Answer:Conduction materials include metals, electrolytes, superconductors, semiconductors, plasmas and some nonmetallic conductors such as graphite and Conductive polymers. Copper has a high conductivity.
Explanation:
Which molecule or ion has a trigonal planar shape?
Answer:B
Explanation: A P E X
Question 7 options: The cell potential of an electrochemical cell made of an Fe, Fe2 half-cell and a Pb, Pb2 half-cell is _____ V. Enter your answer to the hundredths place and do not leave off the leading zero, if needed.
Answer: Thus the cell potential of an electrochemical cell is +0.28 V
Explanation:
The calculation of cell potential is done by :
[tex]E^0=E^0_{cathode}- E^0_{anode}[/tex]
Where both [tex]E^0[/tex] are standard reduction potentials.
[tex]E^0_{[Fe^{2+}/Fe]}= -0.41V[/tex]
[tex]E^0_{[Pb^{2+}/Pb]}=-0.13V[/tex]
As Reduction takes place easily if the standard reduction potential is higher(positive) and oxidation takes place easily if the standard reduction potential is less(more negative). Thus iron acts as anode and lead acts as cathode.
[tex]E^0=E^0_{[Pb^{2+}/Pb]}- E^0_{[Fe^{2+}/Fe]}[/tex]
[tex]E^0=-0.13- (-0.41V)=0.28V[/tex]
Thus the cell potential of an electrochemical cell is +0.28 V
Identify the Lewis acid and Lewis base from among the reactants in each of the following equations. Match the words in the left column to the appropriate blanks in the sentences on the right.
1. Fe3+ (aq)+6CN (aq) Fe(CN) (aq)______is the Lewis acid and_____is the Lewis base. is the Lewis
2. CI- (aq) + AlCl3 (aq) AlCl4-____is the Lewis acid and______is the Lewis base.
3. AlBr3 + NH3 H3NAlBr3______is the Lewis acid and______is the Lewis base.
A. AlCl3
B. CN-
C. AlBr3
D. Cl-
E. NH3
F. Fe3+
Answer:
1. Lewis acid: F. Fe₃⁺, Lewis base: B. CN⁻
2. Lewis acid: A. AlCl₃, Lewis base: D. Cl⁻
3. Lewis acid: C. AlBr₃, Lewis base: E. NH₃
Hope this helps.
The Lewis acid is chemical substance which possesses an empty orbital and accepts an electron pair from a Lewis base ( donor ), in order to create a Lewis adduct ( molecule created from the bonding of Lewis base and acid ).
The Lewis acid from reaction 1 is Fe₃⁺ while the Lewis base is CN⁻ also the Lewis acid from reaction 2 is AICI₃ while the Lewis base is CI⁻
Hence we can conclude that the Lewis acids and Lewis bases of the reactions in the question are as listed above.
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If the average rate of the reaction A --->2B C is 1M/s, what is the average rate of formation (in M/s) of B over that same period of time
Answer:
[tex]r_B=2M/s[/tex]
Explanation:
Hello,
In this case, since the average rate of reaction is related with the consumption of A which has an stoichiometric coefficient of 1, the rate of formation of B will be:
[tex]r_B=2*1M/s\\\\r_B=2M/s[/tex]
By cause of the stoichiometric coefficient of B which doubles the average rate.
Best regards.
Where possible, classify these systems as reactant-favored or product-favored at 298 K. If the direction cannot be determined from the information given, classify the reaction as "Insufficient information."
A. Reactant-favored
B. Product-favored
C. Insufficient information
1. A(s) + B(g) 2C(g) delta H degree = -109 kJ
2. A(s) + 2B(g) C(g) delta H degree=+271 kJ
3. 2A(g) + B(g) 4C(g) delta H degree=+322 kJ
4. A(g) + 2B(g) 2C(g) delta H degree=-89 kJ
Answer:
There is insufficient information to know direction of these systems
Explanation:
Delta H of a reaction is defined as the amount of energy involved when it occurs. The ΔH < 0 represents the reaction will release energy and ΔH > 0 the reaction will absorb energy.
As you can see, ΔH doesn't give information about the direction of a reaction (Spontaneity). In fact, to know spontaneity of a reaction you must know ΔG involved in this reaction.
