Calculate the equilibrium concentrations of N2O4 and NO2 at 25 ∘C in a vessel that contains an initial N2O4 concentration of 0.0655 M . The equilibrium constant Kc for the reaction N2O4(g)⇌2NO2(g) is 4.64×10−3 at 25 ∘C. Express your answers using four decimal places separated by a comma.

Answers

Answer 1

Answer:

[N2O4] = 0.0573M

[NO2] = 0.0163M

Explanation:

The equilibrium of N2O4 is:

N2O4(g)⇌2NO2(g)

Where Kc is defined as:

Kc = 4.64x10⁻³ = [NO2]² / [N2O4]

When you add just N2O4, the reaction will occurs until  [NO2]² / [N2O4] = 4.64x10⁻³. Here, the system reaches equilibrium.

That means if 0.0655M N2O4 begin reaction, in equilibrium we will have:

[N2O4] = 0.0655M - X

[NO2] = 2X

Where X is defined as reaction coordinate

Replacing in Kc:

4.64x10⁻³ = [NO2]² / [N2O4]

4.64x10⁻³ = [2X]² / [0.0655-X]

3.0392x10⁻⁴ - 4.64x10⁻³X = 4X²

3.0392x10⁻⁴ - 4.64x10⁻³X - 4X² = 0

Solving for X:

X = -0.0093 → False solution. there is no negative concentrations

X = 0.008156M → Right solution.

Replacing X, equilibrium concentrations are:

[N2O4] = 0.0655M - X

[NO2] = 2X

[N2O4] = 0.0573M[NO2] = 0.0163M


Related Questions

What are the solutions to the quadratic equation 2x2 + 10x - 48 = 0?

Answers

Answer:

x = 3 , x= -8

Explanation:

[tex]2x^2+10x-48\\=2\left(x^2+5x-24\right)\\x^2+5x-24\\=\left(x^2-3x\right)+\left(8x-24\right)\\=x\left(x-3\right)+8\left(x-3\right)\\=\left(x-3\right)\left(x+8\right)\\=2\left(x-3\right)\left(x+8\right)\\2\left(x-3\right)\left(x+8\right)=0\\x-3=0\\x = 0+3\\x = 3\\x+8=0\\x+8-8=0-8\\x=-8\\x=3,\:x=-8[/tex]

What is titration? Question 1 options: The process of quickly adding one solution to another until a solid is formed. The process of slowly adding one solution to another until the reaction between the two is complete. The process of mixing equal volumes of two solutions to observe the reaction between the two. The process of combining two solids until the reaction between the two is complete.

Answers

Answer:

The process of slowly adding one solution to another until the reaction between the two is complete.

Explanation:

When you perform a titration, you are slowly adding one solution of a known concentration called a titrant to a known volume of another solution of an unknown concentration until the reaction reaches neutralization, in which the reaction is no longer taking place. This is often indicated by a color change.

Hope that helps.

If a radioactive isotope of thorium (atomic number 90, mass number 232) emits 6 alpha particles and 4 beta particles during the course of radioactive decay, what is the mass number of the stable daughter product?

Answers

Answer:

The mass number of the stable daughter product is 208

Explanation:

First thing's first, we have to write out the equation of the reaction. This is given as;

²³²₉₀Th → 6 ⁴₂α  +  4 ⁰₋₁ β + X

In order to obtain the identity of X, we have to obtain it's mass numbers and atomic number.

There is conservation of matter so we expect the mass number to remain the same in both the reactant and products.

Mass Number

Reactant = 232

Product = (6* 4 = 24) + (4 * 0 = 0) + x = 24 + x

since reactant = product

232 = 24 + x

x = 232 - 24 = 208

Atomic Number

Reactant = 90

Product = (6* 2 = 12) + (4 * -1 = -4) + x = 8 + x

since reactant = product

90 = 8 + x

x = 90 - 8 = 82

1. Unas de las formas de producir nitrógeno gaseoso (N2) es mediante la oxidación de metilamina (CH3NH2), tal como se muestra en la siguiente reacción: CH3NH2 + O2 → CO2 + H2O + N2 Si reaccionan 0,5 mol de metil amina (CH3NH2) con 25,6 g de O2. Determine: a) Balancee la ecuación. (2 ptos) b) ¿Cuántos gramos de nitrógeno (N2) se pueden producir? (4 ptos) c) Si experimentalmente se obtuvieron 3,5 gramos de N2. Determine el porcentaje de rendimiento de la reacción. (4 ptos) Por favor es urgente!!!

