Calculate Delta G for each reaction using Delta Gf values: answer kJ ...thank you

a) H2(g)+I2(s)--->2HI(g)

b) MnO2(s)+2CO(g)--->Mn(s)+2CO2(g)

c) NH4Cl(s)--->NH3(g)+HCl(g)

Answer:

0.3 mol

Explanation:

Assuming HCl is in excess and Zn is the limiting reagent,

from the balanced equation, we can see the mole ratio of Zn:H2 = 1:1,

which means, each mole of zinc reacted gives 1 mole of H2.

So, if 0.30 mol Zn is added, the no. of moles of H2 produced will also be 0.3 mol, since the ratio is 1:1.

Answer:

Molar mass of the gas is 0.0961 g/mol

Explanation:

The effusion rate of an unknown gas = 11.1 min

rate of [tex]H_{2}[/tex] effusion = 2.42 min

molar mass of hydrogen = 1 x 2 = 2 g/m

molar mas of unknown gas = ?

From Graham's law of diffusion and effusion, the rate of effusion and diffusion is inversely proportional to the square root of its molar mass.

from

[tex]\frac{R_{g} }{R_{h} }[/tex] = [tex]\sqrt{\frac{M_{h} }{M_{g} } }[/tex]

where

[tex]R_{h}[/tex] = rate of effusion of hydrogen gas

[tex]R_{g}[/tex] = rate of effusion of unknown gas

[tex]M_{h}[/tex] = molar mass of H2 gas

[tex]M_{g}[/tex] = molar mass of unknown gas

substituting values, we have

[tex]\frac{11.1 }{2.42 }[/tex] = [tex]\sqrt{\frac{2 }{M_{g} } }[/tex]

4.587 = [tex]\sqrt{\frac{2 }{M_{g} } }[/tex]

[tex]\sqrt{M_{g} }[/tex] = [tex]\sqrt{2}[/tex]/4.587

[tex]\sqrt{M_{g} }[/tex] = 0.31

[tex]M_{g}[/tex] = [tex]0.31^{2}[/tex] = 0.0961 g/mol

The molar mass of the unknown gas will be "0.0961 g/mol".

Given:

Effusion rate of unknown gas,

Effusion rate of [tex]H_2[/tex],

Molar mass of hydrogen,

              [tex]= 2 \ g/m[/tex]

According to the Graham's law, we get

→    [tex]\frac{R_g}{R_h} = \sqrt{\frac{M_h}{M_g} }[/tex]

By substituting the values, we get

→   [tex]\frac{11.1}{2.42} = \sqrt{\frac{2}{M_g} }[/tex]

→ [tex]4.587=\sqrt{\frac{2}{M_g} }[/tex]

→ [tex]\sqrt{M_g} = \sqrt{\frac{2}{4.587} }[/tex]

   [tex]\sqrt{M_g} = 0.31[/tex]

       [tex]M_g = 0.0961 \ g/mol[/tex]

Thus the above solution is right.          

Learn more:

https://brainly.com/question/6019799

Answer:

An alkyl halide can undergo SN2 reaction with an amine

Explanation:

The displacement of a bromine atom by an an amine (step 2---> 3) in the reaction sequence is an example of an SN2 reaction in which the amine is the nucleophile.

The nitrogen atom of the amine which bears a lone pair of electrons functions as the nucleophile and attacks the electrophilic carbon atom of the alkyl halide displacing the bromide and creating a new Carbon-Nitrogen bond. An ammonium intermediate is immediately formed and the reaction is completed by the abstraction of a hydrogen by a base (such as excess amine present in the system).

This reaction is slower with t-BuNH2 because of steric hindrance and steric crowding in the transition state. SN2 reactions are faster with methylamine where the alkyl carbon is easily accessible.

The detailed mechanism of this reaction has been attached to this answer.

Answer:

4NH₃(g)  + 5O₂(g)  →  4NO(g)  +  6H₂O

2NO(g) + O₂(g) → 2 NO₂

Explanation:

First of all, we need to consider the reaction for production of ammonia. In this reaction we have as reactants, nitrogen and hydroge.

3H₂ (g) +  N₂(g)  →  2NH₃ (g)

Afterwards, ammonia reacts to oxygen, to produce NO and H₂O

The equation for the process will be:

4NH₃(g)  + 5O₂(g)  →  4NO(g)  +  6H₂O

Then, we take the nitric oxide to make it react, to produce NO₂, in order to produce nitric acid, for the final reaction:

2NO(g) + O₂(g) → 2 NO₂

3NO₂(g) + H₂O(g) → 2 HNO₃ (g) + NO(g)

Answer:

495nm

Explanation:

The energy of a photon could be obtained by using:

E = hc / λ

Where E is energy of a photon, h is Planck's constant (6.626x10⁻³⁴Js), c is speed of the light (3x10⁸ms⁻¹) and λ is wavelength.