As the reactions have ΔH but not ΔG,
There is insufficient information to know direction of these systemsThe decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism:
Answer:
The two-step mechanism is a slow mechanism and a fast mechanism. When we combine them, the result is
2H₂O₂ (aq) ⇒2H₂O (l) + O₂ (g)
Explanation:
We know that the decomposition of hydrogen peroxide is catalyzed by iodide ion, which means that the iodide ion will react with the hydrogen peroxide. There is a slow mechanism and a fast one:
H₂O₂(aq) + I₋(aq) ⇒ H₂O(l) + IO₋(aq) this is the slow reaction
IO₋(aq) + H₂O₂(aq)⇒ H₂O(l) + O₂(g) + I₋ (aq) this is the fast reaction
If we cancel the same type of molecules and ions, the final result is:
2H₂O₂ (aq) ⇒2H₂O (l) + O₂ (g)
The two-step mechanism represents the slow mechanism and a fast mechanism. At the time of combining them, the result is 2H₂O₂ (aq) ⇒2H₂O (l) + O₂ (g)
Two-step mechanism:
The decomposition of hydrogen peroxide should be catalyzed by iodide ion, which represents the iodide ion will react with the hydrogen peroxide. There is a slow mechanism and a fast one
Now
H₂O₂(aq) + I₋(aq) ⇒ H₂O(l) + IO₋(aq) this is the slow reaction
IO₋(aq) + H₂O₂(aq)⇒ H₂O(l) + O₂(g) + I₋ (aq) this is the fast reaction
Now in case of cancelling, the same type of molecules and ions, the final result is 2H₂O₂ (aq) ⇒2H₂O (l) + O₂ (g)
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2HCl(aq) + Ba(OH)2(aq) → BaCl2(aq) + 2H2O(l) ΔH = –118 kJ Calculate the heat when 250.0 mL of 0.500 M HCl is mixed 500.0 mL of 0.500 M Ba(OH)2. Assuming that the temperature of both solutions was initially 25.0 oC and that the final mixture has mass of 750.0 g and a specific heat capacity of 4.18 J oC–1g–1, calculate the final temperature (in oC) of the mixture.
Answer:
Heat = 7375J
Final temperature of the mixture = 27.35°C
Explanation:
In the reaction:
2HCl(aq) + Ba(OH)₂(aq) → BaCl₂(aq) + 2H₂O(l) ΔH = –118 kJ
When 2 moles of HCl reacts with excess of Ba(OH)₂ there are released 118kJ.
In the reaction, moles of HCl and Ba(OH)₂ that reacts are:
Moles HCl = 0.250L ₓ (0.500 moles / L) = 0.125 moles HCl
Moles Ba(OH)₂ = 0.500L ₓ (0.500 moles / L) = 0.250 moles Ba(OH)₂
For a complete reaction of 0.125 moles of HCl you need:
0.125 mol HCl ₓ (1 mole Ba(OH)₂ / 2 moles HCl) = 0.0625 moles Ba(OH)₂
As you have 0.250 moles of Ba(OH)₂, this reactant is in excess
2 moles of HCl that react release 118kJ, 0.125 moles of HCl release:
0.125 moles HCl ₓ (118kJ / 2 moles) = 7.375kJ =
7375JThe heat released can be obtained with the formula:
Q = C×m×ΔT
Where Q is heat, C specific heat of the solution, m its mass and ΔT change in temperature.
Replacing:
Q = C×m×ΔT
7375J = 4.18J/g°C×750.0g×ΔT
2.35°C = ΔT
As ΔT = Final T - Initial T:
2.35°C = Final T - 25.0°C
27.35°C = Final temperature of the mixture
Choose the compound that exhibits hydrogen bonding as its strongest intermolecular force.
A. C2H6
B. CH3OH
C. CH2Br2
D. SBr2
E. None of the above compounds exhibit hydrogen bonding.
Answer:
B
Explanation:
To form hydrogen bondings between the molecules, the compound needs a highly electronegative atom (usually N, O, or F) bonded with a hydrogen atom;
and that the highly electronegative atom has lone pair outermost shell electrons.
In the 5 options, only B (CH3OH) has an N, O, or F atom that has lone pair outermost shell electrons (2 lone pairs on each O atom), so it can form hydrogen bonds within its molecules.
