Answer:
D: 5s
Explanation:
hope this helps :)
Which of the following statements about water is not true?
Answer:
Water has a low specific heat capacity and so large bodies of water moderate temperatures on Earth.
Explanation:
Water has a very high specific heat capacity, meaning that it has to absorb a lot of energy to raise the temperature by one degree. Because water has a high specific heat capacity, large bodies of water can moderate the temperature of nearby land.
Hope this helps.
identify the correct acid/conjugate base pair in this equation:
NaHCO3 + H20 = + H2CO3 + OH
+ Na
H20 is an acid and H2CO3 is its conjugate base.
HCO3 is an acid and OH is its conjugate base.
H20 is an acid and HCO3 is its conjugate base.
H20 is an acid and OH is its conjugate base.
Answer:
H20 is an acid and OH is its conjugate base.
Explanation:
Chemical reactions involving acids and bases occur. An acid is a substance that dissociates in water i.e. lose an hydrogen ion/proton. According to the Bronsted-Lowry acid-base theory, when an acid dissociates in water and loses its hydrogen ion, the resulting substance that forms is the CONJUGATE BASE. A conjugate base is the compound formed as a result of the removal of an H+ ion from an acid.
Based on the chemical reaction in the question, NaHCO3 + H20 = H2CO3 + OH- + Na+
The H20 loses its hydrogen ion (H+) to form an anion OH-. This anion formed is the conjugate base while H20 is its acid.
A. Identify the structure drawn below.
Answer:
Hexane
Explanation:
You have a carbon structure with only single bonds. This means that the name will end in -ane.
There are 6 carbon atoms. This means that the name will begin with hex-.
The structure is hexane.
A hot lump of 27.4 g of aluminum at an initial temperature of 69.5 °C is placed in 50.0 mL H2O initially at 25.0 °C and allowed to reach thermal equilibrium. What is the final temperature of the aluminum and water, given that the specific heat of aluminum is 0.903 J/(g·°C)? Assume no heat is lost to surroundings.
Answer:
[tex]\large \boxed{29.7 \,^{\circ}\text{C}}[/tex]
Explanation:
There are two heat transfers involved: the heat lost by the aluminium and the heat gained by the water.
According to the Law of Conservation of Energy, energy can neither be destroyed nor created, so the sum of these terms must be zero.
Let the Al be Component 1 and the H₂O be Component 2.
Data:
For the Al:
[tex]m_{1} =\text{27.4 g; }T_{i} = 69.5 ^{\circ}\text{C; }\\C_{1} = 0.903 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$}[/tex]
For the water:
[tex]m_{2} =\text{50.0 g; }T_{i} = 25.0 ^{\circ}\text{C; }\\C_{2} = 4.184 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$}[/tex]
Calculations
(a) The relative temperature changes
[tex]\begin{array}{rcl}\text{Heat lost by Al + heat gained by water} & = & 0\\m_{1}C_{1}\Delta T_{1} + m_{2}C_{2}\Delta T_{2} & = & 0\\\text{27.4 g}\times 0.903 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$} \times\Delta T_{1} + \text{50.0 g} \times 4.184 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$}\Delta \times T_{2} & = & 0\\24.74\Delta T_{1} + 209.2\Delta T_{2} & = & 0\\\end{array}[/tex]
(b) Final temperature
[tex]\Delta T_{1} = T_{\text{f}} - 69.5 ^{\circ}\text{C}\\\Delta T_{2} = T_{\text{f}} - 25.0 ^{\circ}\text{C}[/tex]
[tex]\begin{array}{rcl}24.74(T_{\text{f}} - 69.5 \, ^{\circ}\text{C}) + 209.2(T_{\text{f}} - 25.0 \, ^{\circ}\text{C}) & = & 0\\24.74T_{\text{f}} - 1719 \, ^{\circ}\text{C} + 209.2T_{\text{f}} -5230 \, ^{\circ}\text{C} & = & 0\\233.9T_{\text{f}} - 6949\, ^{\circ}\text{C} & = & 0\\233.9T_{\text{f}} & = & 6949 \, ^{\circ}\text{C}\\T_{\text{f}}& = & \mathbf{29.7 \, ^{\circ}}\textbf{C}\\\end{array}\\\text{The final temperature is $\large \boxed{\mathbf{29.7 \,^{\circ}}\textbf{C}}$}[/tex]
Check:
[tex]\begin{array}{rcl}27.4 \times 0.903 \times (29.7 - 69.5) + 50.0 \times 4.184 (29.7 - 25.0)& = & 0\\24.74(-39.8) +209.2(4.7) & = & 0\\-984.6 +983.2 & = & 0\\-985 +983 & = & 0\\0&=&0\end{array}[/tex]
The second term has only two significant figures because ΔT₂ has only two.