The energy to break 1 mole of Cl-Cl bonds is 242kJ = 242000J. The energy yo break a single bond is:

242000J/mol ₓ (1mol / 6.022x10²³bonds) = 4.0186x10⁻¹⁹J/bond.

Replacing in the equation:

E = hc / λ

4.0186x10⁻¹⁹J = 3x10⁸ms⁻¹ₓ6.626x10⁻³⁴Js / λ

λ = 4.946x10⁻⁷m

Is maximum wavelength  of light that could break a Cl-Cl bond.

Usually, wavelength is given in nm (1x10⁻⁹m / 1nm). The wavelength in nm is:

4.946x10⁻⁷m ₓ (1nm / 1x10⁻⁹m) =

Answer:

0.373 M

Explanation:

The balanced equation for the reaction is given below:

HC2H3O2 + NaOH —> NaC2H3O2 + H2O

From the balanced equation above, the following were obtained:

Mole ratio of the acid, HC2H3O2 (nA) = 1

Mole ratio of the base, NaOH (nB) = 1

Next, we shall write out the data obtained from the question. This include:

Volume of base, NaOH (Vb) = 32.17 mL

Molarity of base, NaOH (Mb) = 0.116 M

Volume of acid, HC2H3O2 (Va) = 10 mL

Molarity of acid, HC2H3O2 (Ma) =..?

The molarity of the acid solution can be obtained as follow:

MaVa/MbVb = nA/nB

Ma x 10 / 0.116 x 32.17 = 1

Cross multiply

Ma x 10 = 0.116 x 32.17

Divide both side by 10

Ma = (0.116 x 32.17) /10

Ma = 0.373 M

Therefore, the concentration of the acetic acid is 0.373 M.

Answer:

1. REDOX

2. None of the above

3. Precipitation

4. Preicipitation

5. Acid base neutralization

Explanation:

Reactions where a solid is formed, are named as precipitation. This solid is called precipitated.

Option 4 and 3.

3) CaO (s) + CO₂ (g) →  CaCO₃(s)

4) KOH (aq)  + AgCl (aq)  →  KCl (aq)  + AgOH(s)

Reactions where water is produced, and you have an acid and a base as reactants, are named as neutralization. You called them acid-base because, the products.

5) Ba(OH)₂ (aq)  +  2HNO₂(aq)  →  Ba(NO₂)₂ (aq) + 2H₂O(l)

Redox, are the reactions where one of the reactans can be oxidized and reduced, when a mole of electrons is released, or gained.

1) Ba(ClO₃)₂ (s)  → BaCl₂ (s) +  3O₂(g)

Oxygen from the chlorate is oxidized (increases the oxidation state from -2 to 0) and the chlorine is reduced (decreases the oxidation state from +5 to -1).

2.  2NaCl(aq)  +  K₂S(aq)  Na₂S (aq)  + 2KCl (aq)

None of the above

Answer:

0.0913 M

Explanation:

We'll begin by writing the balanced equation for the reaction.

This is given below:

H2C3H2O4 + 2NaOH —> C3H2Na2O4 + 2H2O

From the balanced equation above, we obtained the following:

The mole ratio of the acid (nA) = 1

The mole ratio of the base (nB) = 2

Data obtained from the question include:

Molarity of base, NaOH (Mb) = 0.0990 M

Volume of base, NaOH (Vb) = 20.52 mL

Volume of acid, H2C3H2O4 (Va) = 11.13 mL

Molarity of acid, H2C3H2O4 (Ma) =..?

The molarity of the acid, H2C3H2O4 can be obtained as follow:

MaVa/MbVb = nA/nB

Ma x 11.13 / 0.0990 x 20.52 = 1/2

Cross multiply

Ma x 11.13 x 2 = 0.0990 x 20.52 x 1

Divide both side by 11.13 x 2

Ma = (0.0990 x 20.52)/ (11.13 x 2)

Ma = 0.0913 M

Therefore, the molarity of malonic acid, H2C3H2O4 solution is 0.0913 M

Answer:

(1) Before the addition of any HBr, the pH is 12.02

(2) After adding 12.0 mL of HBr, the pH is 10.86

(3) At the titration midpoint, the pH is 10.73

(4) At the equivalence point, the pH is 5.79

(5) After adding 45.1 mL of HBr, the pH is 1.18

Explanation:

First of all, we have a weak base:

