Answer:
See explanation
Explanation:
We have to start, remembering the mechanism behind the McLafferty rearrangement. The hydrogen in the gamma carbon (in this case, carbon 5) would be removed by a heterolytic rupture due to the cation-radical placed in the oxygen of the carbonyl group. Then we will have several heterolytic ruptures. Between carbons alpha and beta (in this case, 4 and 3) and a rupture in the carbonyl group. Due to these ruptures, two double bonds would be formed. One double bond in the alcohol cation-radical and the other one in the alkene.
See figure 1
I hope it helps!
Assume that a nickel weighs exactly 5.038650 g for the sets of weights listed below obtained by a single weighing on the balance below
Answer:
afshkkyfugutuiryfyi
Sample gas has a volume of 3.40 L at 10°C what will be its volume at 100°C pressure remaining constant
Answer:
V2 = 4.48L
Explanation:
using charles law
V1/T1=V2/T2
3.4/283=V2/373
0.012=V2/373
V2= 0.012 x 373
V2 = 4.48L
Question 14 of 25
What type of reaction is BaCl2 + Na,504 → 2NaCl + Baso,?
A. Single-replacement
B. Synthesis
C. Double-replacement
D. Decomposition
double displacement
bcoz each of the reactants combines with other reactants to obtain the product
For each of the processes, determine whether the entropy of the system is increasing or decreasing. The system is underlined.
1. a snowman melts on a spring day
2. a document goes through a paper shredder
3. a water bottle cools down in a refrigerator
4. silver tarnishes
5. dissolved sigar precipitates out of water to form rock candy
A. Entropy is increasing
B. Entropy is decreasing
Entropy is INCREASING when a snowman melts, a document goes through paper shredder, silver tarnishes, while it is DECREASING when dissolved sugar precipitates, water vapor forms droplets and water cools down.
Entropy can be defined as the degree of randomness or disorder of a particular system.
Entropy is equal to zero (0) for a perfectly ordered system.
Heat increases the entropy of the system because more energy excites the molecules and it increases the amount of random activity.
Moreover, the cooling decreases the entropy of the system because molecules are more ordered and it decreases the amount of random activity.
In conclusion, entropy is INCREASING when a snowman melts, a document goes through paper shredder, silver tarnishes, while it is DECREASING when dissolved sugar precipitates, water vapor forms water droplets and the water cools down.
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oxygen get stable configuration by ____________two electrons
please give the answer as fast as you can
please
Answer:
gaining two electrons
Explanation:
electron configuration
2:6
so add two to 6 to get stable 2:8
The following reaction is part of the electron transport chain. Complete the reaction and identify which species is reduced. The abbreviation Q represents coenzyme Q. Use the appropriate abbreviation for the product.
FADH2+Q→
The reactant that is reduced is: _____
Answer:
[tex]FADH_2+Q --> FAD + QH_2[/tex]
The reactant that is reduced is Q.
Explanation:
The complete equation for the reaction is such that:
[tex]FADH_2+Q --> FAD + QH_2[/tex]
Two molecules of H atom is lost from [tex]FADH_2[/tex] and the H atoms are gained by the coenzyme Q. Consequently, [tex]FADH_2[/tex] becomes FAD while Q becomes [tex]QH_2[/tex].
From the definition of oxidation as loss of hydrogen and reduction as the addition of hydrogen, it can be concluded that the FADH2 that lost hydrogen is a reactant that is oxidized while the coenzyme Q that gained hydrogen is a reactant that is reduced in the reaction.
Sulfuric acid is commonly used as an electrolyte in car batteries. Suppose you spill some on your garage floor. Before cleaning it up, you wisely decide to neutralize it with sodium bicarbonate (baking soda) from your kitchen. The reaction of sodium bicarbonate and sulfuric acid is
Answer:
The mass of NaHCO3 required is 235.22 g
Explanation:
*******
Continuation of Question:
2NaHCO3(s) + H2SO4(aq) → Na2SO4(aq) + 2CO2(g) + 2H2O(l)
You estimate that your acid spill contains about 1.4 mol H2SO4. What mass of NaHCO3 do you need to neutralize the acid?
********\
The question requires us to calculate the mass of NaHCO3 to neutralize the acid.