It agrees to two significant figures
Fructose-2,6-bisphosphate is a regulator of both glycolysis and gluconeogenesis for the phosphofructokinase reaction of glycolysis and the fructose-1,6-bisphosphatase reaction of gluconeogenesis. In turn, the concentration of fructose-2,6-bisphosphate is regulated by many hormones, second messengers, and enzymes.
How do the following affect glycolysis and gluconeogenesis?
Activate glycolysis Inhibit gluconeogenesis Activate gluconeogenesis Inhibit glycolysis
1. increased levels of fructose-2,6-bisphosphatase
2. activation of fructose-2,6-bisphosphate (FBPase-2)
3. increased glucagon levels
4. activation of PFK-2
5. increased levels of CAMP
Answer:
1. Increased levels of fructose-2,6-bisphosphatase : Activate gluconeogenesis Inhibit glycolysis
2. Activation of fructose-2,6-bisphosphate (FBPase-2) : Activate glycolysis Inhibit gluconeogenesis
3. Increased glucagon levels : Activate gluconeogenesis Inhibit glycolysis
4. Activation of PFK-2 : Activate glycolysis Inhibit gluconeogenesis
5. Increased levels of CAMP : Activate gluconeogenesis Inhibit glycolysis
Explanation:
Glycolysis is the breakdown of glucose molecules in order to release energy in the form of ATP in response to the energy needs of the cells of an organism.
Gluconeogenesis is the process by which cells make glucose from other molecules for other metabolic needs of the cell other than energy production.
Glycolysis and gluconeogenesis are metabolically regulated in the cell by various enzymes and molecules.
The following shows the various regulatory methods and their effects on both processes:
1. The enzyme fructose-2,6-bisphosphatase functions in the regulation of both processes. It catalyzes the breakdown of the molecule fructose-2,6-bisphosphate which is an allosteric effector of two enzymes phosphofructokinasse-1, PFK-1 and fructose-1,6-bisphosphatase, FBPase-1 which fuction in glycolysis and gluconeogenesis respectively.
Increased levels of fructose-2,6-bisphosphatase activates gluconeogenesis and inhibits glycolysis by its breakdown of fructose-2,6-bisphosphate.
2. Fructose-2,6-bisphosphate increases the activity of PFK-1 and inhibits the the activity of FBPase-1. The effect is that glycolysis is activated while gluconeogenesis is inhibited.
3. Glucagon is a hormone that stimulates the synthesis of cAMP. It fuctions to activate gluconeogenesis and inhibit glycolysis.
4. Phosphosfructikinase-2, PFK-2 is an enzyme that catalyzes the formation of fructose-2,6-bisphosphate. Activation of PFK-2 results the activation of glycolysis and inhibition of gluconeogenesis.
5. Cyclic-AMP (cAMP) synthesis in response to glucagon release serves to activate a cAMP-dependent protein kinase which phosphorylates the bifunctional protein PFK-2/FBPase-2. This phosphorylation enhances the activity of FBPase-2 while inhibiting the activity of PFK-2, resulting in the activation of gluconeogenesis and inhibition of glycolysis.
A 40.80 gram sample of copper is heated in the presence of excess sulfur. A metal sulfide is formed with a mass of 51.09 g. Determine the empirical formula of the metal sulfide.
Answer:
Cu₂S
Explanation:
From the question,
Cu S
Mass: 40.80 g 51.09-40.80 = 10.29 g
Mole ratio: 40.80/63.5 10.29/32.1
0.64 : 0.32
Divide by the smallest,
0.64/0.32 : 0.32/0.32
2 : 1
Therefore,
Empirical formula = Cu₂S.
what is chemical equation of Braium chloride?