(CH₃)₂NH  + H₂O  ⇄  (CH₃)₂NH₂⁺  +  OH⁻            Kb = 5.4×10⁻⁴

0.289 - x                             x                x

Kb = x² / 0.289-x

Kb . 0.289 - Kbx - x²

1.56×10⁻⁴ - 5.4×10⁻⁴x - x²

After the quadratic equation is solved x = 0.01222 → [OH⁻]

- log  [OH⁻] = pOH → 1.91

pH = 12.02   (14 - pOH)

We determine the mmoles of H⁺, we add:

0.286 M . 12 mL = 3.432 mmol

We determine the mmoles of base⁻, we have

27.9 mL . 0.289 M = 8.0631 mmol

When the base, react to the protons, we have the protonated base plus water (neutralization reaction)

(CH₃)₂NH     +      H₃O⁺        ⇄  (CH₃)₂NH₂⁺  +  H₂O

8.0631 mm       3.432 mm                 -

4.6311 mm                                  3.432 mm

We substract to the dimethylamine mmoles, the protons which are the same amount of protonated base.

[(CH₃)₂NH] → 4.6311 mm / Total volume (27.9 mL + 12 mL) = 0.116 M

[(CH₃)₂NH₂⁺] → 3.432 mm / 39.9 mL = 0.0860 M

We have just made a buffer.

pH = pKa + log (CH₃)₂NH  / (CH₃)₂NH₂⁺

pH = 10.73 + log (0.116/0.0860) = 10.86

mmoles of base = mmoles of acid

Let's find out the volume

0.289 M . 27.9 mL = 0.286 M . volume

volume in Eq. point = 28.2 mL

(CH₃)₂NH     +      H₃O⁺        ⇄  (CH₃)₂NH₂⁺  +  H₂O

8.0631 mm       8.0631mm               -

                                                8.0631 mm

We do not have base and protons, we only have the conjugate acid

We calculate the new concentration:

mmoles of conjugated acid / Total volume (initial + eq. point)

[(CH₃)₂NH₂⁺] = 8.0631 mm /(27.9 mL + 28.2 mL)  = 0.144 M

(CH₃)₂NH₂⁺   +  H₂O   ⇄   (CH₃)₂NH  +  H₃O⁻       Ka = 1.85×10⁻¹¹

 0.144 - x                                  x               x

[H₃O⁺] = √ (Ka . 0.144) →  1.63×10⁻⁶ M  

pH = - log [H₃O⁺] = 5.79

This is the point where we add, the half of acid. (14.1 mL)

This is still a buffer area.

mmoles of H₃O⁺ = 4.0326 mmol (0.286M . 14.1mL)

mmoles of base = 8.0631 mmol - 4.0326 mmol

[(CH₃)₂NH] = 4.0305 mm / (27.9 mL + 14.1 mL) = 0.096 M

[(CH₃)₂NH₂⁺] = 4.0326 mm (27.9 mL + 14.1 mL) = 0.096 M

pH = pKa + log (0.096M / 0.096 M)

pH = 10.73 + log 1 =  10.73

Both concentrations are the same, so pH = pKa. This is the  maximum buffering capacity.

mmoles of acid = 45.1 mL . 0.286 M = 12.8986 mmol

mmoles of base = 8.0631 mmoles

This is an excess of H⁺, so, the new [H⁺] = 12.8986 - 8.0631 / Total vol.

(CH₃)₂NH     +      H₃O⁺        ⇄  (CH₃)₂NH₂⁺  +  H₂O

8.0631 mm     12.8986 mm             -

       -               4.8355 mm                        

[H₃O⁺] = 4.8355 mm / (27.9 ml + 45.1 ml)

[H₃O⁺] = 4.8355 mm / 73 mL → 0.0662 M

- log [H₃O⁺] = pH

- log 0.0662 = 1.18 → pH

Answer:

Explanation:

Mn( NO₃ )₂ + 2Na OH = Mn( OH)₂ (s) ↓ +  2Na NO₃

Converting into ions

Mn⁺ + 2 NO₃⁻ + 2 Na⁺ + 2 OH⁻ = Mn( OH)₂ + 2 Na⁻ + 2 NO₃⁻

Cancelling out common terms

Mn⁺ + 2 OH⁻ = Mn( OH)₂

this is net ionic equation required.

Answer:

Option A

Explanation:

Silicon (Obtained from Sand (SiO2)) is the element that is primarily used in appliances to make electronic chips.

Answer:

A. Silicon (Si)

Explanation:

Silicon (Si) is primarily used as a semiconductor material to make electronic chips.

Answer:

The process of slowly adding one solution to another until the reaction between the two is complete.