Answers

Answer:

a) 4CH₃NH₂ + 9O₂ ⇄  4CO₂ + 10H₂O + 2N₂    

b) m = 5,043 g

c) % = 69,4 %

Explanation:

a) La ecuación balanceada es la siguiente:

4CH₃NH₂ + 9O₂ ⇄  4CO₂ + 10H₂O + 2N₂              

En el balanceo, se tiene en la relación estequiométrica que 4 moles de metilamina reacciona con 9 moles de oxígeno para producir 4 moles de dióxido de carbono, 10 moles de agua y 2 moles de nitrógeno.  

b) Para determinar la masa de nitrógeno se debe calcular primero el reactivo limitante:

[tex]n_{O_{2}} = \frac{m}{M} = \frac{25,6 g}{31,99 g/mol} = 0,800 moles[/tex]      

[tex]n_{CH_{3}NH_{2}} = \frac{4}{9}*0,800 moles = 0,356 moles[/tex]

De la ecuación anterior se tiene que la cantidad de moles de metilamina necesaria para reaccionar con 0,800 moles de oxígeno es 0,356 moles, y la cantidad de moles iniciales de metilamina es 0,5 moles, por lo tanto el reactivo limitante es el oxígeno.

Ahora, podemos calcular la masa de nitrógeno producida:

[tex]n_{N_{2}} = \frac{2}{9}*n_{O_{2}} = \frac{2}{9}*0,8 moles = 0,18 moles[/tex]

[tex]m_{N_{2}} = n_{N_{2}}*M = 0,18 moles*28,014 g/mol = 5,043 g[/tex]

Por lo tanto, se pueden producir 5,043 g de nitrógeno.

c) El redimiento de la reacción se puede calcular usando la siguiente fórmula:

[tex] \% = \frac{R_{r}}{R_{T}}*100 [/tex]

Donde:

[tex]R_{r}[/tex]: es el rendimiento real

[tex]R_{T}[/tex]: es el rendimiento teórico

[tex]\% = \frac{3,5}{5,043}*100 = 69,4[/tex]

Entonces, el procentaje de rendimiento de la reacción es 69,4%.

Espero que te sea de utilidad!        

a certain compound was found to contain 54.0 g of carbon and 10.5 grams of hydrogen. its relative molecular mass is 86.0. find the empirical and molecular formulas

Answers

Answer:

empirical formula = C3H7

molecular formula = C6H14

Which of the following best describes hydrocarbons? a. Alkanes in which a hydrogen atom is replaced by a hydroxyl group b. Binary compounds of carbon and hydrogen c. Organic compounds containing water and carbon d. Covalently bonded carbon compounds which have intermolecular force attractions to hydrogen compounds e. Compounds which are formed by the reaction of a naturally occurring carbon-containing substance and water

Answers

Answer:

b. Binary compounds of carbon and hydrogen

Explanation:

Before proceeding, Hydrocarbons refers to organic chemical compounds composed exclusively of hydrogen and carbon atoms. This means the only elements present in an hydrocarbon are;

- Carbon

- Hydrogen

Looking through the options;

- Option A: This is wrong because the hydroxyl group contains oxygen and hydrocarbons contain only hydrogen and carbon.

- option B: This is correct. Binary compounds refers to compounds with just two elements.

- option C: This is wrong because water contains oxygen and hydrocarbons contain only hydrogen and carbon.

- option D: Carbon atoms can contain other elements so this option is wrong.

- option E: This also wrong because we had already gotten the correct option.

Which of these groups of elements show the least electronegativity?

Answers

Explanation:

On the periodic table, electronegativity generally increases as you move from left to right across a period and decreases as you move down a group. As a result, the most electronegative elements are found on the top right of the periodic table, while the least electronegative elements are found on the bottom left. The answer is alkali metals.

Match each property of a liquid to what it indicates about the relative strength of the intermolecular forces in that liquid.

Strong intermolecular forces

Weak intermolecular forces

Answers

Answer:

Strong intermolecular forces:  an increase in viscosity of the liquid, increase in surface tension, decrease in vapor pressure, and an increase in the boiling point.