Answer:
BaCl2
Explanation:
Barium = Ba
Chloride => Cl-
Chemical Equation:
Ba + Cl => BaCl2
Note:
The valency of barium is 2 and valency of chloride is 1 (i.e. chlorine). The formula formed by the combination of these elements is BaCl2 (there's exchange of valencies when these two elements combine).
In the laboratory you are asked to make a 0.694 m copper(II) iodide solution using 455 grams of water. How many grams of copper(II) iodide should you add
Answer:
100.2g of CuI₂ you must add
Explanation:
Molality, m, is defined as the ratio between moles of solute and kg of solvent.
In the problem, you have a 0.694m of copper (II) iodide -CuI₂, molar mass: 317.35 g/mol-. That means there are 0.694 moles of CuI₂ per kg of water.
As you have 455g = 0.455kg of water -solvent-, moles of CuI₂ are:
0.455kg ₓ (0.694 moles CuI₂ / kg) = 0.316 moles of CuI₂
Using molar mass, grams of CuI₂ in the solution are:
0.316moles CuI₂ ₓ (317.35g / mol) =
100.2g of CuI₂ you must addWhich is the electron configuration for bromine?
Answer:
The answer below would be written in a straight line from left to right but I wrote it as a list to make it easier to read.
Explanation:
1s^2
2s^2
2p^6
3s^2
3p^6
4s^2
3d^10
4p^5
Using Charles’s law, V1/T1 =V2/T2 and the information below, solve the question. If a balloon takes up 625L at 273K, what will the new volume be when the balloon is heated to 353K.
Answer:
The new volume is 808L.
Explanation:
First, you need to set up your proportion, using Charles's law.
V1 V2
=
T1 T2
Then, substitute for the ones you already know.
625 L V2
=
273 K 353 K
Then, you need to cross multiply.
625 x 353 = 273 x V2
Then, solve for V2.
220625 = 273 x V2
220625 ÷ 273 = V2
808 = V2
The final volume is 808L.
What is the name of this molecule?
Answer:
[tex]\boxed{Butyne}[/tex]
Explanation:
Triple Bonds => So it is an alkyne
The suffix used will be "-yne"
4 Carbons => The prefix used will be "But-"
Combining the prefix and suffix, we get:
=> Butyne
Answer:
[tex]\boxed{\mathrm{Butyne}}[/tex]
Explanation:
Alkynes have triple bonds ≡. The molecule has one triple bond.
Suffix ⇒ yne
The molecule has 4 carbon atoms and 6 hydrogen atoms.
Prefix ⇒ But (4 carbons)
The molecule is Butyne.
[tex]\mathrm{C_4H_6}[/tex]
Consider the reaction 2N2(g) O2(g)2N2O(g) Using the standard thermodynamic data in the tables linked above, calculate Grxn for this reaction at 298.15K if the pressure of each gas is 22.20 mm Hg.