Hydrogen bonds are stronger than the van der Waals' forces between its molecules (that exist regardless of whether there are hydrogen bonds).
The compound that exhibits hydrogen bonding as its strongest intermolecular force is CH₃OH as electronegative oxygen atom is bonded to hydrogen atom.
What is compound?Compound is defined as a chemical substance made up of identical molecules containing atoms from more than one type of chemical element.
Molecule consisting atoms of only one element is not called compound.It is transformed into new substances during chemical reactions. There are four major types of compounds depending on chemical bonding present in them.They are:
1)Molecular compounds where in atoms are joined by covalent bonds.
2) ionic compounds where atoms are joined by ionic bond.
3)Inter-metallic compounds where atoms are held by metallic bonds
4) co-ordination complexes where atoms are held by co-ordinate bonds.
They have a unique chemical structure held together by chemical bonds Compounds have different properties as those of elements because when a compound is formed the properties of the substance are totally altered.
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Which Carbon is the triple bound attached to in 6-ethyl-2-octyne?
-first
-fourth
-third
-second
Answer:
-second
Explanation:
6-ethyl-2-octyne is an unsaturated compound with a triple bond.
6-ethyl-2-octyne will have a triple bound attached to the second carbon. The suffix -yne suggests that compound carry a triple bond and the number "2" before suffix refers to the position of triple bond that is second carbon.
Hence, the correct option is "-second ".
3. There are many different primary standards that could be used in a standardization titration. What are the criteria for a primary standard
Answer:
High purity.
Stability (low reactivity)
Low hygroscopicity (to minimize weight changes due to humidity)
Explanation:
There are different primary standards that could be used in a standardization titration in order to achieve the best and accurate result possible. These standards include high purity,stability and low hygoscropicity .
A high purity means the reactants lack impurities which could affect the result. Stability also ensures that there is non reactivity with elements/compounds in the atmosphere while low hygroscopicity ensures weight changes are minimized due to humidity.
Calculate the frequency (Hz) and wavelength (nm)
of the emitted photon when an electron drops from
the n = 4 to the n=2 level in a hydrogen atom
Answer:
wavelength, λ = 486.6 nm
frequency, f = 6.16 * 10¹⁴ Hz
Explanation:
a. Wavelength
Using the wavelength equation; 1/λ = (1/hc) * 2.18 * 10⁻¹⁸ J * (1/nf² - 1/ni²)
Where nf is the final energy level; ni is the initial energy level; h is Planck's constant = 6.63 * 10⁻³⁴ J.s; c is velocity of light = 3 * 10⁸ m/s
1/λ = 1/(6.63 * 10⁻³⁴ J.s * 3 * 10⁸ m/s) * 2.18 * 10⁻¹⁸ J * (1/2² - 1/4²)
1/λ = 2.055 * 10⁶ m
λ = 4.866 * 10⁻⁷ m
wavelength, λ = 486.6 nm
b. Frequency
Using f = c/λ
f = (3 * 10⁸ m/s) / 4.866 * 10⁻⁷ m
frequency, f = 6.16 * 10¹⁴ Hz
Draw the structural formula of the principal organic product formed when ethyl benzoate is treated with C6H5MgBr (two equivalents), then HCl/H2O.
Answer:
Ph3OH
Explanation:
The reaction is between ethyl benzoate (PhCOOC2H5) and a Grignard reagent PhMgBr(C6H5MgBr).
The first step in the reaction mechanism is that the ethyl benzoate is converted to PhCOPh by the first molecule of Grignard reagent.
The second molecule of Grignard reagent now converts PhCOPh to Ph3O^-. In the presence of acid, Ph3O^- is now protonated to yield Ph3OH which is the major organic product of the reaction.
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The volume of a sample of oxygen is 300mL when the pressure is 1 atm and the temperature is 27 C . At what temperature is the volume 1.00 L and the pressure.500 atm?
Answer:
T2 = 500K
Explanation:
Given data:
P1 = 1atm
V1 = 300ml
T1= 27 + 273 = 300K
T2 = ?