From the balanced chemical equation;
1 mol of H2SO4 requires 2 mol of NaHCO3
1.4 would require x?
Upon solving for x we have;
x = 1.4 * 2 = 2.8 mol of NaHCO3
The relationship between mass and number of moles is given as;
Mass = Number of moles * Molar mass
Mass = 2.8 mol * 84.007 g/mol
Mass = 235.22 g
What is the empirical formula for the compound: C8H8S2?
Answer:
Empirical formula = C4H4SExplanation:
The subscripts in a formula determine the ratio of the moles of each element in the compound. To convert this formula to the empirical formula, divide each subscript by 2. This is similar to reducing a fraction to its lowest denominator.
How many moles of aqueous magnesium ions and chloride ions are formed when 0.250 mol of magnesium chloride dissolves in water
Answer:
0.250 mol Mg²⁺
0.500 mol Cl⁻
Explanation:
Magnesium chloride (MgCl₂) dissociates into ions according to the following equilibrium:
MgCl₂ ⇒ Mg²⁺ + 2 Cl⁻
1 mol 1 mol 2 mol
1 mol of Mg²⁺ and 2 moles of Cl⁻ are formed per mole of MgCl₂. If we have 0.250 mol of MgCl₂, the following amounts of ions will be formed:
0.250 mol MgCl₂ x 1 mol Mg²⁺/mol MgCl₂= 0.250 mol Mg²⁺
0.250 mol MgCl₂ x 2 mol Cl⁻/mol MgCl₂= 0.500 mol Cl⁻
Answer:
HEY THE ANSWER ABOVE ME IS RIGHT!! i defientely misclicked my rating :/
5/5 all the way.
Explanation:
1. Suppose 1.00 g of NaOH is used to prepare 250 mL of an NaOH solution. Compare the expected molarity of this solution to the actual average molarity you measured in the standardization. What do you notice
Answer:
0.1M solution of NaOH
Explanation:
1 mole of NaOH - 40g
? moles - 1 g = 1/40 = 0.025 moles.
Molarity of 1.00g of NaOH in 0.25L (250 mL) = no. of moles/volume
= 0.025/0.25
= 0.1M.
Answer all to the best of your ability please
Answer:
2–Ethyl–3–methlypentanal.
Explanation:
To name the compound given in the question above, we must observe the following:
1. The functional group of the compound is Alkanal i.e Aldehyde,
—CHO and it is located at carbon 1.
Note: the aldehyde functional group is always at carbon 1 and there will be no need to state it's position in the compound.
2. The longest continuous carbon chain is 5 i.e pentane. But the presence of the functional group will replace the –e at the end of pentane with –al, making the name to the pentanal.
3. The substituents attached are:
a. Ethyl, CH2CH3 at carbon 2.
b. Methyl, CH3 at carbon 3.
4. Combine the above to get the name of the compound.
Therefore, the name of the compound is:
2–Ethyl–3–methlypentanal.
If D+2 would react with E-1, what do you predict to be the formula?
Answer:
DE2
Explanation: for every one D+2 you need two E-1 because +2=-2
The reaction, 2 SO3(g) <--> 2 SO2(g) + O2(g) is endothermic. Predict what will happen if the temperature is increased.
Explanation:
This reaction is in equilibrium and would hence obey lechatelier's principle. This principle states that whenever a system at equilibrium undergoes a change, it would react in way so as to annul that change.
Since it is an endothermic reaction, increasing the temperature would cause the reaction to shift towards the right.
This means that it favours product formation and more of the product would be formed.
A 400 mL sample of hydrogen gas is collected over water at 20°C and 760 torr the vapor pressure of water at 20°C is 17.5 torr. what volume will the dry hydrogen gas occupy at 20°C and 760 torr?
Answer:
V2 = 17371.43ml
Explanation:
We use Boyles laws
since temperature is constant
P1V1=P2V2
760 x 400 = 17.5 x V2
304000 = 17.5 x V2
V2 = 304000/17.5
V2 = 17371.43ml
The volume will the dry hydrogen gas occupy at the temperature of 20°C and vapor pressure at 760 torrs will be 18 ml.
What is vapor pressure?