Weak intermolecular forces: a decrease in viscosity, a decrease in surface tension, an increase in vapor pressure and an increase in boiling point.

Explanation:

Intermolecular forces are forces of attraction or repulsion between neighboring molecules in a substance. These intermolecular forces inclde dispersion forces, dipole-dipole interactions, hydrogen bonding, and ion-dipole forces.

The strength of the intermolecular forces in a liquid usually affects the various properties of the liquid such as viscosity, surface tension, vapour pressure and boiling point.

Strong intermolecular forces in a liquid results in the following; an increase in viscosity of the liquid, increase in surface tension, decrease in vapor pressure, and an increase in the boiling point of the liquid.

Weak intermolecular forces in a liquid results in the following; a decrease in viscosity, a decrease in surface tension, an increase in vapor pressure and an increase in boiling point of that liquid.

Strong intermolecular force is defined as the increase in viscosity of the liquid, increase in surface tension, decrease in vapor pressure, and an increase in the boiling point while  weak intermolecular forces define as the decrease in viscosity, a decrease in surface tension, an increase in vapor pressure, and an increase in boiling point.

Intermolecular forces are forces of attraction or repulsion between neighboring molecules in a substance. These intermolecular forces include as follows:-

Dispersion forcesDipole-dipole interactionsHydrogen bondingion-dipole forces.

Strong intermolecular forces in a liquid result in the following; an increase in viscosity of the liquid, increase in surface tension, decrease in vapor pressure, and an increase in the boiling point of the liquid.

Weak intermolecular forces in a liquid result in the following; a decrease in viscosity, a decrease in surface tension, an increase in vapor pressure, and an increase in the boiling point of that liquid.

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A vehicle travels 2345 meter in 35 second toward the evening sun in the West. What is its speed? A. 47 m/s West

Answers

Explanation:

Speed = 2345 ÷ 35 = 67m/s

Qualitatively estimate the relative melting points for each of the solids, and rank them in decreasing order.
Rank from highest to lowest melting point. To rank items as equivalent, overlap them.
sodium chloride
graphite
solid ammonia

Answers

Answer:

Graphite> sodium chloride> solid ammonia

Explanation:

Melting points of solids has a lot to do with the nature of intermolecular forces in the solid. A substance melts when the intermolecular forces holding the crystal lattice has been overcome such that that the crystal structure of the solid just collapses.

Graphite consists of covalently bonded layers of carbon atom which form a giant lattice. The melting point of graphite is very high because of the fact that the strong covalent bonds that hold the carbon atoms together in the layers require a lot of heat energy to break. Grapoghite melts at about 3600°C

Sodium chloride is an ionic compound that melts at about 801°C. The lattice is composed of alternate sodium and chloride ions.

Solid ammonia is held together by much weaker intermolecular interaction hence it has a melting point of about −77.73 °C.

A certain radioactive nuclide has a half life of 1.00 hour(s). Calculate the rate constant for this nuclide. s-1 Calculate the decay rate for 1.000 mole of this nuclide. decays s-1

Answers

Answer:

k= 1.925×10^-4 s^-1

1.2 ×10^20 atoms/s

Explanation:

From the information provided;

t1/2=Half life= 1.00 hour or 3600 seconds

Then;

t1/2= 0.693/k

Where k= rate constant

k= 0.693/t1/2 = 0.693/3600

k= 1.925×10^-4 s^-1

Since 1 mole of the nuclide contains 6.02×10^23 atoms

Rate of decay= rate constant × number of atoms

Rate of decay = 1.925×10^-4 s^-1 ×6.02×10^23 atoms

Rate of decay= 1.2 ×10^20 atoms/s

g Increasing the number of unsaturations in a fatty acid ____________ the melting temperature of the fatty acid.

Answers

Answer:

Decreases

Explanation:

Fatty acid which have the double bond or triple bond are called unsaturated fatty acids. Because of the double or triple bond, unsaturated fatty acids are loosely packed and form some distance among molecules which lowers the melting point of unsaturated fatty acids.

So, if the unsaturation of fatty acid will increase, it leads to more branched and loosely packed molecules and decreases the melting temperature accordingly.

Arrange the following elements in order of decreasing first ionization energy: S, Ca, F, Rb, and Si.
Rank from largest to smallest. To rank items as equivalent, overlap them.

