (I2) , carbonmonoxide (CO) and Bromine (Br2) are the formulas of the elements that is present as diatomic molecules under normal environmental conditions. Diatomic molecules refers to those molecules that is composed of only two atoms of the same or different elements. There are large number of diatomic molecules which is made up of two similar elements or different elements.

Learn more: https://brainly.com/question/17081808

Hydrogen iodide decomposes according to the equation: 2HI(g) H 2(g) + I 2(g), K c = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of HI at equilibrium.

Answers

Answer:

[HI] = 0.264M

Explanation:

Based on the equilibrium:

2HI(g) ⇄ H₂(g) + I₂(g)

It is possible to define Kc of the reaction as the ratio between concentration of products and reactants using coefficients of each compound, thus:

Kc = 0.0156 = [H₂] [I₂] / [HI]²

As initial concentration of HI is 0.660mol / 2.00L = 0.330M, the equlibrium concentrations will be:

[HI] = 0.330M - 2X

[H₂] = X

[I₂] = X

Where X is reaction coefficient.

Replacing in Kc:

0.0156 = [X] [X] / [0.330M - 2X]²

0.0156 = X² / [0.1089 - 1.32X + 4X² ]

0.00169884 - 0.020592 X + 0.0624 X² = X²

0.00169884 - 0.020592 X - 0.9376 X² = 0

Solving for X:

X = - 0.055 → False solution, there is no negative concentrations

X = 0.0330 → Right solution.

Replacing in HI formula:

[HI] = 0.330M - 2×0.033M

[HI] = 0.264M

Calculate the volume in liters of a M mercury(II) iodide solution that contains of mercury(II) iodide . Round your answer to significant digits.

Answers

Answer:

41L

Explanation:

Of a 4.8x10⁻⁵M mercury (II) iodide that contains 900mg of mercury (II) iodide. 2 significant digits

Molarity, M, is an unit of concentration in chemistry defined as the ratio between moles of solute (Mercury (II) iodide in this case) per Liter of solution.

A 4.8x10⁻⁵M solution contains 4.8x10⁻⁵ moles of solute per liter.

Now, 900mg = 0.900g of mercury (II) iodide (Molar mass: 454.4g/mol) are:

0.900g × (1mol / 454.4g) = 1.98x10⁻³moles of HgI₂

If in 1L there are 4.8x10⁻⁵ moles of HgI₂, There are 1.98x10⁻³moles of HgI₂ in:

1.98x10⁻³moles of HgI₂ ₓ (1L / 4.8x10⁻⁵moles) =

41L

Zinc bromide is considered which of the following?

A) molecular compound

B) atomic element

C) molecular element

D) ionic compound

Answers

Answer:

D

Explanation:

soluble in water and acidic

Which of the following statements about metal elements is correct?
A. Metals tend to easily gain more valence electrons.
B. Metal elements are always heavier than non-metal elements.
C. Metals tend to easily lose their valence electrons.
D. A metal atom can take an electron from a non-metal atom.​

Answers

Answer: C. Metals tend to easily lose their valence electrons.

Explanation:

Metals are those substances which have tendency to loose their valence electrons to attain noble gas configuration and forms positive ions called as cations.

Example: Gold, potassium etc

[tex]M\rightarrow M^++e^-[/tex]

Non metals are those substances which have tendency to gain valence electrons to attain noble gas configuration and form negative ions called as anions.

Example: Sulphur, Chlorine

[tex]N+e^-\rightarrow N^-[/tex]

A student is given an antacid tablet that weighs 5.8400 g. The tablet is crushed and 4.2800 g of the antacid is added to 200. mL of simulated stomach acid. It is allowed to react and then filtered. It is found that 25.00 mL of this partially neutralized stomach acid required 11.6 mL of a NaOH solution to titrate it to a methyl red end point. It takes 29.0 mL of this NaOH solution to neutralize 25.00 mL of the original stomach acid. How much of the original 200. mL of stomach acid (in mL) is neutralized by the 4.2800 g crushed sample of the tablet

Answers

Answer:

Explanation:

Given that:

mass of the antacid tablet = 5.8400 g

required mass of the antacid tablet = 4.2800 g was added to 200. mL of simulated stomach acid.