The vapor pressure of a liquid is independent of the volume of liquid in the container, whether one liter or thirty liters; both samples will have the same vapor pressure at the same temperature.
The temperature has an exponential connection with vapor pressure, which means that as the temperature rises, the vapor pressure rises as well the equation is -
P1 V1 / T1 = P2 V2 / T1
here, P = pressure
T = temperature
V = volume
substituting the value in the equation,
400 ×760 / 20 = 17.5× V / 20
V = 400× 760 / 20 × 17.5 / 20
V = 18 ml
Therefore the volume of the hydrogen gas remaining at this temperature will be 18 ml.
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A chemist adds of a mercury(I) chloride solution to a reaction flask. Calculate the micromoles of mercury(I) chloride the chemist has added to the flask.
Answer:
3.383x10⁻³ micromoles of HgCl
Explanation:
The chemist adds 170mL of a 1.99x10⁻⁵mmol/L Mercury (I) chloride, HgCl.
The solution contains 1.99x10⁻⁵milimoles of HgCl in 1L. That means in 170mL = 0.170L there are:
0.170L × (1.99x10⁻⁵milimoles HgCl / L) = 3.383x10⁻⁶ milimoles of HgCl.
Now, in 1milimole you have 1000 micromoles. That means in 3.383x10⁻⁶ milimoles of HgCl you have:
3.383x10⁻⁶ milimoles of HgCl ₓ (1000micromoles / 1milimole) =
3.383x10⁻³ micromoles of HgClIf the H+ concentration is 0.00001 M, what is the OH- concentration?
Answer:
1.00x10^-9
Explanation:
Suppose of copper(II) acetate is dissolved in of a aqueous solution of sodium chromate. Calculate the final molarity of copper(II) cation in the solution. You can assume the volume of the solution doesn't change when the copper(II) acetate is dissolved in it. Round your answer to significant digit.
Answer:
Molarity Cu²⁺ = 0.423M Cu²⁺
Explanation:
40.8g of copper (II) acetate into 200mL of a 0.700M sodium chromate
The reaction of copper acetate with sodium chromate occurs as follows:
Cu(CH₃COO)₂(aq) + Na₂CrO₄(aq) → CuCrO₄(s) + 2CH₃COONa
In water, the Copper(II) acetate dissociates in Cu²⁺ cation.
To know final molarity of Cu²⁺ we need to calculate the moles of Cu²⁺ that don't react with chromate ion, thus:
Moles of 40.8g of copper(II) acetate (Molar mass: 181.63g/mol) are:
40.8g × (1mol / 181.63g) = 0.2246 moles of Copper(II) acetate
Moles of sodium chromate are:
0.200L ₓ (0.700mol / L) = 0.140 moles of sodium chromate.
As 1 mole of Copper(II) acetate reacts per mole of sodium chromate, moles of Copper(II) acetate = Moles of Cu²⁺ that remains after the reaction are:
0.2246mol - 0.140moles = 0.0846 moles of Cu²⁺
Molarity is ratio between moles of solute (Moles Cu²⁺) and volume in liters of solution (200mL = 0.200L):
Molarity Cu²⁺ = 0.0846 moles / 0.200L
Molarity Cu²⁺ = 0.423M Cu²⁺question attached ! asap please
Answer:
A. copper is highly water soluble. It will turn into 5 different hydrates as it absorbs more and more water.
b. Glycerol is easily soluble in water, due to the ability of the polyol groups to form hydrogen bonds with water molecules
c. octane is considered to be non-polar, it will not be soluble in water, since water is a polar solvent. This will happen because octane (hydrocarbons in general) contains neither ionic groups, nor polar functional groups that can interact with water molecules.
d. Nitric acid decomposes into water, nitrogen dioxide, and oxygen, forming a brownish yellow solution.