V2 = 1.00ml
P2 = 500atm
Apply combined law:
P1xV1//T1 = P2xV2/T2 ...eq1
Substituting values into eq1:
1 x 300/300 = 500 x 1/T2
Solve for T2:
300T2 = 500 x 300
300T2 = 150000
Divide both sides by the coefficient of T2:
300T2/300 = 150000/300
T2 = 500K
Re-order each list of elements in the table below, if necessary, so that the elements are listed in order of decreasing electronegativity.
Answer:
O, S, Te
Cl, Br, Se
Explanation:
Main group elements have an electronegativity that increases across a period (from left to right) and decreases down a group.
Each atom has its own value which you can find on the electronegativity chart.
Metals have low values
Nonmetals have high values
I'm your case:
O = 3.5
S = 2.5
Te = 2.1
Cl = 3.0
Br = 2.8
Se = 2.4
O, S, Te, and Cl, Br, Se are the correct order for the elements listed in order of decreasing electronegativity.
What is electronegativity?
Electronegativity. is the tendency or the efficiency of an atom to attract the lone pair of electrons towards itself to become stable and complete their octave is known as electronegativity.
In the periodic table oxygen, fluorine and nitrogen are the three top, most electronegative elements, and from moving up to down in periodic table electronegativity. decreases and left to right increases.
Therefore, the correct order for the elements listed in order of decreasing electronegativity is O, S, Te, and Cl, Br, Se.
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Determine the number of moles of the anhydrous salt present after heating, assuming that the contents of the aluminum cup after heating are pure anhydrous KAl(SO 4 ) 2 .
Answer:
0.2 moles, assuming weight of dried salt
Explanation:
In order to determine the number of moles, we need to be aware of the mass of the substance in question.
Assuming the mass of the dehydrated [tex]KAl(SO_{4} )_{2}.H_{2} O[/tex] is 50g.
No. of moles = mass of substance/ molar mass of the substance.
= [tex]\frac{50g}{39+27+32*2+16*4*2\\)g/mol}[/tex]
= 0.2 moles moles.
Which equation best represents the net ionic equation for the reaction that occurs when aqueous solutions of potassium phosphate and iron(II) nitrate are mixed? Question 8 options: 3Fe2+(aq) + 2PO43–(aq) → Fe3(PO4)2(s) 2K+(aq) + Fe(NO3)2(aq) → 2KNO3(aq) + Fe2+(aq) 3Fe2+(aq) + 2PO43–(aq) → Fe3(PO4)2(aq) 2K3PO4(aq) + 3Fe2+(aq) → Fe3(PO4)2(s) + (K+)6(aq) 2K3PO4(aq) + 3Fe(NO3)2(aq) → Fe3(PO4)2(s) + 6KNO3(aq)
Answer:
2PO₄³⁻ + 3Fe²⁺ → Fe₃(PO₄)₂(s)
Explanation:
In a net ionic equation you list only the ions that are participating in the reaction.
When potassium phosphate, K₃PO₄, reacts with iron (II) nitrate, Fe(NO₃)₂ producing iron (II) phosphate, Fe₃(PO₄)₂ that is an insoluble salt. The reaction is:
2K₃PO₄ + 3 Fe(NO₃)₂ → Fe₃(PO₄)₂(s) + 6NO₃⁻ + 6K⁺
The ionic equation is:
6K⁺ + 2PO₄³⁻ + 3Fe²⁺ + 6NO₃⁻→ Fe₃(PO₄)₂(s) + 6NO₃⁻ + 6K⁺
Subtracting the K⁺ and NO₃⁻ ions that are not participating in the reaction, the net ionic equation is:
2PO₄³⁻ + 3Fe²⁺ → Fe₃(PO₄)₂(s)what is the osmotic pressure of pure water
Answer:
The osmotic pressure of ocean water is about 27 atm.
Explanation:
Pure water is water that contains no impurities. Ocean water is 96.5% pure with only about 3.5% of its content, salt water.
Osmotic pressure occurs when solutions that have different concentrations are isolated by a membrane. This osmotic pressure makes water move towards the solution that has the highest concentration, which means that if the concentration or temperature of the solution is high, the osmotic pressure becomes higher.
The equation for osmotic pressure is pi = iMRT.