Answers

Answer:

The concentration of energy needed to withdraw an electron from an atom’s mole in the gas phase is known as the ionization energy of an atom. It is more accurately termed as the first ionization energy. The ionization energy upsurges from left to right through a period and from top to bottom in the groups.  

Of the given elements S, Ca, F, Rb, and Si, the S, and Si belong to the third period, and the atomic radius of S is less in comparison to Si, F belongs to the second period, Rb belongs to the fifth period, and Ca belongs to the fourth period. Thus, the decreasing order of first ionization energy, that is, from largest to smallest is F > S > S > Ca > Rb.  

Considering the definition of ionization energy,

Ionization energy, also called ionization potential, is the necessary energy that must be supplied to a neutral, gaseous, ground-state atom to remove an electron from an atom. When an electron is removed from a neutral atom, a cation with a charge equal to +1 is formed.

You should keep in mind that the electrons of the last layer are always lost, because they are the weakest attracted to the nucleus.

In a group, the ionization energy increases upwards because when passing from one element to the bottom, it contains one more layer of electrons. Therefore, the valence layer electrons, being further away from the nucleus, will be less attracted to it and it will cost less energy to pluck them.

In the same period, in general, it increases as you shift to the right. This is because the elements in this way have a tendency to gain electrons and therefore it will cost much more to tear them off than those on the left which, having few electrons in the last layer will cost them much less to lose them.

Taking into account the above, the decreasing order of first ionization energy, that is, from largest to smallest is F > S > S > Ca > Rb.  

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The amount of space an object takes up is called _____. gravity weight mass volume

Answers

Volume is the amount of space an object takes up

Determine the volume occupied by 10 mol of helium at 27 ° C and 82 atm

please.

Answers

Answer:

3.00 L

Explanation:

Convert the pressure to Pascals.

P = 82 atm × (101325 Pa/atm)

P = 8,308,650 Pa

Convert temperature to Kelvins.

T = 27°C + 273

T = 300 K

Use ideal gas law:

PV = nRT

(8,308,650 Pa) V = (10 mol) (8.314 J/mol/K) (300 K)

V = 0.00300 m³

If desired, convert to liters.

V = (0.00300 m³) (1000 L/m³)

V = 3.00 L

Answer:

[tex]\large \boxed{\text{3.0 L}}[/tex]

Explanation:

[tex]\begin{array}{rcl}pV &=& nRT\\\text{82 atm} \times V & = & \text{10 mol} \times \text{0.082 06 L}\cdot\text{atm}\cdot\text{K}^{-1}\text{mol}^{-1} \times \text{300.15 K}\\82V & = & \text{246 L}\\V & = & \textbf{3.0 L} \\\end{array}\\\text{The volume of the balloon is $\large \boxed{\textbf{3.0 L}}$}[/tex]

what are the similarities between amorphous solid and crystalline solid

Answers

Answer:

solid dont know

Explanation:

so sorry ask another

The cell potential for an electrochemical cell with a Zn, Zn2 half-cell and an Al, Al3 half-cell is _____ V. Enter your answer to the hundredths place and do not leave out a leading zero, if it is needed.

Answers

Answer:

0.900 V

Explanation:

Oxidation half cell;

2Al(s) -----> 2Al^3+(aq) + 6e

Reduction half equation;

3Zn^2+(aq) + 6e ----> 3Zn(s)

E°anode = -1.66V

E°cathode= -0.76 V

E°cell= E°cathode - E°anode

E°cell= -0.76-(-1.66)

E°cell= 0.900 V

Write the net ionic equation for any precipitation reaction that may be predicted when aqueous solutions of manganese(II) nitrate and sodium hydroxide are combined.

Answers

Answer:

Explanation:

Mn( NO₃ )₂ + 2Na OH = Mn( OH)₂ (s) ↓ +  2Na NO₃

Converting into ions

Mn⁺ + 2 NO₃⁻ + 2 Na⁺ + 2 OH⁻ = Mn( OH)₂ + 2 Na⁻ + 2 NO₃⁻

Cancelling out common terms

Mn⁺ + 2 OH⁻ = Mn( OH)₂

this is net ionic equation required.

Which compound is composed of oppositely charged ions? A. SCl2 B. OF2 C. PH3 D. Li2O

Answers

Answer:

D.

Explanation:

If a compound is composed of oppositely charged ions, it has to be formed by metal and non-metal.