Answer:
[tex]\Delta G^0 _{rxn} = 207.6\ kJ/mol[/tex]
ΔG ≅ 199.91 kJ
Explanation:
Consider the reaction:
[tex]2N_{2(g)} + O_{2(g)} \to 2N_2O_{(g)}[/tex]
temperature = 298.15K
pressure = 22.20 mmHg
From, The standard Thermodynamic Tables; the following data were obtained
[tex]\Delta G_f^0 \ \ \ N_2O_{(g)} = 103 .8 \ kJ/mol[/tex]
[tex]\Delta G_f^0 \ \ \ N_2{(g)} =0 \ kJ/mol[/tex]
[tex]\Delta G_f^0 \ \ \ O_2{(g)} =0 \ kJ/mol[/tex]
[tex]\Delta G^0 _{rxn} = 2 \times \Delta G_f^0 \ N_2O_{(g)} - ( 2 \times \Delta G_f^0 \ N_2{(g)} + \Delta G_f^0 \ O_{2(g)})[/tex]
[tex]\Delta G^0 _{rxn} = 2 \times 103.8 \ kJ/mol - ( 2 \times 0 + 0)[/tex]
[tex]\Delta G^0 _{rxn} = 207.6\ kJ/mol[/tex]
The equilibrium constant determined from the partial pressure denoted as [tex]K_p[/tex] can be expressed as :
[tex]K_p = \dfrac{(22.20)^2}{(22.20)^2 \times (22.20)}[/tex]
[tex]K_p = \dfrac{1}{ (22.20)}[/tex]
[tex]K_p[/tex] = 0.045
[tex]\Delta G = \Delta G^0 _{rxn} + RT \ lnK[/tex]
where;
R = gas constant = 8.314 × 10⁻³ kJ
[tex]\Delta G =207.6 + 8.314 \times 10 ^{-3} \times 298.15 \ ln(0.045)[/tex]
[tex]\Delta G =207.6 + 2.4788191 \times \ ln(0.045)[/tex]
[tex]\Delta G =207.6+ (-7.687048037)[/tex]
[tex]\Delta G =[/tex] 199.912952 kJ
ΔG ≅ 199.91 kJ
g Air contains nitrogen, oxygen, argon, and trace gases. If the partial pressure of nitrogen is 592 mm Hg, oxygen is 160 mm Hg, argon is 7 mm Hg, and trace gas is 1 mm Hg, what is the atmospheric pressure
Answer:
Explanation:
Atmospheric pressure = partial pressure of nitrogen + partial pressure of oxygen + partial pressure of argon + partial pressure of trace element
putting the given values
Atmospheric pressure = 592 + 160 + 7 + 1
= 760 mm of Hg .
A chemistry student weighs out of lactic acid into a volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with solution. Calculate the volume of solution the student will need to add to reach the equivalence point. Round your answer to significant digits
Answer:
28.0mL of the 0.0500M NaOH solution
Explanation:
0.126g of lactic acid diluted to 250mL. Titrated with 0.0500M NaOH solution.
The reaction of lactic acid, H₃C-CH(OH)-COOH (Molar mass: 90.08g/mol) with NaOH is:
H₃C-CH(OH)-COOH + NaOH → H₃C-CH(OH)-COO⁻ + Na⁺ + H₂O
Where 1 mole of the acid reacts per mole of the base.
You must know the student will reach equivalence point when moles of lactic acid = moles NaOH.
the student will titrate the 0.126g of H₃C-CH(OH)-COOH. In moles (Using molar mass) are:
0.126g ₓ (1mol / 90.08g) = 1.40x10⁻³ moles of H₃C-CH(OH)-COOH
To reach equivalence point, the student must add 1.40x10⁻³ moles of NaOH. These moles comes from:
1.40x10⁻³ moles of NaOH ₓ (1L / 0.0500moles NaOH) = 0.0280L of the 0.0500M NaOH =
28.0mL of the 0.0500M NaOH solutionGiven that Ag-107 (51.839% abundance) and the mass ratio: Ag-109/Ag-107=1.0187.
Calculate the mass of Ag-107. (Atomic mass of Ag = 107.87 amu)
Answer:
Atomic mass of Ag-107 = 106.94 amu
Explanation:
Let the mass of Ag-107 be y
Since the mass ratio of Ag-109/Ag-107 is 1.0187, the mass of Ag-109 is 1.0187 times heavier than the mass of Ag-107
Mass of Ag-109 = 1.0187y
Relative atomic mass of Ag = sum of (mass of each isotope * abundance)
Relative atomic mass of Ag = 107.87
Abundance of Ag-107 = 51.839% = 0.51839
Abundance of Ag-109 = 41.161% = 0.48161
107.87 = (y * 0.51839) + (1.018y * 0.48161)
107.87 = 0.51838y + 0.49027898y
107.87 = 1.00865898y
y = 107.87/1.00865898
y = 106.94 amu
Therefore, atomic mass of Ag-107 = 106.94 amu
What does the period number tell about the energy levels occupied by
electrons in an atom?
A. The period number tells how many electrons are in the highest
energy level of the atom.
B. The period number tells which is the highest energy level occupied
by the electrons.
C. The period number tells how many electrons are in each sublevel
of the atom.
D. The period number tells how many energy sublevels are occupied
in the atom.