Explanation:

When you perform a titration, you are slowly adding one solution of a known concentration called a titrant to a known volume of another solution of an unknown concentration until the reaction reaches neutralization, in which the reaction is no longer taking place. This is often indicated by a color change.

Hope that helps.

Answer:

a. increase

Explanation:

Catalysis is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst, which is not consumed in the catalyzed reaction.

By default, catalysts exists to speed up the rate of reactions. Increasing the amount of catalysts means that there would be an increase in the rate of reaction. The correct option is A.

Answer:

37%

Explanation:

From the question, the equation goes does.

C2H6+ (1-x)+a(O2+3.76N2)=bC02 + cH2O + axO2 + 3.76dN2.

Mair=Mair/Rin

( MN)O2 + (MN)N2÷ (MN)O2 + (MN)N2 +(MN)C2H6.

33 . 3.25(1-x) + 28 × 13.16(1-x) ÷ 33 × 3.25(1-x) + 28 × 13.16(1-x). + 30.1

= 176/176+8

X= 0.37

0.37 × 100

X= 37%

Explanation:

Speed = 2345 ÷ 35 = 67m/s

Answer:

The mass number of the stable daughter product is 208

Explanation:

First thing's first, we have to write out the equation of the reaction. This is given as;

²³²₉₀Th → 6 ⁴₂α  +  4 ⁰₋₁ β + X

In order to obtain the identity of X, we have to obtain it's mass numbers and atomic number.

There is conservation of matter so we expect the mass number to remain the same in both the reactant and products.

Mass Number

Reactant = 232

Product = (6* 4 = 24) + (4 * 0 = 0) + x = 24 + x

since reactant = product

232 = 24 + x

x = 232 - 24 = 208

Atomic Number

Reactant = 90

Product = (6* 2 = 12) + (4 * -1 = -4) + x = 8 + x

since reactant = product

90 = 8 + x

x = 90 - 8 = 82

Answer:

100 g of water: specific heat of water 4.18 J/g°C

Explanation:

To know the correct answer to the question, we shall determine the temperature change in each case.

For 100 g of water:

Mass (M) = 100 g

Specific heat capacity (C) = 4.18 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 100 x 4.18 x ΔT

Divide both side by 100 x 4.18

ΔT = 55000/ (100 x 4.18)

ΔT = 131.6 °C

Therefore the temperature change is 131.6 °C

For 50 g of water:

Mass (M) = 50 g

Specific heat capacity (C) = 4.18 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 50 x 4.18 x ΔT

Divide both side by 50 x 4.18

ΔT = 55000/ (50 x 4.18)

ΔT = 263.2 °C

Therefore the temperature change is 263.2 °C

For 50 g of lead:

Mass (M) = 50 g

Specific heat capacity (C) = 0.128 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 50 x 0.128 x ΔT

Divide both side by 50 x 0.128

ΔT = 55000/ (50 x 0.128)

ΔT = 8593.8 °C

Therefore the temperature change is 8593.8 °C.

For 100 g of iron:

Mass (M) = 100 g

Specific heat capacity (C) = 0.449 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 100 x 0.449 x ΔT

Divide both side by 100 x 0.449

ΔT = 55000/ (100 x 0.449)

ΔT = 1224.9 °C

Therefore the temperature change is 1224.9 °C.

The table below gives the summary of the temperature change of each substance:

Mass >>> Substance >> Temp. Change

100 g >>> Water >>>>>> 131.6 °C

50 g >>>> Water >>>>>> 263.2 °C

50 g >>>> Lead >>>>>>> 8593.8 °C

100 g >>> Iron >>>>>>>> 1224.9 °C

From the table given above we can see that 100 g of water has the smallest temperature change.

Answer:

b. Binary compounds of carbon and hydrogen

Explanation:

Before proceeding, Hydrocarbons refers to organic chemical compounds composed exclusively of hydrogen and carbon atoms. This means the only elements present in an hydrocarbon are;

- Carbon

- Hydrogen

Looking through the options;

- Option A: This is wrong because the hydroxyl group contains oxygen and hydrocarbons contain only hydrogen and carbon.

- option B: This is correct. Binary compounds refers to compounds with just two elements.

- option C: This is wrong because water contains oxygen and hydrocarbons contain only hydrogen and carbon.

- option D: Carbon atoms can contain other elements so this option is wrong.

- option E: This also wrong because we had already gotten the correct option.

Answer:

It will take 6486.92 minutes  for [H2O2] to fall from 0.95 M to 0.33 M

Explanation:

The order of reaction is defined as the sum of the powers of the concentration terms in the equation. Order of a reaction is given by the number of atoms or molecule whose concentration change during the reaction and determine the rate of reaction.