Li2O

Li - metal

O - non-metal

1. In the addition of HBr to conjugated dienes, is the product which results from 1,2-addition or that which results from 1,4-addition the product of kinetic control?
A. From 1,2-addition
B. From 1,4-addition
2. Which of the following is the strongest acid?
A. CH3CH20H
B. CHзOCH3
C. CH3CH
D. CH3COCH3
E. CH3COH

Answers

Answer:

The answer to this question can be defined as follows:

In question 1, the answer is "Option A".

In question 2, the answer is "[tex]\bold{CH_3COOH}[/tex]".

Explanation:

In the second question, there is mistype error in the choices so the correct answer to this question can be defined as follows:

The product From 1,2-addition as its consequence of 1,4-addition is the result of kinetic regulation by HBr in conjugated dienes.The chemical name of the [tex]CH_3COOH[/tex] is the acetic acid, it is one of the carboxylic acids quite basic. It is a major chemical production factor for use as disposable soft drinks, movies or wood glue, polyethylene terephthalate, and many plastics, fibers, and fabrics. It is also used in the storage of the water and soft drinks in the bottles.

What amounts of sodium benzoate would be required to prepare 2.5L of 0.35M benzoic buffer solution with a pH of 6.10? Ka of benzoic acid = 6.5 x 10-5 MW benzoic acid, HC7H5O2, is 122.01 MW sodium benzoate, NaC7H5O2, is 144.01

Answers

Answer:

Benzoic acid: 1.288g

Sodium benzoate: 124.48g

Explanation:

Benzoic acid, HC7H5O2 is in equilibrium with its conjugate base, C7H5O2⁻ producing a buffer. The pH of the buffer can be determined following H-H equation:

pH = pKa + log [C7H5O2⁻] / [HC7H5O2] (1)

Where pH is desire pH = 6.10 pKa is -log Ka = 4.187 and [] are molar concentrations of the buffer.

As you want to prepare 2.5L of a 0.35M of buffer, moles of buffer are:

2.5L ₓ (0.35mol / L) = 0.875moles of buffer.

And you can write:

0.875 moles = [C7H5O2⁻] + [HC7H5O2] (2)

Replacing (2) in (1)

pH = pKa + log [C7H5O2⁻] / [HC7H5O2]

6.10 = 4.187 + log [C7H5O2⁻] / [HC7H5O2]

1.913 =  log [C7H5O2⁻] / [HC7H5O2]

81.846 = 0.875mol - [HC7H5O2] / [HC7H5O2]

81.846 [HC7H5O2] = 0.875mol - [HC7H5O2]

82.846 [HC7H5O2] = 0.875mol

[HC7H5O2] = 0.01056 moles

And moles of the benzoate, [C7H5O2⁻]:

[C7H5O2⁻] = 0.875mol - 0.01056mol =

[C7H5O2⁻] = 0.8644mol

Using molar mass of benzoic acid and sodium benzoate, amount of each compound you must add to prepare 2.5L of the buffer are:

Benzoic acid: 0.01056mol ₓ (122.01g/mol) = 1.288g

Sodium benzoate: 0.8644mol ₓ (144.01g/mol) = 124.482g

A buffered solution containing dissolved aniline, C6H5NH2, and aniline hydrochloride, C6H5NH3Cl, has a pH of 5.57 . A. Determine the concentration of C6H5NH+3 in the solution if the concentration of C6H5NH2 is 0.200 M. The pKb of aniline is 9.13. g

Answers

Answer:

[C₆H₅NH₃⁺] = 0.0399 M

Explanation:

This excersise can be easily solved by the Henderson Hasselbach equation

C₆H₅NH₃Cl → C₆H₅NH₃⁺  + Cl⁻

pOH = pKb + log (salt/base)

As we have value of pH, we need to determine the pOH

14 - pH = pOH

pOH = 8.43  (14 - 5.57)

Now we replace data:

pOH = pKb + log ( C₆H₅NH₃⁺/  C₆H₅NH₂ )

8.43 = 9.13 + log (  C₆H₅NH₃⁺ / 0.2 )

-0.7 = log (  C₆H₅NH₃⁺ / 0.2 )

10⁻⁰'⁷ = C₆H₅NH₃⁺ / 0.2

0.19952 = C₆H₅NH₃⁺ / 0.2

C₆H₅NH₃⁺ = 0.19952 . 0.2  = 0.0399 M

14. Based on your previous observations, predict the impact of changing the number of moles of a gas sample on the volume of the gas sample (if pressure and temperature are held constant). What effect would changing the number of moles of a gas sample have on the temperature of a gas sample (if pressure and volume are held constant)? Explain

Answers

Answer:

Number of moles of gas is directly proportional to the volume of the gas

Number of moles of the gas is directly proportional to the temperature of the gas

Explanation:

According to Avogadro's law, changing the number of moles of a gas changing the volume of the gas also since the volume of a gas is directly proportional to the number of moles of the gas.