Answer: B. The period number tells which is the highest energy level occupied by the electrons
Explanation:
The period number ( denoted by 'n' ) is the outer energy level that is occupied by electrons in an atom. The period number that an element is in, is the number of energy levels that the element has.When we move across a period from left to right in a periodic table the number of electrons in atoms increases within the same orbit.Thus, we can say that the period number tells which is the highest energy level occupied by the electrons in an atom.
hence, the correct option is B. The period number tells which is the highest energy level occupied by the electrons.
The period number tell about the energy levels occupied by electrons in an atom B. The period number tells which is the highest energy level occupied by the electrons. option B , second option is correct.
What are energy levels ?The fixed distances from an atom's nucleus where electrons may be found are referred to as energy levels (also known as electron shells). Higher energy electrons have greater energy as you move out from the nucleus. A region of space within an energy level known as an orbital is where an electron is most likely to be found.
When a quantum mechanical system or particle is bound, or spatially constrained, it can only take on specific discrete energy values, or energy levels. Classical particles, on the other hand, can have any energy level.
Therefore, option B , second option is correct.
Learn more about energy levels at;
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Where possible, classify these systems as reactant-favored or product-favored at 298 K. If the direction cannot be determined from the information given, classify the reaction as "Insufficient information."
A. Reactant-favored
B. Product-favored
C. Insufficient information
1. A(s) + B(g) 2C(g) delta H degree = -109 kJ
2. A(s) + 2B(g) C(g) delta H degree=+271 kJ
3. 2A(g) + B(g) 4C(g) delta H degree=+322 kJ
4. A(g) + 2B(g) 2C(g) delta H degree=-89 kJ
Answer:
There is insufficient information to know direction of these systems
Explanation:
Delta H of a reaction is defined as the amount of energy involved when it occurs. The ΔH < 0 represents the reaction will release energy and ΔH > 0 the reaction will absorb energy.
As you can see, ΔH doesn't give information about the direction of a reaction (Spontaneity). In fact, to know spontaneity of a reaction you must know ΔG involved in this reaction.
As the reactions have ΔH but not ΔG,
There is insufficient information to know direction of these systemsA spinning turbine can generate electricity only in the form of a/an _______ current.
Of all the alternative energy technologies presented in this section, only solar panels produce a/an _______ current.
Answer:
The correct answer is - alternating and direct, in order.
Explanation:
Alternating current is is type of electric current that is characterized by the direction of the flow of electrons in continuously switches its directs in opposite manner at regular cycles. While direct current or DC is flow of the electrons that move from starting to end in one direction.
Spinning turbines always leads to the alternating electric current while only solar energy produces the direct current with the help of the solar panels.
Thus, the correct answer is - alternating and direct, in order.
Answer:
1. alternating
2. direct
3. The sun heats up the atmosphere as Earth spins, creating areas of high and low temperature. This temperature difference causes wind to start moving through convection, which can then drive a wind turbine to produce electricity.
Explanation:
From Penn
Which accurately describes one impact of the atmosphere on Earth’s cycles?
Answer:
Produces Wind Currents
Explanation:
Answer:
produces wind currents
Explanation:
i just took the test and got it right :}
A gas mixture containing N2 and O2 was kept inside a 2.00 L container at a temperature of 23.0°C and a total pressure of 1.00 ATM the partial pressure of oxygen was 0.722 ATM how many grams of nitrogen are present in the gas mixture
Answer:
0.641 g of Nitrogen are present in the mixture.
Explanation:
We use the Ideal Gases Law, to solve this question.
For the mixture:
P mixture . V mixture = mol mixture . R . T
We convert the T° to K → 23°C + 273 = 296 K
R = Ideal gases constant → 0.082 L.atm/mol.K
1 atm . 2L = mol mixture . 0.082 L.atm/mol.K . 296K
2 atm.L / ( 0.082 mol /L.atm) . 296 = 0.0824 moles
We know that sum of partial pressure = 1
Partial pressure N₂ + Partial pressure O₂ = 1
1 - 0.722 atm = Partial pressure N₂ → 0.278 atm
We apply the mole fraction concept:
Partial pressure N₂ / Total pressure = Moles N₂ / Total moles
Moles N₂ = (Partial pressure N₂ / Total pressure) . Total moles
Moles N₂ = (0.278 atm / 1 atm) . 0.0824 mol → 0.0229 moles
We convert the moles to mass → 0.0229 mol . 28 g/mol = 0.641 g
641 mg
The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science. CO2 ( aq) + H2O ( l) H2CO3 ( aq) Which one of the following is the correct equilibrium constant expression (K c) for this reaction?