Which correctly lists the three land uses that the Bureau of Land Management was originally created to manage? mining, recreation, wildlife refuges recreation, developing oil and gas, battlefields grazing, mining, developing oil and gas developing oil and gas, battlefields, wildlife refuges
Answer: C
Explanation:
Right on edge 2020
The Bureau of Land Management was originally created to manage land for grazing, mining, developing oil and gas.
What is land management?Land management refers to the activities which are done in order to protect and preserve the land as well the resources found on land.
The Bureau of Land Management was created to manage land in the US.
The Bureau of Land Management was originally created to manage land for grazing, mining, developing oil and gas.
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plez hurry Which is an important safety precaution that should be taken during a tornado? Stay away from doors and windows. Move to high ground to avoid flood waters. Try to avoid the storm by driving or running. Stay outside to avoid being trapped in a building.
Answer: stay away from doors and windows.
Explanation:
to aviod geting hit by glass
Answer:
Stay away from doors and windows.
Explanation:
Always stay in the center of the room during a tornado storm. Avoid windows, doors, and corners. If you’re near a window, the glass can shatter and hurt you.
The free energy obtained from the oxidation (reaction with oxygen) of glucose (C6H12O6) to form carbon dioxide and water can be used to re-form ATP by driving the above reaction in reverse. Calculate the standard free energy change for the oxidation of glucose.
Answer:
The correct answer is -2878 kJ/mol.
Explanation:
The reaction that takes place at the time of the oxidation of glucose is,
C₆H₁₂O₆ (s) + 6O₂ (g) ⇒ 6CO₂ (g) + 6H₂O (l)
The standard free energy change for the oxidation of glucose can be determined by using the formula,
ΔG°rxn = ∑nΔG°f (products) - ∑nΔG°f (reactants)
The ΔG°f for glucose is -910.56 kJ/mol, for oxygen is 0 kJ/mol, for H2O -237.14 kJ/mol and for CO2 is -394.39 kJ/mol.
Therefore, ΔG°rxn = 6 (-237.14) + 6 (-394.39) - (-910.56)
ΔG°rxn = -2878 kJ/mol
Interpret the following equation for a chemical reaction using the coefficients given:
Cl2(g) + F2(g) 2ClF(g)
On the particulate level:
________ of Cl2(g) reacts with ______ of F2(g) to form______ of ClF(g).
On the molar level:
______ of Cl2(g) reacts with______ of F2(g) to form______ of ClF(g).
Answer and Explanation:
Given the following chemical equation:
Cl₂(g) + F₂(g) ⇒ 2ClF(g)
The coefficients are: 1 for Cl₂, 1 for F₂ and 2 for ClF. The coefficients indicate the number of units of each ompound that participates in the reaction. It gives the proportion of reactants and products in the reaction. These units can be molecules or moles. In this reaction, we can say:
On the particulate level: 1 molecule of Cl₂(g) reacts with 1 molecule of F₂(g) to form 2 molecules of ClF(g).
On the molar level: 1 mol of Cl₂(g) reacts with 1 mol of F₂(g) to form 2 mol of ClF(g).
Why is phosphorus unusual compared to other group 15 elements? Select the correct answer below: A. There are compounds that contain phosphorus-phosphorus bonds with uncommon oxidation states. B. Phosphorus is relatively unreactive. C. Phosphorus only forms compounds where the oxidation number of phosphorus is 5+. D. Phosphorus is the most electronegative of the group 15 elements.
Answer:
There are compounds that contain phosphorus-phosphorus bonds with uncommon oxidation states.
Explanation:
Phosphorus is a member of group 15 in the periodic table. Its common oxidation States are -3 and +5. Phosphorus is believed to firm some of its compounds by the participation of hybridized d-orbitals in bonding although this is also disputed by some scientists owing to the high energy of d - orbitals.
Phosphorus form compounds having phosphorus-phosphorus bonds in unusual oxidation states such as diphosphorus tetrahydride, H2P-PH2, and tetraphosphorus trisulfide, P4S hence the answer.
Based on their molecular structure, identify the stronger acid from each pair of oxyacids. Match the words in the left column to the appropriate blanks in the sentences on the right.
1) HI is a stronger acid than H2Te because iodine____than tellurium.
2) H2Te is a stronger acid than H2S because the H-Te bond is_____.