Hence from Avogadro's law; V= kn where k is a proportionality constant, V is the volume of the gas and n is the number of moles of the gas.

Changing the number of moles will also lead to a change in the temperature of the gas, since volume is directly proportional to the number of moles of the gas and volume is also directly proportional to temperature (Charles law), it the follows that number of moles of the gas is directly proportional to its temperature.

It takes 242. kJ/mol to break a chlorine-chlorine single bond. Calculate the maximum wavelength of light for which a chlorine-chlorine single bond could be broken by absorbing a single photon. Round your answer to 3 significant digits. single by absorbing a significant digit.

Answers

Answer:

495nm

Explanation:

The energy of a photon could be obtained by using:

E = hc / λ

Where E is energy of a photon, h is Planck's constant (6.626x10⁻³⁴Js), c is speed of the light (3x10⁸ms⁻¹) and λ is wavelength.

The energy to break 1 mole of Cl-Cl bonds is 242kJ = 242000J. The energy yo break a single bond is:

242000J/mol ₓ (1mol / 6.022x10²³bonds) = 4.0186x10⁻¹⁹J/bond.

Replacing in the equation:

E = hc / λ

4.0186x10⁻¹⁹J = 3x10⁸ms⁻¹ₓ6.626x10⁻³⁴Js / λ

λ = 4.946x10⁻⁷m

Is maximum wavelength  of light that could break a Cl-Cl bond.

Usually, wavelength is given in nm (1x10⁻⁹m / 1nm). The wavelength in nm is:

4.946x10⁻⁷m ₓ (1nm / 1x10⁻⁹m) =

495nm

A solution of malonic acid, H2C3H2O4, was standardized by titration with 0.0990 M NaOH solution. If 20.52 mL mL of the NaOH solution is required to neutralize completely 11.13 mL of the malonic acid solution, what is the molarity of the malonic acid solution

Answers

Answer:

0.0913 M

Explanation:

We'll begin by writing the balanced equation for the reaction.

This is given below:

H2C3H2O4 + 2NaOH —> C3H2Na2O4 + 2H2O

From the balanced equation above, we obtained the following:

The mole ratio of the acid (nA) = 1

The mole ratio of the base (nB) = 2

Data obtained from the question include:

Molarity of base, NaOH (Mb) = 0.0990 M

Volume of base, NaOH (Vb) = 20.52 mL

Volume of acid, H2C3H2O4 (Va) = 11.13 mL

Molarity of acid, H2C3H2O4 (Ma) =..?

The molarity of the acid, H2C3H2O4 can be obtained as follow:

MaVa/MbVb = nA/nB

Ma x 11.13 / 0.0990 x 20.52 = 1/2

Cross multiply

Ma x 11.13 x 2 = 0.0990 x 20.52 x 1

Divide both side by 11.13 x 2

Ma = (0.0990 x 20.52)/ (11.13 x 2)

Ma = 0.0913 M

Therefore, the molarity of malonic acid, H2C3H2O4 solution is 0.0913 M

What mass of aluminum metal can be produced per hour in the electrolysis of a molten aluminum salt by a current of 21 A? Express your answer using two significant figures.

Answers

Answer

mass of aluminum metal= 7 .0497g of Al

Explanation:

current = 21 A

time = 1 hour = 60 X 60 = 3600 s

quantity of electricity passed = current X time = 21X 3600 = 75600 C

Following the electrolysis the below reaction will occur :

Al3+ + 3e- --------> Al

therefore, 3F i.e. 3 X 96500 C = 289500 C gives 1 mole of Al

so 1 C will produce 1/289500 moles of Al

so 108000 C will produce 1/289500 X 75600 = 0.2611 moles of Al

now 1 mole of aluminium weighs = 27 g/mole

so 0.2611 moles of Al = 0.2611 X 27 = 7 .0497 g

mass of aluminum metal= 7 .0497 g of Al

The mass of aluminum metal can be produced per hour in the electrolysis of a molten aluminum salt by a current of 21 A is 7.05 g

We'll begin by calculating the the quantity of electricity used. This can be obtained as follow:

Current (I) = 21 A

Time(t) = 1 h = 60 × 60 = 3600 s

Quantity of electricity (Q) =?