The amount of the  original 200. mL of stomach acid (in mL) needed to  neutralize the 4.2800 g crushed sample of the tablet can be calculated as:

= 11.6 mL of NaOH × 25.00 mL /29.0 mL NaOH

= 10.00 mL original stomach acid

Now; since it requires 11.6  mL of  NaOH o neutralize 10.00 mL of  original acid , then:

the antacid neutralized = 200 mL - 10.00 mL

the antacid neutralized = 190.00 mL

Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C 6H 5CO 2H) and 0.15M sodium benzoate (C 6H 5COONa). [K a = 6.5 × 10 –5 for benzoic acid]

Answers

Answer:

3.97

Explanation:

pH of buffer solution = pKa+Log(Cb/Ca)

pH of buffer solution = -log(Ka)+log(Cb/Ca)............... Equation 1

Where Ca = concentration of acid, Cb = concentration of base.

Given: Ka = 6.5×10⁻⁵, Ca = 0.25 M, Cb = 0.15 M

Substitute into equation 1

pH of buffer solution = -log(6.5×10⁻⁵)+log(0.15/0.25)

pH of buffer solution = 4.19+(0.22)

pH of buffer solution = 3.97.

Which element would have the most valence electrons and also be able to react with hydrogen?

Answers

Answer:

Fluorine, Chlorine, Bromine, or Iodine

Explanation:

These all have an ALMOST full valence shell. And they need one more electron so they'd react with hydrogen

Answer:

its chlorine

Explanation:

just trust me do i look like i would lie too you ;-)

btw i just took the test :-)

A study of the system, 4NH3(g) + 7O2(g) <--> 2N2O4(g) + 6H2O(g), was carried out. A system was prepared with [NH3] = [O2] = 3.60 M as the only components initially. At equilibrium, [N2O4] is 0.600 M. Calculate the equilibrium concentration of NH3(g).

Answers

Answer:

The equilbrium concentration of NH₃(g) is 2.4 M

Explanation:

The balanced reaction is:

4 NH₃(g) + 7 O₂(g) ⇔ 2 N₂O₄(g) + 6 H₂O(g)

By stoichiometry of the reaction,  2 moles of N₂O₄ are formed from 4 moles of NH₃.

Considering that the concentration is [tex]concentration=\frac{number of moles}{volume}[/tex] and with a volume of 1 liter, it is possible to apply the following rule of three: if 2 M of N₂O₄ are formed from 4 M of NH₃, 0.6 M of N₂O₄ from what concentration  of NH₃ are formed?

[tex]concentration of NH_{3}=\frac{0.6 M of N_{2}O_{3} *4MofNH_{3} }{2 M of N_{2}O_{3} }[/tex]

concentration of NH₃= 1.2 M

By subtracting the moles of NH3 in equilibrium from the moles of NH₃ initially, you will see how many moles of NH₃ were converted and remain in equilibrium: 3.6 M - 1.2 M= 2.4 M

The equilbrium concentration of NH₃(g) is 2.4 M

Why was it important to establish the Clean Air Act?

Answers

Answer: The Clean Air Act was important because it emphasized cost-effective methods to protect the air; encouraged people to study the effects of dirty air on human health; and created a regulation that makes any activities that pollute the air illegal.

Explanation:

Answer:

Clean Air Act (CAA), U.S. federal law, passed in 1970 and later amended, to prevent air pollution and thereby protect the ozone layer and promote public health. The Clean Air Act (CAA) gave the federal Environmental Protection Agency (EPA) the power it needed to take effective action to fight environmental pollution.

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