3) NaH is not acidic because hydrogen____than sodium.
a. has a more negative electron afflity
b. is more electronegative
c. has a larger atomic radius
d. stronger
e. is harder to ionize
Answer:
1)is more electronegative
2)
3) is more electronegative
Explanation:
1) for the first question, iodine is more electronegative than tellurium hence we naturally expect that HI should be more acidic than H2Te since electronegativities play a role in the acidity of chemical species.
2) the correct option is not listed because the H2Te bond is weaker than the H2S bond. This makes it easier for H2Te to dissociate releasing H^+ , thereby being more acidic than H2S.
3) Hydrogen is more electronegative than sodium hence it cannot be ionized thus NaH is not acidic.
Un globo lleno de helio tenia un volumen de 8.5 L en el suelo a 20°C y a una presión de 750 torr. Cuando se le soltó, el globo se elevo a una altitud donde la temperatura era de -20°C y la presión de 425 torr, ¿Cuál era el volumen del gas del globo en estas condiciones?
Answer:
El volumen del gas era 12.95 L
Explanation:
Se relaciona la presión y el volumen mediante la ley de Boyle, que dice:
“El volumen ocupado por una determinada masa gaseosa a temperatura constante, es inversamente proporcional a la presión”
La ley de Boyle se expresa matemáticamente como: P*V=k
Por otro lado, la Ley de Charles consiste en la relación que existe entre el volumen y la temperatura absoluta de una cierta cantidad de gas ideal, el cual se mantiene a una presión constante. Esta ley dice que cuando la cantidad de gas y de presión se mantienen constantes, el cociente que existe entre el volumen y la temperatura siempre tendrán el mismo valor:
[tex]\frac{V}{T}=k[/tex]
Por último, la Ley de Gay Lussac dice que la temperatura absoluta y la presión son directamente proporcionales. Es decir, cuando se mantiene todo lo demás constante, mientras suba la temperatura de un gas subirá también su presión. Y mientras la temperatura del gas baje, lo mismo ocurrirá con la presión:
[tex]\frac{P}{T}=k[/tex]
Combinado las mencionadas tres leyes se obtiene:
[tex]\frac{P*V}{T} =k[/tex]
Cuando se desean estudiar dos diferentes estados, uno inicial y una final de un gas, se puede aplicar:
[tex]\frac{P1*V1}{T1} =\frac{P2*V2}{T2}[/tex]
Recordando que la temperatura debe usarse en grados Kelvin, conoces los siguientes datos:
P1: 750 torrV1: 8.5 LT1: 20°C= 293°K (siendo 0°C=273°K)P2: 425 torrV2: ?T2: -20°C= 253 °KReemplazando:
[tex]\frac{750 torr*8.5 L}{293K} =\frac{425 torr*V2}{253 K}[/tex]
Resolviendo:
[tex]V2=\frac{750 torr*8.5 L}{293K} *\frac{253 K}{425 torr}[/tex]
V2= 12.95 L
El volumen del gas era 12.95 L
A saturated solution of lead(II) iodide, PbI2 has an iodide concentration of 3.0 x 10^-3 mol/L.
a) What is the molar solubility of PbI2?
b) Determine the solubility constant, Ksp, for lead(II) iodide.
c) Does the molar solubility of lead (II) iodide increase, decrease, or remain unchanged with the addition of potassium iodide to the solution? EXPLAIN.
Answer:
a) 1.5 x 10^-3 mol/L
b) 1.35×10^-8
c) decrease
Explanation:
The solubility of lead II iodide is given by the equation;
PbI2(s) -----> Pb^2+(aq) + 2I^-
By looking at the ICE table, I^-=2x= 3.0 x 10^-3 mol/L/2 = 1.5×10^-3 mol/L
Hence molar solubility of PbI2 = 1.5 x 10^-3 mol/L
Ksp= [Pb^2+] [2I^-]^2 =
Let the molar solubility of each ion be x, therefore;
Ksp= 4x^3
Ksp= 4(1.5 x 10^-3 mol/L)^3= 1.35×10^-8
Addition of kI to the saturated solution will shift the equilibrium position to the left thereby decreasing the solubility of the PbI2 in the system due to common ion effect. The concentration of the iodide ion is now excess in the system leading to the reverse reaction being favoured according to Le Chateliers principle.
a) The molar solubility of PbI₂ is [tex]1.5 * 10^{-3} mol/L[/tex]
b) The solubility constant is [tex]1.35*10^{-8}[/tex]
c) The molar solubility of lead (II) will decrease.