Q = it

Q = 21 × 3600

Q = 75600 C

Finally, we shall determine the mass of the aluminum metal produced.

Al³⁺ + 3e —> Al

Recall:

1 mole of Al = 27 g

1 electron (e) = 96500 C

Thus,

3 electrons = 3 × 96500 = 289500 C

From the balanced equation above,

289500 C of electricity produced 27 g of Al.

Therefore,

75600 C of electricity will produce = (75600 × 27) / 289500 = 7.05 g of Al

Thus, the mass of the aluminum metal obtained is 7.05 g

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Determine the volumes of 0.10 M CH3COOH and 0.10 M CH3COONa required to prepare 10 mL of the following pH buffers: pH 4.7, pH 5.7. (Note: the pKa of CH3COOH

Answers

Answer:

pH 4.7: 5mL of 0.10 M CH3COOH and 5mL 0.10 M CH3COONa

pH 5.7: 0.91mL of 0.10 M CH3COOH and 9.09mL 0.10 M CH3COONa

Explanation:

pKa acetic acid, CH3COOH = 4.7

It is possible to determine pH of a buffer using H-H equation:

pH = pka + log [A⁻] / [HA]

For the acetic buffer,

pH = 4.7 + log [CH3COONa] / [CH3COOH]

As you want a pH 4.7 buffer:

4.7 = 4.7 + log [CH3COONa] / [CH3COOH]

1 = [CH3COONa] / [CH3COOH]

That means you need the same amount of both species of the buffer to make the pH 4.7 buffer. That is:

5mL of 0.10 M CH3COOH and 5mL 0.10 M CH3COONa

For pH 5.7:

5.7 = 4.7 + log [CH3COONa] / [CH3COOH]

1 = log [CH3COONa] / [CH3COOH]

10 = [CH3COONa] / [CH3COOH] (1)

That means you need 10 times [CH3COONa] over [CH3COOH]

And as you know:

10mL=  [CH3COONa] + [CH3COOH] (2)

Replacing (1) in (2):

10 = 10mL + [CH3COOH] / [CH3COOH]

10[CH3COOH] = 10mL + [CH3COOH]

11[CH3COOH] = 10mL

[CH3COOH] = 0.91mL

And [CH3COONa] = 10mL - 0.91mL =

[CH3COONa] = 9.09mL

That is:

0.91mL of 0.10 M CH3COOH and 9.09mL 0.10 M CH3COONa

The volumes according to the pH are as follows:

(i) 5mL of 0.10 M CHCOOH and 5mL 0.10 M CHCOONa for pH 4.7

(ii) 0.91mL of 0.10 M CHCOOH and 9.09mL 0.10 M CHCOONa pH 5.7

Calculating the volume of chemicals needed:

Given that pKa of acetic acid, CH₃COOH = 4.7

The pH of a buffer using the H-H equation is given by:

pH = pKa + log [A⁻] / [HA]

For the acetic buffer,

pH = 4.7 + log [CH₃COONa] / [ CH₃COOH]

4.7 = 4.7 + log [CH₃COONa] / [ CH₃COOH]

0 = log [CH₃COONa] / [ CH₃COOH]

takin antilog on both sides of the equation we get:

1 = [CHCOONa] / [CHCOOH]

It implies that the same amount of both species is needed to make the pH 4.7 buffer.