a) K =[H2CO3]/ [CO2]
b) K=[CO2]/ [H2CO3]
c) K=[H2CO3]/ [CO2][H2O]
d) K=[CO2][H2O]/ [H2CO3]
e) K=1/[H2CO3]
Answer:
Kc = [H₂CO₃] / [CO₂]
Explanation:
Equilibrium constant expression (Kc) of any reaction is defined as the ratio between molar concentrations in equilibrium of products over reactants.
Pure solids and liquids don't affect the equilibrium and you don't have to take its concentrations in the equilibrium.
Also, each specie must be powered to its reactant coefficient.
For example, for the reaction:
aA(s) + bB(aq) ⇄ cC(l) + nD(g) + xE(aq)
The equilibrium constant, kc is:
Kc = [D]ⁿ / [B]ᵇ[E]ˣ
You don't take A nor C species because are pure solids and liquids. b, n and x are the reactant coefficients of each substance. Ratio of products over reactants
Thus, for the reaction:
CO₂(aq) + H₂O(l) ⇄ H₂CO₃(aq)
The Kc is:
Kc = [H₂CO₃] / [CO₂]
We wear cotton clothes in summer.
Answer:
we wear cotton clothes because it helps to cool us down and remove the excess heat that causes us to feel hot.
Answer:
[tex]\boxed{\mathrm{view \: explanation}}[/tex]
Explanation:
We wear cotton clothes in the summer beacuse cotton absorbs and removes body moisture caused by the sweat and allows better air circulation than fabric clothes.
What is the percent yield for a chemical reaction if the actual yield is 36 g and the theorical yield is 45 g.
Answer:
⇒ Percent yield = 80 %
Explanation:
Given:
Actual yield = 36 g
Theoretical yield = 45 g
Find:
Percent yield
Computation:
⇒ Percent yield = [Actual yield / Theoretical yield] 100%
⇒ Percent yield = [36 / 45] 100%
⇒ Percent yield =[0.8] 100%
⇒ Percent yield = 80 %
The s orbital can hold
Answer:
2 electrons
Explanation:
When (R)-3-bromo-2,3-dimethylpentane is treated with sodium hydroxide, four different alkenes are formed. Draw all four products, and rank them in terms of stability.
Answer:
Most stable: 2,3-dimethylpent-2-ene > (E)-3,4-dimethylpent-2-ene > (Z)-3,4-dimethylpent-2-ene > 2-methyl-3-methylenepentane : Least stable
Explanation:
Treatment of NaOH with (R)-3-bromo-2,3-dimethylpentane results in the elimination of HBr. Each H atoms present on each [tex]\beta[/tex]-carbon atoms can be eliminated result in the formation of four possible products: (1) 2,3-dimethylpent-2-ene, (2) (E)-3,4-dimethylpent-2-ene, (3) (Z)-3,4-dimethylpent-2-ene and (4) 2-methyl-3-methylenepentane.
The stability of these alkenes depends on the number of hyperconjugative H atoms present with respect to the double bond. In accordance with this, 2,3-dimethylpent-2-ene is the most stable alkene (11-hyperconjugative H atoms). Then, 3,4-dimethylpent-2-ene is the second most stable alkene (7-hyperconjugative H atoms). Among (E)-3,4-dimethylpent-2-ene and (Z)-3,4-dimethylpent-2-ene, (E)-3,4-dimethylpent-2-ene is more stable due to it's less sterically hindered structure. 2-methyl-3-methylenepentane is the least stable alkene (3-hyperconjugative H atoms).
So, decreasing order of stability of alkenes from most stable to least stable:
2,3-dimethylpent-2-ene > (E)-3,4-dimethylpent-2-ene > (Z)-3,4-dimethylpent-2-ene > 2-methyl-3-methylenepentane
Three bromo As just a result of the nucleophilic substitution mechanism, 2,4 dimethylpentane generates a racemic mix containing both the r and s forms of the molecule.