In first order reaction;

[tex]In \dfrac{a}{a_o-x}= k_1 t[/tex]

where;

a = concentration at time t

[tex]a_o[/tex] = initial concentration

and k = constant.

[tex]In (\dfrac{0.33}{0.95})= -1.63 \times 10^{-4} \times t[/tex]

[tex]-1.05736933 = -1.63 \times 10^{-4} \times t[/tex]

[tex]t = \dfrac{-1.05736933}{ -1.63 \times 10^{-4} }[/tex]

t = 6486.92 minutes

Answer:

aldehyde

carbon-1

ketone

carbon-2

Explanation:

Monosaccharides are colorless crystalline solids that are very soluble in water. Moat have a swwet taste. D-Fructose is the sweetest monosaccharide.

In the open chain form, monosaaccharides have a carbonuyl group in one of their chains. If the carbonyl group is in the form of an aldehyde group, the monosaccharide is an aldose; if the carbonyl group is in the form of a ketone group, the monosaccharide is known as a ketose. glucose is an aldose while fructose is a ketose.

In D-glucose, there is an aldehyde functional group, and the carbonyl group is at carbon-1 when looking at the Fischer projection.

In D-fructose, there is a ketone functional group, and the carbonyl group is at carbon-2 when looking at the Fischer projection.

Answer:

The answer to this question can be defined as follows:

In question 1, the answer is "Option A".

In question 2, the answer is "[tex]\bold{CH_3COOH}[/tex]".

Explanation:

In the second question, there is mistype error in the choices so the correct answer to this question can be defined as follows:

Answer:

3.00 L

Explanation:

Convert the pressure to Pascals.

P = 82 atm × (101325 Pa/atm)

P = 8,308,650 Pa

Convert temperature to Kelvins.

T = 27°C + 273

T = 300 K

Use ideal gas law:

PV = nRT

(8,308,650 Pa) V = (10 mol) (8.314 J/mol/K) (300 K)

V = 0.00300 m³

If desired, convert to liters.

V = (0.00300 m³) (1000 L/m³)

V = 3.00 L

Answer:

[tex]\large \boxed{\text{3.0 L}}[/tex]

Explanation:

[tex]\begin{array}{rcl}pV &=& nRT\\\text{82 atm} \times V & = & \text{10 mol} \times \text{0.082 06 L}\cdot\text{atm}\cdot\text{K}^{-1}\text{mol}^{-1} \times \text{300.15 K}\\82V & = & \text{246 L}\\V & = & \textbf{3.0 L} \\\end{array}\\\text{The volume of the balloon is $\large \boxed{\textbf{3.0 L}}$}[/tex]

A heterogeneous mixture​

Answer:

0.900 V

Explanation:

Oxidation half cell;

2Al(s) -----> 2Al^3+(aq) + 6e

Reduction half equation;

3Zn^2+(aq) + 6e ----> 3Zn(s)

E°anode = -1.66V

E°cathode= -0.76 V

E°cell= E°cathode - E°anode

E°cell= -0.76-(-1.66)

E°cell= 0.900 V

Answer:

Osmolarity of solution of KCI = 0.40 osmol

Explanation:

Given:

KCL ⇒ K⁺ + Cl⁻

Find:

Osmolarity of solution of KCI

When M = 0.20 M

Computation:

1 mole of KCL = 2 osmol

1 M of KCl = 2 Osmolarity

So,

Osmolarity of solution of KCI = 2 × 0.20

Osmolarity of solution of KCI = 0.40 osmol

Answer:

The correct option is d

Explanation:

Nuclide is synonymous with groups of electrons or protons, that is, a nuclide is the grouping of nucleons.

Answer:

Graphite> sodium chloride> solid ammonia

Explanation:

Melting points of solids has a lot to do with the nature of intermolecular forces in the solid. A substance melts when the intermolecular forces holding the crystal lattice has been overcome such that that the crystal structure of the solid just collapses.

Graphite consists of covalently bonded layers of carbon atom which form a giant lattice. The melting point of graphite is very high because of the fact that the strong covalent bonds that hold the carbon atoms together in the layers require a lot of heat energy to break. Grapoghite melts at about 3600°C

Sodium chloride is an ionic compound that melts at about 801°C. The lattice is composed of alternate sodium and chloride ions.

Solid ammonia is held together by much weaker intermolecular interaction hence it has a melting point of about −77.73 °C.

Answer:

6

Explanation:

Alkanes undergo substitution reaction so the number of replacement reaction hydrogen is 6