Molar Solubility:The solubility of lead II iodide is given by the equation;
[tex]PbI_2(s) ----- > Pb^{2+}(aq) + 2I^-[/tex]
By looking at the ICE table,
[tex]I^-=2x= 3.0 * 10^{-3} mol/L/2 =[/tex] [tex]1.5 * 10^{-3} mol/L[/tex]
Hence, molar solubility of PbI2 = [tex]1.5 * 10^{-3} mol/L[/tex]
[tex]Ksp= [Pb^{2+}] [2I^-]^2[/tex]
Let the molar solubility of each ion be x, therefore;
[tex]Ksp= 4x^3\\\\Ksp= 4(1.5 * 10^{-3} mol/L)^3\\\\Ksp= 1.35*10^{-8}[/tex]
The addition of KI to the saturated solution will shift the equilibrium position to the left thereby decreasing the solubility of the PbI₂ in the system due to common ion effect. The concentration of the iodide ion is now excess in the system leading to the reverse reaction being favoured according to Le- Ch-ateliers principle.
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For a single substance at atmospheric pressure, classify the following as describing a spontaneous process, a nonspontaneous process, or an equilibrium system.
A) Solid melting below its melting point
B) Gas condensing below its condensation point
C) Liquid vaporizing above its boiling point
D) Liquid freezing below its freezing point
E) Liquid freezing above its freezing point
F) Solid melting above its melting point
G) Liquid and gas together at boiling point with no net condensation or vaporization
H) Gas condensing above its condensation point
I) Solid and liquid together at the melting point with no net freezing or melting
Answer:
Spontaneous process- This is the process that occurs on its own without the application of any external energy or other factor. They include
B) Gas condensing below its condensation point
C) Liquid vaporizing above its boiling point
D) Liquid freezing below its freezing point
F) Solid melting above its melting point
Non spontaneous - This is the process that doesn’t occurs on its own and requires the application of any external energy or factor. They include
A) Solid melting below its melting point
E) Liquid freezing above its freezing point
H) Gas condensing above its condensation point
Equilibrium system
G) Liquid and gas together at boiling point with no net condensation or vaporization
I) Solid and liquid together at the melting point with no net freezing or melting
A) Solid melting below its melting point - nonspontaneous process
B) Gas condensing below its condensation point - spontaneous process
C) Liquid vaporizing above its boiling point - spontaneous process
D) Liquid freezing below its freezing point - spontaneous process
E) Liquid freezing above its freezing point - nonspontaneous process
F) Solid melting above its melting point - spontaneous process
G) Liquid and gas together at boiling point with no net condensation or vaporization - Equilibrium system
H) Gas condensing above its condensation point - nonspontaneous process
I) Solid and liquid together at the melting point with no net freezing or melting - Equilibrium system
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Choose the substance with the lowest boiling point.
A. NBr3.
B. CI2H2.
C. H2O2.
D. H2S.
E. O2.
Answer:
E. O2
Explanation:
All substances has a simple molecular structure, where between their molecules are held by van der Waals' forces. But C must be incorrect because between the H2O2 molecules, they are mainly held by hydrogen bonds on top of van der Waals' forces. Hydrogen bonds are stronger than van der Waals' forces, so more energy is required to separate the H2O2 molecules.
In structures A and D, the molecules are polar. Their van der Waals' forces are stronger than Cl2H2 and O2, which are non-polar.
Between the Cl2H2 and O2, O2 has a smaller molecular size. The van der Waals' forces between the O2 molecules are hence the weakest. Least amount of energy is required to break the intermolecular forces between the O2 molecules therefore it has the lowest boiling point.