In the first, sluggish phase, a two-degree cation with a positive charge is produced at carbon 3, and then it undergoes rearrangement to a 3-degree carbocation at carbon 2 either from the side. So because carbocation only has 6 electrons in its outermost shell, it is sp2 hybridized and thus planar in structure. In step two then occurs, as well as the attack of the -OH group, as the -OH (hydroxyl) group can strike from either side (top or bottom), leading to the formation of a racemic mixture of 2,4 dimethyl pentane-2-ol.This quantity of alpha-hydrogens in an alkyl group can be used to determine its stability. The greater the number of alpha-hydrogens inside an alkene, the overall larger the number of hyperconjugated structures, and thus the greater the stability. Due to the obvious symmetrical structure of a trans-isomer, whenever the amount of alpha-hydrogens is the same, the trans-alkene isomer is much more stable than that of the cis-alkene isomer.Please find the attached file.
Learn more about the 3-Bromo-2,3-dimethylpentane:
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Provide the structures of the fragments that result when the molecular ion of 2-heptanone undergoes fragmentation via McLafferty rearrangement. Include charges and single electrons.
Answer:
See explanation
Explanation:
We have to start, remembering the mechanism behind the McLafferty rearrangement. The hydrogen in the gamma carbon (in this case, carbon 5) would be removed by a heterolytic rupture due to the cation-radical placed in the oxygen of the carbonyl group. Then we will have several heterolytic ruptures. Between carbons alpha and beta (in this case, 4 and 3) and a rupture in the carbonyl group. Due to these ruptures, two double bonds would be formed. One double bond in the alcohol cation-radical and the other one in the alkene.
See figure 1
I hope it helps!
Given 3.4 grams of x compound with a molar mass of 85 g and 4.2 grams of y compound with a molar mass of 48 g How much of compound xy can be generated 2x + y2 = 2xy
Answer:
[tex]4.36~g~XY[/tex]
Explanation:
In this case, we can start with the reaction:
[tex]2X + Y_2~->~2XY[/tex]
If we check the reaction, we will have 2 X and Y atoms on both sides. So, the reaction is balanced. Now, the problem give to us two amounts of reagents. Therefore, we have to find the limiting reagent. The first step then is to find the moles of each compound using the molar mass:
[tex]3.4~g~X\frac{1~mol~X}{85~g~X}=0.04~mol~X[/tex]
[tex]4.2~g~Y_2\frac{1~mol~Y_2}{48~g~Y_2}=0.0875~mol~Y_2[/tex]
Now, we can divide by the coefficient of each compound (given by the balanced reaction):
[tex]\frac{0.04~mol~X}{1}=~0.04[/tex]
[tex]\frac{0.0875~mol~Y_2}{2}=0.04375[/tex]
The smallest value is for "X", therefore this is our limiting reagent. Now, if we use the molar ratio between "X" and "XY" we can calculate the moles of XY, so:
[tex]0.04~mol~X\frac{2~mol~XY}{2~mol~X}=0.04~mol~XY[/tex]
Finally, with the molar mass of "XY" we can calculate the grams. Now, we know that 1 mol X = 85 g X and 1 mol [tex]Y_2[/tex] = 48 g [tex]Y_2[/tex] (therefore 1 mol Y = 24 g Y). With this in mind the molar mass of XY would be 85+24 = 109 g/mol. With this in mind:
[tex]0.04~mol~XY\frac{109~g~XY}{1~mol~XY}=4.36~g~XY[/tex]
I hope it helps!
2HCl(aq) + Ba(OH)2(aq) → BaCl2(aq) + 2H2O(l) ΔH = –118 kJ Calculate the heat when 250.0 mL of 0.500 M HCl is mixed 500.0 mL of 0.500 M Ba(OH)2. Assuming that the temperature of both solutions was initially 25.0 oC and that the final mixture has mass of 750.0 g and a specific heat capacity of 4.18 J oC–1g–1, calculate the final temperature (in oC) of the mixture.