e. Barium carbonate is a white powder. It is insoluble in water and soluble in most acids
Explanation:
2
22. A sodium chloride solution is 15.0% m/m%. Calculate mass of sodium chloride in 219 g solution.
14.2g
80.38
11.2 g
32.9 g
Answer: The mass of sodium chloride in 219 g solution is 32.9 g
Explanation:
To calculate the mass percent of element in a given compound, we use the formula:
[tex]\text{Mass percent of A}=\frac{\text{Mass of A}}{\text{mass of A +mass of B}}\times 100[/tex]
To find mass of sodium chloride in solution:
[tex]\text{Mass percent of sodium chloride}=\frac{\text{Mass of sodium chloride}}{\text{mass of solution}}\times 100[/tex]
Mass percent of sodium chloride= 15.0 %
Mass of solution = 219g
[tex]15=\frac{\text{Mass of sodium chloride}}{219}\times 100[/tex]
[tex]{\text{Mass of sodium chloride}=32.9g[/tex]
Thus mass of sodium chloride in 219 g solution is 32.9 g
Calculate the amount of heat energy, in kJ, needed to increase the temperature of 200g of water by 300 C.
Answer:
Q = 246 kJ
Explanation:
It is given that,
Mass of water, m = 200 g
Let initial temperature, [tex]T_i=5^{\circ}[/tex]
Final temperature of water, [tex]T_f=300^{\circ} C[/tex]
We know that the specific heat capacity of water, [tex]c=4.18\ J/g-^{\circ} C[/tex]
So, the heat energy needed to raise the temperature is given by :
[tex]Q=mc\Delta T\\\\Q=200\times 4.18\times (300-5)\\\\Q=246620\ J[/tex]
or
Q = 246 kJ
So, the heat energy of 246 kJ is needed.
Explain why o-vanillin does not fully protonate p-toluidine. Reference appropriate pKa values and include a balanced chemical reaction and an appropriate reaction arrow in your answer.
Answer:
Here's what I get
Explanation:
pKₐ of o-vanillin = 7.81; pKₐ of p-toluidine = 4.44
The higher the pKₐ, the weaker the acid.
Thus, o-vanillin is the weaker acid and has a stronger conjugate base.
The conjugate acid of p-toluidine is the stronger and has the weaker conjugate base.
The equation for the equilibrium is
H-OC₆H₃(OCH₃)CHO + CH₃C₆H₄NH₂ ⇌ ⁻OC₆H₃(OCH₃)CHO + CH₃C₆H₄NH₃⁺
weaker acid weaker base stronger base stronger acid
The reaction between the stronger acid and the stronger base pushes the position of equilibrium to the left.
Thus, o-vanillin does not fully protonate p-toluidine.
O-vanillin is a weaker acid than p-toluidine and has a more stable conjugate base; hence, o-vanillin does not fully protonate p-toluidine.
The pKa is defined as the negative logarithm of Ka. The dissociation constant of an acid Ka shows the extent of dissociation of an acid in solution. The higher the pKa, the lower the Ka and the weaker the acid.
The pKₐ of o-vanillin is 7.81 while the pKₐ of p-toluidine is 4.44. This means that o-vanillin is a weaker acid than p-toluidine and has a more stable conjugate base. Hence, o-vanillin does not fully protonate p-toluidine.
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Find the [OH−] of a 0.32 M methylamine (CH3NH2) solution. (The value of Kb for methylamine (CH3NH2) is 4.4×10−4.) Express your answer to two significant figures and include the appropriate units.
Answer:
[tex][OH^-]=0.01165M[/tex]
Explanation:
Hello,
In this case, for the dissociation of methylamine:
[tex]CH_3NH_2(aq)+H_2O(l)\rightleftharpoons CH_3NH_3^+(aq)+OH^-(aq)[/tex]
We can write the basic dissociation constant as:
[tex]Kb=\frac{[CH_3NH_3^+][OH^-]}{[CH_3NH_2]}[/tex]
That in terms of the reaction extent [tex]x[/tex], turns out:
[tex]Kb=\frac{x*x}{[CH_3NH_2]_0-x}[/tex]
[tex]4.4x10^{-4}=\frac{x^2}{0.32M-x}[/tex]
That has the following solution for [tex]x[/tex]:
[tex]x_1=-0.01209M\\x_2=0.01165M[/tex]
Yer 0.01165M is valid only as no negative concentrations are eligible. It means that it is the concentration of hydroxyl ions in the solution:
[tex][OH^-]=0.01165M[/tex]
Best regards.
Which of the following is an alkaline earth metal?