Calculate Delta G for each reaction using Delta Gf values: answer kJ ...thank you
a) H2(g)+I2(s)--->2HI(g)
b) MnO2(s)+2CO(g)--->Mn(s)+2CO2(g)
c) NH4Cl(s)--->NH3(g)+HCl(g)
Answer:
a) [tex]\Delta G=2.6kJ[/tex]
b) [tex]\Delta G=-979.57kJ[/tex]
c) [tex]\Delta G=264.21kJ[/tex]
Explanation:
Hello,
In this case, in each reaction we must subtract the Gibbs free energy of formation the reactants to the Gibbs free energy of formation of the products considering each species stoichiometric coefficients. In such a way, the Gibbs free energy of formations are:
[tex]\Delta _fG_{H_2}=\Delta _fG_{I_2}=0kJ/mol\\\Delta _fG_{HI}=1.3kJ/mol\\\Delta _fG_{CO_2}=-394.4kJ/mol\\\Delta _fG_{CO}=-137.3 kJ/mol\\\Delta _fG_{NH_3}=16.7 kJ/mol\\\Delta _fG_{HCl}=-95.3kJ/mol\\\Delta _fG_{MnO_2}=465.37kJ/mol\\\Delta _fG_{Mn}=0kJ/mol\\\Delta _fG_{NH_4Cl}=-342.81kJ/mol[/tex]
So we proceed as follows:
a)
[tex]\Delta G=2\Delta _fG_{HI}-\Delta _fG_{H_2}-\Delta _fG_{I_2}\\\\\Delta G=2*1.3\\\\\Delta G=2.6kJ[/tex]
b)
[tex]\Delta G=\Delta _fG_{Mn}+2*\Delta _fG_{CO_2}-\Delta _fG_{MnO_2}-2*\Delta _fG_{CO}\\\\\Delta G=0+2*-394.4-465.37-2*-137.3\\\\\Delta G=-979.57kJ[/tex]
c)
[tex]\Delta G=\Delta _fG_{NH_3}+\Delta _fG_{HCl}-\Delta _fG_{NH_4Cl}\\\\\Delta G=16.7-95.3-(-342.81)\\\\\Delta G=264.21kJ[/tex]
Regards.
Draw structures for (a) a chain isomer, (b) a positional isomer, and (c) a functional isomer of hexan-1-ol
(i.e., 1-hexanol)
a. Chain isomer
b. Positional isomer
c. Functional isomer
Answer:
See attached picture.
Explanation:
Hello,
In this case, we should define each type of structural formula as shown below:
- Chain isomers: molecules with the same molecular formula, but different arrangements.
- Positional isomers are constitutional isomers that have the same carbon skeleton and the same functional groups but differ from each other in the location of the functional groups.
- Functional isomers are structural isomers that have the same molecular formula (that is, the same number of atoms of the same elements), but the atoms are connected in different ways so that the groupings are dissimilar.
Regards.
Methanol is produced industrially by catalytic hydrogenation of carbon monoxide according to the following equation: CO(g) + 2 H2(g) → CH3OH(l) If the yield of the reaction is 40%, what volume of CO (measured at STP) would be needed to produce 1.0 × 106 kg CH3OH?
Answer:
1.7 × 10⁹ L
Explanation:
Step 1: Write the balanced equation
CO(g) + 2 H₂(g) → CH₃OH(l)
Step 2: Calculate the moles corresponding to 1.0 × 10⁶ kg CH₃OH
The molar mass of CH₃OH is 32.04 g/mol.
[tex]1.0 \times 10^{6} kg \times \frac{10^{3}g }{1kg} \times \frac{1mol}{32.04g} = 3.1 \times 10^{7} mol[/tex]
Step 3: Calculate the theoretical yield of CH₃OH
The real yield of CH₃OH is 3.1 × 10⁷ mol and the percent yield is 40%. The theoretical yield is:
[tex]3.1 \times 10^{7} mol (R) \times \frac{100mol(T)}{40mol(R)} = 7.8 \times 10^{7}mol(T)[/tex]
Step 4: Calculate the moles of CO required to produce 7.8 × 10⁷ mol of CH₃OH
The molar ratio of CO to CH₃OH is 1:1. The moles of CO required are 1/1 × 7.8 × 10⁷ mol = 7.8 × 10⁷ mol
Step 5: Calculate the volume of 7.8 × 10⁷ mol of CO at STP
The volume of 1 mole of CO at STP is 22.4 L.
[tex]7.8 \times 10^{7}mol \times \frac{22.4L}{mol} = 1.7 \times 10^{9}L[/tex]