Answer:
Heat = 7375J
Final temperature of the mixture = 27.35°C
Explanation:
In the reaction:
2HCl(aq) + Ba(OH)₂(aq) → BaCl₂(aq) + 2H₂O(l) ΔH = –118 kJ
When 2 moles of HCl reacts with excess of Ba(OH)₂ there are released 118kJ.
In the reaction, moles of HCl and Ba(OH)₂ that reacts are:
Moles HCl = 0.250L ₓ (0.500 moles / L) = 0.125 moles HCl
Moles Ba(OH)₂ = 0.500L ₓ (0.500 moles / L) = 0.250 moles Ba(OH)₂
For a complete reaction of 0.125 moles of HCl you need:
0.125 mol HCl ₓ (1 mole Ba(OH)₂ / 2 moles HCl) = 0.0625 moles Ba(OH)₂
As you have 0.250 moles of Ba(OH)₂, this reactant is in excess
2 moles of HCl that react release 118kJ, 0.125 moles of HCl release:
0.125 moles HCl ₓ (118kJ / 2 moles) = 7.375kJ =
7375JThe heat released can be obtained with the formula:
Q = C×m×ΔT
Where Q is heat, C specific heat of the solution, m its mass and ΔT change in temperature.
Replacing:
Q = C×m×ΔT
7375J = 4.18J/g°C×750.0g×ΔT
2.35°C = ΔT
As ΔT = Final T - Initial T:
2.35°C = Final T - 25.0°C
27.35°C = Final temperature of the mixture
11. (2 pts) Sodium Hydroxide, is also known as lye and was a critical component in
homemade soap. Now it is a commonly used drain cleaner because it chemically reacts
with fats (the typical cause of a clog) to form a soap that can be swept down the drain.
What is the molarity of 5.00 g Sodium Hydroxide in 750.0 mL of solution?
Answer:
0.167M
Explanation:
Molarity, M, is an unit of concentration in chemistry defined as the ratio between moles of solute (NaOH in this case) and volume of the solution in liters.
To find molarity of 5.00 g Sodium Hydroxide in 750.0 mL of solution we need to convert mass of NaOH to moles (Using its molar mass: 40g/mol) and the mililiters of solution to liters (1L = 1000mL), thus:
Moles NaOH = 5.00g × (1mol/ 40g) = 0.125 moles NaOH = Moles solute
Liters solution = 750.0mL × (1L / 1000mL) = 0.7500L solution
And molariy is:
0.125 moles NaOH / 0.7500L solution =
0.167M
Diluting sulfuric acid with water is highly exothermic:
(Use data from the Appendix to find for diluting 1.00 mol of H2SO4(l) (d = 1.83 g/mL) to 1 L of 1.00 MH2SO4(aq) (d = 1.060 g/mL). )
Suppose you carry out the dilution in a calorimeter. The initial T is 25.2°C, and the specific heat capacity of the final solution is 3.458 J/gK. What is the final T in °C ?
Answer:
The correct answer is 51.2 degree C.
Explanation:
The standard enthalpy for H₂SO₄ (l) is -814 kJ/mole and the standard enthalpy for H₂SO₄ (aq) is -909.3 kJ/mole.
Now the dHreaction = dHf (product) - dHf (reactant)
= -909.3 - (-814)
dHreaction or q = -95.3 kJ of energy will be used for dissociating one mole of H₂SO₄.
The heat change in calorimetry can be determined by using the formula,
q = mass * specific heat capacity * change in temperature -----------(i)
Based on the given information, the density of H₂SO₄ is 1.060 g/ml
The volume of H₂SO₄ is 1 Liter
Therefore, the mass of H₂SO₄ will be, density/Volume = 1.060 g/ml / 1 × 10⁻³ ml = 1060 grams
The initial temperature given is 25.2 degrees C, or 273+25.2 = 298.2 K, let us consider the final temperature to be T₂.
ΔT = T₂ -T₁ = T₂ - 298.2 K
Now putting the values in equation (i) we get,
95.3 kJ = 1060 grams × 3.458 j/gK (T₂ - 298.2 K) (the specific heat capacity of the final solution is 3.458 J/gK)
(T₂ - 298.2 K) = 95300 J / 1060 × 3.458 = 26 K
T₂ = 298.2 K + 26 K
T₂ = 324.2 K or 324.2 - 273 = 51.2 degree C.