A. Silicon (Si)
B. Magnesium (Mg)
C. Carbon (C)
D. Aluminum (AI)
Answer:
B
Explanation:
The alkaline earth metals are the elements located in Group 2. The only element out of our choices that is in Group 2 is Magnesium.
Using the Bohr model, determine the lowest possible energy, in joules, for the electron in the Li2+ ion.
Answer: E = - 19.611×[tex]10^{-18}[/tex] J
Explanation: The lowest possible energy can be calculated using the formula:
[tex]E_{n} = - Z^{2}.\frac{k}{n^{2}}[/tex]
where:
Z is atomic number of the atom;
k is a constant which contains other constants and is 2.179×[tex]10^{-18}[/tex] J
n is a layer;
For the lowest possible, n=1.
Atom of Lithium has atomic number of Z=3
Substituing:
[tex]E_{1} = - 3^{2}.\frac{2.179.10^{-18}}{1}[/tex]
[tex]E_{1} =[/tex] [tex]-19.611.10^{-18}[/tex] J
The energy for the electron in the [tex]Li^{+2}[/tex] ion is - 19.611 joules
The lowest possible energy, in Joules, for the electron in the [tex]Li^{2+}[/tex] ion is equal to [tex]1.96\times 10^{-17}\; Joules[/tex]
To determine the lowest possible energy, in Joules, for the electron in the [tex]Li^{2+}[/tex] ion, we would use the Bohr model:
Mathematically, Bohr's model is given by the equation:
[tex]Energy = -Z^2 \frac{k}{n^2}[/tex]
Where:
Z is the atomic number of an atom.n is the number of energy level.k is Rydberg constant.We know that the atomic number of lithium (Li) is equal to 3.
Also, at the lowest possible energy, n = 1.
Rydberg constant = [tex]2.179 \times 10^{-18}[/tex]
Substituting the parameters into the equation, we have;
[tex]E_1 = -3^2 \times \frac{2.179 \times 10^{-18}}{1^2} \\\\E_1 =9 \times 2.179 \times 10^{-18}\\\\E_1 =1.96\times 10^{-17}\; Joules[/tex]
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Determine the volume occupied by 10 mol of helium at
27 ° C and 82 atm
Answer:
3.00 L
Explanation:
PV = nRT
(82 atm × 101325 Pa/atm) V = (10 mol) (8.314 J/mol/K) (27 + 273) K
V = 0.00300 m³
V = 3.00 L
Given a fixed amount of gas help at a constant pressure, calculate the temperature to which the gas would have to be changed if a 1.75 L sample at 23.0*C were to have a final volume of 3.50 L.
A. 46.0*C
B. 89.5*C
C. 169*C
D. 319*C
E. 592*C
Answer:
592 K or 319° C
Explanation:
From the statement of Charles law we know that the volume of a given mass of gas is directly proportional to its absolute temperature at constant pressure. Thus;
V1/T1= V2/T2
Initial volume V1 = 1.75 L
Initial temperature T1= 23.0 +273 = 296 K
Final volume V2= 3.50 L
Final temperature T2 = the unknown
T2= V2T1/V1= 3.50 × 296 / 1.75
T2 = 592 K or 319° C
Given a fixed amount of gas in a rigid container (no change in volume), what pressure will the gas exert if the pressure is initially 1.50 atm at 22.0oC, and the temperature is changed to 11.0oC?
A. 301 atm
B. 1.56 atm
C. 0.750 atm
D. 1.44 atm
E. 3.00 atm
Answer:
The pressure the gas will have if the pressure is initially 1.50 atm at 22.0 ° C and the temperature changes at 11.0 ° C is 1.44 atm (option D)
Explanation:
Gay Lussac's law indicates that, as long as the volume of the container containing the gas is constant, as the temperature increases, the gas molecules move more rapidly. Then the number of collisions against the walls increases, that is, the pressure increases. That is, the gas pressure is directly proportional to its temperature.