So,

5mL of 0.10 M CHCOOH and 5mL 0.10 M CHCOONa makes a buffer of pH 4.7

Similarly:

5.7 = 4.7 + log [CH₃COONa] / [CH₃COOH]

1 = log [CH₃COONa] / [CH₃COOH]

takin antilog on both sides of the equation we get:

10 = [CHCOONa] / [CHCOOH]

10[CHCOOH] = [CHCOONa]

It implies that we need 10 times [CH₃COONa] as much of [CH₃COOH]

We have to prepare 10 mL of buffer, so:

10mL=  [CH₃COONa] + [CH₃COOH]

10mL = 11[CH₃COOH]

[CH₃COOH] = 0.91mL

So, [CH₃COONa] = 10mL - 0.91mL

[CHCOONa] = 9.09mL

Therefore,

0.91mL of 0.10 M CH3COOH and 9.09mL 0.10 M CH3COONa is required to make a buffer of pH 5.7

Learn more about buffer:

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D-Fructose is the sweetest monosaccharide. How does the Fischer projection of D-fructose differ from that of D-glucose? Match the words in the left column to the appropriate blanks in the sentences on the right. Fill in the blanks.
a ketone
carbon 3
carbon 2
carbon 1
an aldehyde
carbon 4
In D-glucose, there is__________ functional group, and the carbonyl group is at___________ when looking at the Fischer projection.
In D-tructose. there is functional group, and the carbonyl group is at when looking at______ the Fischer projection.

Answers

Answer:

aldehyde

carbon-1

ketone

carbon-2

Explanation:

Monosaccharides are colorless crystalline solids that are very soluble in water. Moat have a swwet taste. D-Fructose is the sweetest monosaccharide.

In the open chain form, monosaaccharides have a carbonuyl group in one of their chains. If the carbonyl group is in the form of an aldehyde group, the monosaccharide is an aldose; if the carbonyl group is in the form of a ketone group, the monosaccharide is known as a ketose. glucose is an aldose while fructose is a ketose.

In D-glucose, there is an aldehyde functional group, and the carbonyl group is at carbon-1 when looking at the Fischer projection.

In D-fructose, there is a ketone functional group, and the carbonyl group is at carbon-2 when looking at the Fischer projection.

Phosphorus pentafluoride, PF5, acts as a __________ during the formation of the anion PF−6. Select the correct answer below: A. Lewis acid B. Lewis base C. catalyst D. drying agent

Answers

Answer:

Lewis acid

Explanation:

In chemistry, a Lewis acid is any chemical specie that accepts a lone pair of electrons while a Lewis base is any chemical specie that donates a lone pair of electrons.

If we look at the formation of PF6^-, the process is as follows;

PF5 + F^- -----> PF6^-

We can see that PF5 accepted a lone pair of electrons from F^- making PF5 a lewis acid according to our definition above.

Hence in the formation of PF6^-, PF5 acts a Lewis acid.

Which sample is most likely to experience the smallest temperature change upon observing 55KJ of heat? 

Answers

Answer:

100 g of water: specific heat of water 4.18 J/g°C

Explanation:

To know the correct answer to the question, we shall determine the temperature change in each case.

For 100 g of water:

Mass (M) = 100 g

Specific heat capacity (C) = 4.18 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 100 x 4.18 x ΔT

Divide both side by 100 x 4.18

ΔT = 55000/ (100 x 4.18)

ΔT = 131.6 °C

Therefore the temperature change is 131.6 °C

For 50 g of water:

Mass (M) = 50 g

Specific heat capacity (C) = 4.18 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 50 x 4.18 x ΔT

Divide both side by 50 x 4.18

ΔT = 55000/ (50 x 4.18)

ΔT = 263.2 °C

Therefore the temperature change is 263.2 °C

For 50 g of lead:

Mass (M) = 50 g

Specific heat capacity (C) = 0.128 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 50 x 0.128 x ΔT

Divide both side by 50 x 0.128

ΔT = 55000/ (50 x 0.128)

ΔT = 8593.8 °C

Therefore the temperature change is 8593.8 °C.

For 100 g of iron:

Mass (M) = 100 g

Specific heat capacity (C) = 0.449 J/g°C

Heat absorbed (Q) = 55 KJ = 55000 J

Change in temperature (ΔT) =..?

Q = MCΔT

55000 = 100 x 0.449 x ΔT

Divide both side by 100 x 0.449

ΔT = 55000/ (100 x 0.449)

ΔT = 1224.9 °C

Therefore the temperature change is 1224.9 °C.

The table below gives the summary of the temperature change of each substance:

Mass >>> Substance >> Temp. Change

100 g >>> Water >>>>>> 131.6 °C

50 g >>>> Water >>>>>> 263.2 °C

50 g >>>> Lead >>>>>>> 8593.8 °C

100 g >>> Iron >>>>>>>> 1224.9 °C

From the table given above we can see that 100 g of water has the smallest temperature change.

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