Gay-Lussac's law can be expressed mathematically as follows:
[tex]\frac{P}{T}=k[/tex]
Where P = pressure, T = temperature, K = Constant
You have a gas that is at a pressure P1 and at a temperature T1. When the temperature varies to a new T2 value, then the pressure will change to P2, and then:
[tex]\frac{P1}{T1}=\frac{P2}{T2}[/tex]
In this case:
P1= 1.50 atmT1= 22 °C= 295 °K (being 0°C= 273 °K)P2= ?T2= 11 °C= 284 KReplacing:
[tex]\frac{1.5 atm}{295 K}=\frac{P2}{284 K}[/tex]
Solving:
[tex]P2= 284 K*\frac{1.5 atm}{295 K}[/tex]
P2=1.44 atm
The pressure the gas will have if the pressure is initially 1.50 atm at 22.0 ° C and the temperature changes at 11.0 ° C is 1.44 atm (option D)
Calculate the heat absorbed by a sample of water that has a mass of 45.00 g when the temperature increases from 21.0oC to 38.5 oC. (s=4.184 J/g.o C)
Answer:
The heat absorbed by the sample of water is 3,294.9 J
Explanation:
Calorimetry is the measurement and calculation of the amounts of heat exchanged by a body or a system.
The sensible heat of a body is the amount of heat received or transferred by a body when it undergoes a temperature variation (Δt) without there being a change of physical state (solid, liquid or gaseous). Its mathematical expression is:
Q = c * m * ΔT
Where Q is the heat exchanged by a body of mass m, made up of a specific heat substance c and where ΔT is the temperature variation.
In this case:
Q=?m= 45 gc= 4.184 [tex]\frac{J}{g*C}[/tex]ΔT= Tfinal - Tinitial= 38.5 C - 21 C= 17.5 CReplacing:
Q= 4.184 [tex]\frac{J}{g*C}[/tex] * 45 g* 17.5 C
Solving:
Q=3,294.9 J
The heat absorbed by the sample of water is 3,294.9 J
Calculate the mass percent of .485g of H, which reacts with O to form 2.32g H2O?
Answer:
53.1% of hydrogen reacts
Explanation:
The mixture of 2 atoms of H with 1 atom of O produce 1 molecule of H₂.
The mass of hydrogen in 2.32g of H₂O could be obtained using molar mass of H₂O (18.01g/mol) and molar mass of hydrogen (1.01g/mol) as follows:
Moles H₂O: 2.32g H₂O × (1mole / 18.01g) = 0.1288 moles of water
1 mole of H₂O contains 2 moles of H, moles of hydrogen in 0.1288 moles of water are:
0.1288 moles H₂O × (2 moles H / 1 mole H₂O) = 0.2576 moles of H
In mass:
0.2576 moles H × (1.01g/ mol H) = 0.260g H you have in the formed water
As before reaction you had 0.485g of H and just 0.260g reacted, mass percent is:
(Mass that reacts / Mass added) × 100
(0.260g / 0.485g) × 100 =
53.1% of hydrogen reactsWhich of the following solutions would have the highest pH? Assume that they are all 0.10 M in acid at 25°C. The acid is followed by its Ka value.
a. HCHO2, 1.8 x 10-4
b. HF, 3.5 x 10-4
c. HClO2, 1.1 x 10-2
d. HCN, 4.9 x 10-10
e. HNO2, 4.6 x 10-4
Answer:
[tex]HCN~~Ka=4.9x10^-^1^0[/tex]
Explanation:
In this case, we have to remember the relationship between the Ka value and the pH. We can use the general reaction for any acid with his Ka value expression:
[tex]HA~->~H^+~+~A^-[/tex] [tex]Ka=\frac{[H^+][A^-]}{[HA]}[/tex]
In the Ka expression, we have a proportional relationship between Ka and the concentration of [tex]H^+[/tex]. Therefore, if we have a higher Ka value we will have a smaller pH (lets keep in mind that with a higher
So, if we have to find the higher pH value we need to search the smaller Ka value in this case [tex]HCN~~Ka=4.9x10^-^1^0[/tex].
I hope helps!
HCN has the highest pH among all the acids listed in the question.
The Ka is called the acid dissociation constant. It shows the extent to which an acid is ionized in water. The pH shows the hydrogen ion concentration of water. The higher the Ka, the higher the hydrogen ion concentration and the lower the pH.
Hence, HCN has the lowest Ka and the lowest hydrogen ion concentration. Therefore, HCN has the highest pH among all the acids listed in the question.
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